About: Preparation and structures of [2-(dimethylamino)phenyl]diorganotin(IV) acetates substituted with organophosphorus groups in the alpha-position of the acetate ligand     Goto   Sponge   NotDistinct   Permalink

An Entity of Type : http://linked.opendata.cz/ontology/domain/vavai/Vysledek, within Data Space : linked.opendata.cz associated with source document(s)

AttributesValues
rdf:type
Description
  • Organotin(IV) carboxylates (R2LSnOC)-Sn-NC(O)CH2P(E)Ph-2, where L-NC is an N-chelating 2-(dimethylamino)phenyl group, and R/E = Ph/void (1a), Ph/O (1b), Ph/S (1c), Me/void (2a), Me/O (2b) and Me/S (2c), were synthesized, characterized by H-1, C-13, P-31 and Sn-119 NMR, IR and MS spectra, and the solid-state structures of 1b, 1c, 2b and 2c were determined by single-crystal X-ray diffraction. Spectral and structural data showed that the compounds are monomeric in CDCl3 solution and the solid state, with the organophosphorus groups in the alpha-position of the monodentate carboxylate ligands not interacting with the tin atom. Copyright (C) 2004 John Wiley Sons, Ltd.
  • Organotin(IV) carboxylates (R2LSnOC)-Sn-NC(O)CH2P(E)Ph-2, where L-NC is an N-chelating 2-(dimethylamino)phenyl group, and R/E = Ph/void (1a), Ph/O (1b), Ph/S (1c), Me/void (2a), Me/O (2b) and Me/S (2c), were synthesized, characterized by H-1, C-13, P-31 and Sn-119 NMR, IR and MS spectra, and the solid-state structures of 1b, 1c, 2b and 2c were determined by single-crystal X-ray diffraction. Spectral and structural data showed that the compounds are monomeric in CDCl3 solution and the solid state, with the organophosphorus groups in the alpha-position of the monodentate carboxylate ligands not interacting with the tin atom. Copyright (C) 2004 John Wiley Sons, Ltd. (en)
  • Tri- and di-organotin(IV) compounds containing one or two 2-(dimethylaminomethyl)phenyl-(L-CN) groups as chelating ligands were prepared by reactions of lithium compound (LLi)-Li-CN with an appropriate amount of (organo)tin halide. The geometry of tin in 1 ((L-CN)(2)SnPhCl) is on the boundary between octahedral and trigonal bipyramidal. The diorganotin compounds 2-4 ((L-CN)(2)SnX2, where X = Cl, Br, I) have a distorted octahedral geometry in the solid state and show dynamic processes in solution with a lowering of activation energy of the dynamic process going from diiodide to dichloride derivative. Compound 5 ((LSnPhCl2)-Sn-CN) has a trigonal bipyramidal structure with non-equivalent chlorine atoms. Copyright (c) 2005 John Wiley & Sons, Ltd. (cs)
Title
  • Preparation and structures of [2-(dimethylamino)phenyl]diorganotin(IV) acetates substituted with organophosphorus groups in the alpha-position of the acetate ligand
  • Preparation and structures of [2-(dimethylamino)phenyl]diorganotin(IV) acetates substituted with organophosphorus groups in the alpha-position of the acetate ligand (en)
  • Structure and properties of double-C,N-chelated tri-and diorganotin(IV) halides (cs)
skos:prefLabel
  • Preparation and structures of [2-(dimethylamino)phenyl]diorganotin(IV) acetates substituted with organophosphorus groups in the alpha-position of the acetate ligand
  • Preparation and structures of [2-(dimethylamino)phenyl]diorganotin(IV) acetates substituted with organophosphorus groups in the alpha-position of the acetate ligand (en)
  • Structure and properties of double-C,N-chelated tri-and diorganotin(IV) halides (cs)
skos:notation
  • RIV/00216275:25310/05:00003175!RIV08-MSM-25310___
http://linked.open.../vavai/riv/strany
  • 118-124
http://linked.open...avai/riv/aktivita
http://linked.open...avai/riv/aktivity
  • P(GA203/04/0223), P(GA203/99/M037), P(GP203/02/D169), P(LC523), Z(MSM0021627501)
http://linked.open...iv/cisloPeriodika
  • 19
http://linked.open...vai/riv/dodaniDat
http://linked.open...aciTvurceVysledku
http://linked.open.../riv/druhVysledku
http://linked.open...iv/duvernostUdaju
http://linked.open...titaPredkladatele
http://linked.open...dnocenehoVysledku
  • 538178
http://linked.open...ai/riv/idVysledku
  • RIV/00216275:25310/05:00003175
http://linked.open...riv/jazykVysledku
http://linked.open.../riv/klicovaSlova
  • organotin(IV) compounds; phosphinocarboxylic acids; C,N-chelate ligand; NMR; X-ray diffraction MOLECULAR-STRUCTURE; CRYSTAL-STRUCTURE; SN-N; COORDINATION; DERIVATIVES; CHEMISTRY; BEHAVIOR; HALIDES; ACID (en)
http://linked.open.../riv/klicoveSlovo
http://linked.open...odStatuVydavatele
  • GB - Spojené království Velké Británie a Severního Irska
http://linked.open...ontrolniKodProRIV
  • [8F87BF1A7EB3]
http://linked.open...i/riv/nazevZdroje
  • Applied Organometallic Chemistry
http://linked.open...in/vavai/riv/obor
http://linked.open...ichTvurcuVysledku
http://linked.open...cetTvurcuVysledku
http://linked.open...vavai/riv/projekt
http://linked.open...UplatneniVysledku
http://linked.open...v/svazekPeriodika
  • 1
http://linked.open...iv/tvurceVysledku
  • Císařová, Ivana
  • Růžička, Aleš
  • Štěpnička, Petr
  • Zoufalá, Petra
http://linked.open...n/vavai/riv/zamer
issn
  • 0268-2605
number of pages
http://localhost/t...ganizacniJednotka
  • 25310
Faceted Search & Find service v1.16.118 as of Jun 21 2024


Alternative Linked Data Documents: ODE     Content Formats:   [cxml] [csv]     RDF   [text] [turtle] [ld+json] [rdf+json] [rdf+xml]     ODATA   [atom+xml] [odata+json]     Microdata   [microdata+json] [html]    About   
This material is Open Knowledge   W3C Semantic Web Technology [RDF Data] Valid XHTML + RDFa
OpenLink Virtuoso version 07.20.3240 as of Jun 21 2024, on Linux (x86_64-pc-linux-gnu), Single-Server Edition (126 GB total memory, 48 GB memory in use)
Data on this page belongs to its respective rights holders.
Virtuoso Faceted Browser Copyright © 2009-2024 OpenLink Software