About: Decomposition of some Polynitro Arenes Initiated by Heat and Shock. Part II..Several N-(2,4,6-trinitrophenyl)-substituted amino derivatives)

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rdf:type	skos:Concept http://linked.opendata.cz/ontology/domain/vavai/Vysledek
Description	Samples of 2,4,6-trinitroaniline (PAM), 2,4,6-trinitro-N-(2,4,6-trinitrophenyl)aniline (DPA), N,N´-bis(2,4,6-trinitrophenyl)-3,5-dinitropyridine-2,6-diamine (PYX) and N,N?,N??-tris(2,4,6-trinitrophenyl)-1,3,5-triazine-2,4,6-triamine (TPM) were exposed to heat or to shock and then analysed chromatographically (LC?UV and LC/MS). It was found that the main identified decomposition products of these two incomplete initiations are identical for each of the compounds studied. It has been stated that the chemical micro-mechanism of the primary fragmentations of their low-temperature decomposition should be the same as in the case of their initiation by shock, including fragmentation during their detonation transformation. Samples of 2,4,6-trinitroaniline (PAM), 2,4,6-trinitro-N-(2,4,6-trinitrophenyl)aniline (DPA), N,N´-bis(2,4,6-trinitrophenyl)-3,5-dinitropyridine-2,6-diamine (PYX) and N,N?,N??-tris(2,4,6-trinitrophenyl)-1,3,5-triazine-2,4,6-triamine (TPM) were exposed to heat or to shock and then analysed chromatographically (LC?UV and LC/MS). It was found that the main identified decomposition products of these two incomplete initiations are identical for each of the compounds studied. It has been stated that the chemical micro-mechanism of the primary fragmentations of their low-temperature decomposition should be the same as in the case of their initiation by shock, including fragmentation during their detonation transformation. (en) Samples of 2,4,6-trinitroaniline (PAM), 2,4,6-trinitro-N-(2,4,6-trinitrophenyl)aniline (DPA), N,N´-bis(2,4,6-trinitrophenyl)-3,5-dinitropyridine-2,6-diamine (PYX) and N,N?,N??-tris(2,4,6-trinitrophenyl)-1,3,5-triazine-2,4,6-triamine (TPM) were exposed to heat or to shock and then analysed chromatographically (LC?UV and LC/MS). It was found that the main identified decomposition products of these two incomplete initiations are identical for each of the compounds studied. It has been stated that the chemical micro-mechanism of the primary fragmentations of their low-temperature decomposition should be the same as in the case of their initiation by shock, including fragmentation during their detonation transformation. (cs)
Title	Decomposition of some Polynitro Arenes Initiated by Heat and Shock. Part II..Several N-(2,4,6-trinitrophenyl)-substituted amino derivatives) Decomposition of some Polynitro Arenes Initiated by Heat and Shock. Part II..Several N-(2,4,6-trinitrophenyl)-substituted amino derivatives) (en) Decomposition of some Polynitro Arenes Initiated by Heat and Shock. Part II..Several N-(2,4,6-trinitrophenyl)-substituted amino derivatives) (cs)
skos:prefLabel	Decomposition of some Polynitro Arenes Initiated by Heat and Shock. Part II..Several N-(2,4,6-trinitrophenyl)-substituted amino derivatives) Decomposition of some Polynitro Arenes Initiated by Heat and Shock. Part II..Several N-(2,4,6-trinitrophenyl)-substituted amino derivatives) (en) Decomposition of some Polynitro Arenes Initiated by Heat and Shock. Part II..Several N-(2,4,6-trinitrophenyl)-substituted amino derivatives) (cs)
skos:notation	RIV/00216275:25310/06:00004583!RIV08-MSM-25310___
http://linked.open.../vavai/riv/strany	1345-1351
http://linked.open...avai/riv/aktivita	Z
http://linked.open...avai/riv/aktivity	Z(MSM0021627501)
http://linked.open...iv/cisloPeriodika	137
http://linked.open...vai/riv/dodaniDat	2008
http://linked.open...aciTvurceVysledku	Varga, Robert Zeman, Svatopluk
http://linked.open.../riv/druhVysledku	J - Článek v odborném periodiku
http://linked.open...iv/duvernostUdaju	S - Úplné a pravdivé údaje nepodléhající ochraně podle zvláštních právních předpisů
http://linked.open...titaPredkladatele	Univerzita Pardubice / Fakulta chemicko-technologická
http://linked.open...dnocenehoVysledku	470576
http://linked.open...ai/riv/idVysledku	RIV/00216275:25310/06:00004583
http://linked.open...riv/jazykVysledku	eng - angličtina
http://linked.open.../riv/klicovaSlova	Polynitro Arenes; decomposition (en)
http://linked.open.../riv/klicoveSlovo	decomposition Polynitro Arenes
http://linked.open...odStatuVydavatele	NL - Nizozemsko
http://linked.open...ontrolniKodProRIV	[65D6CFB2DCB5]
http://linked.open...i/riv/nazevZdroje	Journal of Hazardous Materials
http://linked.open...in/vavai/riv/obor	CF
http://linked.open...ichTvurcuVysledku	2 (xsd:int)
http://linked.open...cetTvurcuVysledku	2 (xsd:int)
http://linked.open...UplatneniVysledku	2006
http://linked.open...v/svazekPeriodika	neuveden
http://linked.open...iv/tvurceVysledku	Zeman, Svatopluk Varga, Robert
http://linked.open...n/vavai/riv/zamer	Aimed preparation of special compounds and materials and investigation of their physical and chemical properties and supramolecular structures
issn	0304-3894
number of pages	6 (xsd:int)
http://localhost/t...ganizacniJednotka	25310

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