About: Decomposition of some Polynitro Arenes Initiated by Heat and Shock. Part I. 2,4,6-Trinitrotoluene     Goto   Sponge   NotDistinct   Permalink

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Description
  • Vzorky 2,4,6-trinitrotoluenu (TNT) po expozici teplem a rázovou vlnou, včetně residua po detonaci TNT, byly analyzovány chromatograficky (LC-UV a LC/MS). Bylo nalezeno, že hlavní identifikované meziprodukt těchto štěpení byly ve všech třech případech identické. 4,6-Dinitro-2,1-benzoisoxazol and 2,4,6-trinitrobenzaldehyd jsou z nich nejreaktivnější. . Bylo konstatováno, že chemický mikromechanizmus primární fragmentace šokem exponovaného TNT a/nebo jeho detonační transformace by měl být totožný s jeho štěpením v nízko-teplotní termolýze. (cs)
  • Samples of 2,4,6-trinitrotoluene (TNT) exposed to heat or to shock and residues after their detonation have been analyzed chromatographically (LC-UV and LC/MS). It was found that the main identified decomposition intermediates are identical in all the three cases. 4,6-Dinitro-2,1-benzoisoxazole and 2,4,6-trinitrobenzaldehyde are the most reactive from them. It has been stated that the chemical micro-mechanism of the primary fragmentations of shock-exposed TNT molecules and/or its detonation transformation should be the same as in the case of its low-temperature thermal decomposition
  • Samples of 2,4,6-trinitrotoluene (TNT) exposed to heat or to shock and residues after their detonation have been analyzed chromatographically (LC-UV and LC/MS). It was found that the main identified decomposition intermediates are identical in all the three cases. 4,6-Dinitro-2,1-benzoisoxazole and 2,4,6-trinitrobenzaldehyde are the most reactive from them. It has been stated that the chemical micro-mechanism of the primary fragmentations of shock-exposed TNT molecules and/or its detonation transformation should be the same as in the case of its low-temperature thermal decomposition (en)
Title
  • Decomposition of some Polynitro Arenes Initiated by Heat and Shock. Part I. 2,4,6-Trinitrotoluene
  • Decomposition of some Polynitro Arenes Initiated by Heat and Shock. Part I. 2,4,6-Trinitrotoluene (en)
  • Rozklad některých polynitroarenů iniciovaný teplem a šokem. Část I. 2,4,6-Trinitrotoluen (cs)
skos:prefLabel
  • Decomposition of some Polynitro Arenes Initiated by Heat and Shock. Part I. 2,4,6-Trinitrotoluene
  • Decomposition of some Polynitro Arenes Initiated by Heat and Shock. Part I. 2,4,6-Trinitrotoluene (en)
  • Rozklad některých polynitroarenů iniciovaný teplem a šokem. Část I. 2,4,6-Trinitrotoluen (cs)
skos:notation
  • RIV/00216275:25310/06:00004582!RIV07-MSM-25310___
http://linked.open.../vavai/riv/strany
  • 165-170
http://linked.open...avai/riv/aktivita
http://linked.open...avai/riv/aktivity
  • Z(MSM0021627501)
http://linked.open...iv/cisloPeriodika
  • 132
http://linked.open...vai/riv/dodaniDat
http://linked.open...aciTvurceVysledku
http://linked.open.../riv/druhVysledku
http://linked.open...iv/duvernostUdaju
http://linked.open...titaPredkladatele
http://linked.open...dnocenehoVysledku
  • 470575
http://linked.open...ai/riv/idVysledku
  • RIV/00216275:25310/06:00004582
http://linked.open...riv/jazykVysledku
http://linked.open.../riv/klicovaSlova
  • chromatography; detonation; 4; 6-dinitro-2; 1-benzoisoxazole; initiation; thermal decomposition; 2; 4; 6-trinitrotoluene (en)
http://linked.open.../riv/klicoveSlovo
http://linked.open...odStatuVydavatele
  • NL - Nizozemsko
http://linked.open...ontrolniKodProRIV
  • [4DBC3C0B40B8]
http://linked.open...i/riv/nazevZdroje
  • Journal of Hazardous Materials
http://linked.open...in/vavai/riv/obor
http://linked.open...ichTvurcuVysledku
http://linked.open...cetTvurcuVysledku
http://linked.open...UplatneniVysledku
http://linked.open...v/svazekPeriodika
  • neuveden
http://linked.open...iv/tvurceVysledku
  • Zeman, Svatopluk
  • Varga, Robert
http://linked.open...n/vavai/riv/zamer
issn
  • 0304-3894
number of pages
http://localhost/t...ganizacniJednotka
  • 25310
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