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rdf:type
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Description
| - Organotin(IV) carboxylates (R2LSnOC)-Sn-NC(O)CH2P(E)Ph-2, where L-NC is an N-chelating 2-(dimethylamino)phenyl group, and R/E = Ph/void (1a), Ph/O (1b), Ph/S (1c), Me/void (2a), Me/O (2b) and Me/S (2c), were synthesized, characterized by H-1, C-13, P-31 and Sn-119 NMR, IR and MS spectra, and the solid-state structures of 1b, 1c, 2b and 2c were determined by single-crystal X-ray diffraction. Spectral and structural data showed that the compounds are monomeric in CDCl3 solution and the solid state, with the organophosphorus groups in the alpha-position of the monodentate carboxylate ligands not interacting with the tin atom. Copyright (C) 2004 John Wiley Sons, Ltd.
- Organotin(IV) carboxylates (R2LSnOC)-Sn-NC(O)CH2P(E)Ph-2, where L-NC is an N-chelating 2-(dimethylamino)phenyl group, and R/E = Ph/void (1a), Ph/O (1b), Ph/S (1c), Me/void (2a), Me/O (2b) and Me/S (2c), were synthesized, characterized by H-1, C-13, P-31 and Sn-119 NMR, IR and MS spectra, and the solid-state structures of 1b, 1c, 2b and 2c were determined by single-crystal X-ray diffraction. Spectral and structural data showed that the compounds are monomeric in CDCl3 solution and the solid state, with the organophosphorus groups in the alpha-position of the monodentate carboxylate ligands not interacting with the tin atom. Copyright (C) 2004 John Wiley Sons, Ltd. (en)
- Tri- and di-organotin(IV) compounds containing one or two 2-(dimethylaminomethyl)phenyl-(L-CN) groups as chelating ligands were prepared by reactions of lithium compound (LLi)-Li-CN with an appropriate amount of (organo)tin halide. The geometry of tin in 1 ((L-CN)(2)SnPhCl) is on the boundary between octahedral and trigonal bipyramidal. The diorganotin compounds 2-4 ((L-CN)(2)SnX2, where X = Cl, Br, I) have a distorted octahedral geometry in the solid state and show dynamic processes in solution with a lowering of activation energy of the dynamic process going from diiodide to dichloride derivative. Compound 5 ((LSnPhCl2)-Sn-CN) has a trigonal bipyramidal structure with non-equivalent chlorine atoms. Copyright (c) 2005 John Wiley & Sons, Ltd. (cs)
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Title
| - Preparation and structures of [2-(dimethylamino)phenyl]diorganotin(IV) acetates substituted with organophosphorus groups in the alpha-position of the acetate ligand
- Preparation and structures of [2-(dimethylamino)phenyl]diorganotin(IV) acetates substituted with organophosphorus groups in the alpha-position of the acetate ligand (en)
- Structure and properties of double-C,N-chelated tri-and diorganotin(IV) halides (cs)
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skos:prefLabel
| - Preparation and structures of [2-(dimethylamino)phenyl]diorganotin(IV) acetates substituted with organophosphorus groups in the alpha-position of the acetate ligand
- Preparation and structures of [2-(dimethylamino)phenyl]diorganotin(IV) acetates substituted with organophosphorus groups in the alpha-position of the acetate ligand (en)
- Structure and properties of double-C,N-chelated tri-and diorganotin(IV) halides (cs)
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skos:notation
| - RIV/00216275:25310/05:00003175!RIV08-MSM-25310___
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http://linked.open.../vavai/riv/strany
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http://linked.open...avai/riv/aktivita
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http://linked.open...avai/riv/aktivity
| - P(GA203/04/0223), P(GA203/99/M037), P(GP203/02/D169), P(LC523), Z(MSM0021627501)
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http://linked.open...iv/cisloPeriodika
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http://linked.open...vai/riv/dodaniDat
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http://linked.open...aciTvurceVysledku
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http://linked.open.../riv/druhVysledku
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http://linked.open...iv/duvernostUdaju
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http://linked.open...titaPredkladatele
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http://linked.open...dnocenehoVysledku
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http://linked.open...ai/riv/idVysledku
| - RIV/00216275:25310/05:00003175
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http://linked.open...riv/jazykVysledku
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http://linked.open.../riv/klicovaSlova
| - organotin(IV) compounds; phosphinocarboxylic acids; C,N-chelate ligand; NMR; X-ray diffraction MOLECULAR-STRUCTURE; CRYSTAL-STRUCTURE; SN-N; COORDINATION; DERIVATIVES; CHEMISTRY; BEHAVIOR; HALIDES; ACID (en)
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http://linked.open.../riv/klicoveSlovo
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http://linked.open...odStatuVydavatele
| - GB - Spojené království Velké Británie a Severního Irska
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http://linked.open...ontrolniKodProRIV
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http://linked.open...i/riv/nazevZdroje
| - Applied Organometallic Chemistry
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http://linked.open...in/vavai/riv/obor
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http://linked.open...ichTvurcuVysledku
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http://linked.open...cetTvurcuVysledku
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http://linked.open...vavai/riv/projekt
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http://linked.open...UplatneniVysledku
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http://linked.open...v/svazekPeriodika
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http://linked.open...iv/tvurceVysledku
| - Císařová, Ivana
- Růžička, Aleš
- Štěpnička, Petr
- Zoufalá, Petra
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http://linked.open...n/vavai/riv/zamer
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issn
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number of pages
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http://localhost/t...ganizacniJednotka
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