About: Use of C,N-chelated di-n-butyltin(IV) fluoride for the synthesis of acyl fluorides, fluoroformates and fluorophosgene

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rdf:type	skos:Concept http://linked.opendata.cz/ontology/domain/vavai/Vysledek
Description	{2-[(CH3)(2)NCH2]C6H4}(n-Bu)(2)SnF (1) reacts with various chloroformates, acyl chlorides, methanesulfonyl chloride, 4,4'-dimethoxytrityl chloride and phosgene precursors or derivatives to form fluorinated analogues. All reactions proceed rapidly and under mild conditions. The use of a catalytic amount of 1 and KF in toluene led to a relatively high yield of a selected fluoroformate. (C) 2008 Elsevier Ltd. All rights reserved. {2-[(CH3)(2)NCH2]C6H4}(n-Bu)(2)SnF (1) reacts with various chloroformates, acyl chlorides, methanesulfonyl chloride, 4,4'-dimethoxytrityl chloride and phosgene precursors or derivatives to form fluorinated analogues. All reactions proceed rapidly and under mild conditions. The use of a catalytic amount of 1 and KF in toluene led to a relatively high yield of a selected fluoroformate. (C) 2008 Elsevier Ltd. All rights reserved. (en) {2-[(CH3)(2)NCH2]C6H4}(n-Bu)(2)SnF (1) reacts with various chloroformates, acyl chlorides, methanesulfonyl chloride, 4,4'-dimethoxytrityl chloride and phosgene precursors or derivatives to form fluorinated analogues. All reactions proceed rapidly and under mild conditions. The use of a catalytic amount of 1 and KF in toluene led to a relatively high yield of a selected fluoroformate. (C) 2008 Elsevier Ltd. All rights reserved. (cs)
Title	Use of C,N-chelated di-n-butyltin(IV) fluoride for the synthesis of acyl fluorides, fluoroformates and fluorophosgene Use of C,N-chelated di-n-butyltin(IV) fluoride for the synthesis of acyl fluorides, fluoroformates and fluorophosgene (en) Use of C,N-chelated di-n-butyltin(IV) fluoride for the synthesis of acyl fluorides, fluoroformates and fluorophosgene (cs)
skos:prefLabel	Use of C,N-chelated di-n-butyltin(IV) fluoride for the synthesis of acyl fluorides, fluoroformates and fluorophosgene Use of C,N-chelated di-n-butyltin(IV) fluoride for the synthesis of acyl fluorides, fluoroformates and fluorophosgene (en) Use of C,N-chelated di-n-butyltin(IV) fluoride for the synthesis of acyl fluorides, fluoroformates and fluorophosgene (cs)
skos:notation	RIV/00216275:25310/08:00007579!RIV09-GA0-25310___
http://linked.open...avai/riv/aktivita	P Z
http://linked.open...avai/riv/aktivity	P(GA203/07/0468), P(LC523), Z(MSM0021627501)
http://linked.open...iv/cisloPeriodika	44
http://linked.open...vai/riv/dodaniDat	2009
http://linked.open...aciTvurceVysledku	Eisner, Aleš Růžička, Aleš Weidlich, Tomáš Česlová, Lenka
http://linked.open.../riv/druhVysledku	J - Článek v odborném periodiku
http://linked.open...iv/duvernostUdaju	S - Úplné a pravdivé údaje nepodléhající ochraně podle zvláštních právních předpisů
http://linked.open...titaPredkladatele	Univerzita Pardubice / Fakulta chemicko-technologická
http://linked.open...dnocenehoVysledku	401728
http://linked.open...ai/riv/idVysledku	RIV/00216275:25310/08:00007579
http://linked.open...riv/jazykVysledku	eng - angličtina
http://linked.open.../riv/klicovaSlova	FLUORINATING AGENTS; HALIDES; TRIORGANOTIN(IV); REAGENT; LIGAND; ION (en)
http://linked.open.../riv/klicoveSlovo	ION REAGENT FLUORINATING AGENTS HALIDES TRIORGANOTIN(IV) LIGAND
http://linked.open...odStatuVydavatele	GB - Spojené království Velké Británie a Severního Irska
http://linked.open...ontrolniKodProRIV	[B01B287F2F71]
http://linked.open...i/riv/nazevZdroje	Tetrahedron Letters
http://linked.open...in/vavai/riv/obor	CA
http://linked.open...ichTvurcuVysledku	4 (xsd:int)
http://linked.open...cetTvurcuVysledku	6 (xsd:int)
http://linked.open...vavai/riv/projekt	Perspective inorganic materials Study of properties and the use of C,N- and Y,C,Y-chelated organometallic compounds
http://linked.open...UplatneniVysledku	2008
http://linked.open...v/svazekPeriodika	49
http://linked.open...iv/tvurceVysledku	Růžička, Aleš Weidlich, Tomáš Švec, Petr Eisner, Aleš Pejchal, Vladimír Kolářová, Lenka
http://linked.open...n/vavai/riv/zamer	Aimed preparation of special compounds and materials and investigation of their physical and chemical properties and supramolecular structures
issn	0040-4039
number of pages	4 (xsd:int)
http://localhost/t...ganizacniJednotka	25310

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