About: Reactivity of intramolecularly coordinated aluminum compounds to R3EOH (E = Sn, Si). Remarkable migration of N,C,N and O,C,O pincer ligands

Facets (new session)
Description
Metadata
Settings
- owl:sameAs
- Inference Rule:

About: Reactivity of intramolecularly coordinated aluminum compounds to R3EOH (E = Sn, Si). Remarkable migration of N,C,N and O,C,O pincer ligands Goto Sponge NotDistinct Permalink

An Entity of Type : http://linked.opendata.cz/ontology/domain/vavai/Vysledek, within Data Space : linked.opendata.cz associated with source document(s)

Attributes	Values
rdf:type	skos:Concept http://linked.opendata.cz/ontology/domain/vavai/Vysledek
Description	The reaction of organoaluminum compounds containing O,C,O or N,C,N chelating (so called pincer) ligands [2,6-(YCH2)(2)C6H3]-(AlBu2)-Bu-i (Y = MeO 1, (BuO)-Bu-t 2, Me2N 3) with R3SnOH (R = Ph or Me) gives tetraorganotin complexes [2,6-(YCH2)(2)C6H3]SnR3 (Y = MeO, R = Ph 4, Y = MeO, R = Me 5; Y = (BuO)-Bu-t, R = Ph 6, Y = (BuO)-Bu-t, R = Me 7; Y = Me2N, R = Ph 8, Y = Me2N, R = Me 9) as the result of migration of O,C,O or N,C,N pincer ligands from aluminum to tin atom. Reaction of 1 and 2 with ((Bu3Sn)-Bu-n)(2)O proceeded in similar fashion resulting in 10 and 11 ([2,6-(YCH2)(2)C6H3](SnBu3)-Bu-n, Y = MeO 10; Y = (BuO)-Bu-t 11) in mixture with (Bu3SnBu)-Bu-n-Bu-i. The reaction I and 3 with 2 equiv. of Ph3SiOH followed another reaction path and ([2,6-(YCH2)(2)C6H3]Al(OSiPh3)(2), Y = MeO 12, Me2N 13) were observed as the products of alkane elimination. The organotin derivatives 4-11 were characterized by the help of elemental analysis, ESI-MS technique, H-1, C-13, Sn-119 NMR spectroscopy and in the case 6 a The reaction of organoaluminum compounds containing O,C,O or N,C,N chelating (so called pincer) ligands [2,6-(YCH2)(2)C6H3]-(AlBu2)-Bu-i (Y = MeO 1, (BuO)-Bu-t 2, Me2N 3) with R3SnOH (R = Ph or Me) gives tetraorganotin complexes [2,6-(YCH2)(2)C6H3]SnR3 (Y = MeO, R = Ph 4, Y = MeO, R = Me 5; Y = (BuO)-Bu-t, R = Ph 6, Y = (BuO)-Bu-t, R = Me 7; Y = Me2N, R = Ph 8, Y = Me2N, R = Me 9) as the result of migration of O,C,O or N,C,N pincer ligands from aluminum to tin atom. Reaction of 1 and 2 with ((Bu3Sn)-Bu-n)(2)O proceeded in similar fashion resulting in 10 and 11 ([2,6-(YCH2)(2)C6H3](SnBu3)-Bu-n, Y = MeO 10; Y = (BuO)-Bu-t 11) in mixture with (Bu3SnBu)-Bu-n-Bu-i. The reaction I and 3 with 2 equiv. of Ph3SiOH followed another reaction path and ([2,6-(YCH2)(2)C6H3]Al(OSiPh3)(2), Y = MeO 12, Me2N 13) were observed as the products of alkane elimination. The organotin derivatives 4-11 were characterized by the help of elemental analysis, ESI-MS technique, H-1, C-13, Sn-119 NMR spectroscopy and in the case 6 a (en) The reaction of organoaluminum compounds containing O,C,O or N,C,N chelating (so called pincer) ligands [2,6-(YCH2)(2)C6H3]-(AlBu2)-Bu-i (Y = MeO 1, (BuO)-Bu-t 2, Me2N 3) with R3SnOH (R = Ph or Me) gives tetraorganotin complexes [2,6-(YCH2)(2)C6H3]SnR3 (Y = MeO, R = Ph 4, Y = MeO, R = Me 5; Y = (BuO)-Bu-t, R = Ph 6, Y = (BuO)-Bu-t, R = Me 7; Y = Me2N, R = Ph 8, Y = Me2N, R = Me 9) as the result of migration of O,C,O or N,C,N pincer ligands from aluminum to tin atom. Reaction of 1 and 2 with ((Bu3Sn)-Bu-n)(2)O proceeded in similar fashion resulting in 10 and 11 ([2,6-(YCH2)(2)C6H3](SnBu3)-Bu-n, Y = MeO 10; Y = (BuO)-Bu-t 11) in mixture with (Bu3SnBu)-Bu-n-Bu-i. The reaction I and 3 with 2 equiv. of Ph3SiOH followed another reaction path and ([2,6-(YCH2)(2)C6H3]Al(OSiPh3)(2), Y = MeO 12, Me2N 13) were observed as the products of alkane elimination. The organotin derivatives 4-11 were characterized by the help of elemental analysis, ESI-MS technique, H-1, C-13, Sn-119 NMR spectroscopy and in the case 6 a (cs)
Title	Reactivity of intramolecularly coordinated aluminum compounds to R3EOH (E = Sn, Si). Remarkable migration of N,C,N and O,C,O pincer ligands Reactivity of intramolecularly coordinated aluminum compounds to R3EOH (E = Sn, Si). Remarkable migration of N,C,N and O,C,O pincer ligands (en) Reaktivita intramolekulárně koordinovaných organohlinitých sloučenin s R3EOH (E = Sn, Si). Remarkable migration of N,C,N and O,C,O pincer ligands (cs)
skos:prefLabel	Reactivity of intramolecularly coordinated aluminum compounds to R3EOH (E = Sn, Si). Remarkable migration of N,C,N and O,C,O pincer ligands Reactivity of intramolecularly coordinated aluminum compounds to R3EOH (E = Sn, Si). Remarkable migration of N,C,N and O,C,O pincer ligands (en) Reaktivita intramolekulárně koordinovaných organohlinitých sloučenin s R3EOH (E = Sn, Si). Remarkable migration of N,C,N and O,C,O pincer ligands (cs)
skos:notation	RIV/00216275:25310/06:00004128!RIV08-MSM-25310___
http://linked.open.../vavai/riv/strany	35-44
http://linked.open...avai/riv/aktivita	P Z
http://linked.open...avai/riv/aktivity	P(GA203/03/1071), P(GP203/03/P128), P(LC523), Z(MSM0021627501)
http://linked.open...iv/cisloPeriodika	691
http://linked.open...vai/riv/dodaniDat	2008
http://linked.open...aciTvurceVysledku	Dostál, Libor Růžička, Aleš Jambor, Roman Holeček, Jaroslav
http://linked.open.../riv/druhVysledku	J - Článek v odborném periodiku
http://linked.open...iv/duvernostUdaju	S - Úplné a pravdivé údaje nepodléhající ochraně podle zvláštních právních předpisů
http://linked.open...titaPredkladatele	Univerzita Pardubice / Fakulta chemicko-technologická
http://linked.open...dnocenehoVysledku	496492
http://linked.open...ai/riv/idVysledku	RIV/00216275:25310/06:00004128
http://linked.open...riv/jazykVysledku	eng - angličtina
http://linked.open.../riv/klicovaSlova	aluminum; tin; silicon; chelating ligand; transmetallation (en)
http://linked.open.../riv/klicoveSlovo	transmetallation aluminum silicon tin chelating ligand
http://linked.open...odStatuVydavatele	CH - Švýcarská konfederace
http://linked.open...ontrolniKodProRIV	[7496E85C8A6D]
http://linked.open...i/riv/nazevZdroje	Journal of Organometallic Chemistry
http://linked.open...in/vavai/riv/obor	CA
http://linked.open...ichTvurcuVysledku	4 (xsd:int)
http://linked.open...cetTvurcuVysledku	6 (xsd:int)
http://linked.open...vavai/riv/projekt	Perspective inorganic materials Structural analysis of organometallic compounds using mass spectrometry with MSn analysis Intramolecularly coordinated organoaluminium compounds
http://linked.open...UplatneniVysledku	2006
http://linked.open...v/svazekPeriodika	12
http://linked.open...iv/tvurceVysledku	Císařová, Ivana Dostál, Libor Jambor, Roman Růžička, Aleš Jirásko, Robert Holeček, Jaroslav
http://linked.open...n/vavai/riv/zamer	Aimed preparation of special compounds and materials and investigation of their physical and chemical properties and supramolecular structures
issn	0022-328X
number of pages	10 (xsd:int)
http://localhost/t...ganizacniJednotka	25310

Faceted Search & Find service v1.16.118 as of Jun 21 2024

Alternative Linked Data Documents: ODE Content Formats:

RDF

ODATA

Microdata

About

OpenLink Virtuoso version 07.20.3240 as of Jun 21 2024, on Linux (x86_64-pc-linux-gnu), Single-Server Edition (126 GB total memory, 48 GB memory in use)
Data on this page belongs to its respective rights holders.
Virtuoso Faceted Browser Copyright © 2009-2024 OpenLink Software