About: C, N and N, C, N-chelated Organotin (IV) Fluorides     Goto   Sponge   NotDistinct   Permalink

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Description
  • One of the goals in the chemistry of tri-, di-, and monoorganotin(IV) compounds is to prepare and characterize structurally monomeric organotin fluorides, which are of great interest due to their ability to undergo the metathetical halide for fluoride exchange reactions with different kinds of organic, inorganic or organometallic halides. For these purposes, organotin systems containing C,N-chelating or N,C,N-chelating ligands were selected. During the last five years, a set of compounds was prepared and structurally characterized. C,N-chelated triorganotin compounds bearing the LCN ligand, where LCN is {2-[(CH3)2NCH2]C6H4}- , reveal the monomeric structure in solution as well as in the solid state with pentacoordinated tin atom and the longest Sn-F distances due to the trans effect of the lone electron pair of nitrogen. Di-, and monoorganotin(IV) fluorides having either the monomeric and oligomeric structure with hexacoordinated tin atoms and both terminal and bridging fluorine atoms. The N,C,N-chela
  • One of the goals in the chemistry of tri-, di-, and monoorganotin(IV) compounds is to prepare and characterize structurally monomeric organotin fluorides, which are of great interest due to their ability to undergo the metathetical halide for fluoride exchange reactions with different kinds of organic, inorganic or organometallic halides. For these purposes, organotin systems containing C,N-chelating or N,C,N-chelating ligands were selected. During the last five years, a set of compounds was prepared and structurally characterized. C,N-chelated triorganotin compounds bearing the LCN ligand, where LCN is {2-[(CH3)2NCH2]C6H4}- , reveal the monomeric structure in solution as well as in the solid state with pentacoordinated tin atom and the longest Sn-F distances due to the trans effect of the lone electron pair of nitrogen. Di-, and monoorganotin(IV) fluorides having either the monomeric and oligomeric structure with hexacoordinated tin atoms and both terminal and bridging fluorine atoms. The N,C,N-chela (en)
  • One of the goals in the chemistry of tri-, di-, and monoorganotin(IV) compounds is to prepare and characterize structurally monomeric organotin fluorides, which are of great interest due to their ability to undergo the metathetical halide for fluoride exchange reactions with different kinds of organic, inorganic or organometallic halides. For these purposes, organotin systems containing C,N-chelating or N,C,N-chelating ligands were selected. During the last five years, a set of compounds was prepared and structurally characterized. C,N-chelated triorganotin compounds bearing the LCN ligand, where LCN is {2-[(CH3)2NCH2]C6H4}- , reveal the monomeric structure in solution as well as in the solid state with pentacoordinated tin atom and the longest Sn-F distances due to the trans effect of the lone electron pair of nitrogen. Di-, and monoorganotin(IV) fluorides having either the monomeric and oligomeric structure with hexacoordinated tin atoms and both terminal and bridging fluorine atoms. The N,C,N-chela (cs)
Title
  • C, N and N, C, N-chelated Organotin (IV) Fluorides
  • C, N and N, C, N-chelated Organotin (IV) Fluorides (en)
  • C, N and N, C, N-chelated Organotin (IV) Fluorides (cs)
skos:prefLabel
  • C, N and N, C, N-chelated Organotin (IV) Fluorides
  • C, N and N, C, N-chelated Organotin (IV) Fluorides (en)
  • C, N and N, C, N-chelated Organotin (IV) Fluorides (cs)
skos:notation
  • RIV/00216275:25310/07:00005940!RIV08-MSM-25310___
http://linked.open.../vavai/riv/strany
  • 281-312
http://linked.open...avai/riv/aktivita
http://linked.open...avai/riv/aktivity
  • P(GA203/07/0468), P(LC523)
http://linked.open...vai/riv/dodaniDat
http://linked.open...aciTvurceVysledku
http://linked.open.../riv/druhVysledku
http://linked.open...iv/duvernostUdaju
http://linked.open...titaPredkladatele
http://linked.open...dnocenehoVysledku
  • 412476
http://linked.open...ai/riv/idVysledku
  • RIV/00216275:25310/07:00005940
http://linked.open...riv/jazykVysledku
http://linked.open.../riv/klicovaSlova
  • tin; fluorine (en)
http://linked.open.../riv/klicoveSlovo
http://linked.open...ontrolniKodProRIV
  • [CA17E2DD7A64]
http://linked.open...i/riv/mistoVydani
  • NY, USA
http://linked.open...i/riv/nazevZdroje
  • Fluorine Chemistry Research Advances
http://linked.open...in/vavai/riv/obor
http://linked.open...ichTvurcuVysledku
http://linked.open...cetTvurcuVysledku
http://linked.open...vavai/riv/projekt
http://linked.open...UplatneniVysledku
http://linked.open...iv/tvurceVysledku
  • Růžička, Aleš
number of pages
http://purl.org/ne...btex#hasPublisher
  • Nova Science Publishers
https://schema.org/isbn
  • 1-60021-730-3
http://localhost/t...ganizacniJednotka
  • 25310
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