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| Description
| - Tepelné reactivity TMTA, RDX, TNT, TNT/TMTA a RDX/TMTA směsí a směsí TNB s TMTA a TMTA/RDX byly specifikovány pomocí DTA se zpracováním výstupů Kissingerovou methodou. Tepelné reaktivyty, vyjádřené směrnicí Ea R-1 Kissingerova vztahu, korealují se čtverci detonačních rychlostí studoaných substance ve smyslu modifikovaného Evans-- Polanyi-Semenovova vztahu. Na základě toho je konstatováno, že detonace směsí s obsahem TMTA začíná primárním štěpením TMTA. Participuje-li dominantně iontový mechanizmus na trepelném rozkladu některých studovaných směsí, potom rezuiltující Ea R-1 hodnoty nekorelují ve smyslu zmíněného vztahu. To je případ směsí TNT/TMTA, kde TNT má kyselý character ve vztahu k TMTA. Také TNB/TMTA/RDX směs může pridukovat aminy, které iontově rozkládají RDX. (cs)
- Thermal reactivities of 1,3,5-trinitroso-1,3,5-triazinane (TMTA), 1,3,5-trinitro-1,3,5-triazinane (RDX), 2,4,6-trinitrotoluene (TNT), TNT/TMTA and RDX/TMTA mixtures and mixtures of 1,3,5-trinitrobenzene (TNB) with TMTA and TMTA/RDX were specified by means of differential thermal analysis with outputs evaluation by the Kissinger method. The reactivities, expressed as Ea R-1 slopes of Kissinger relationship, correlate with squares of detonation velocities of the corresponding explosive samples in the sense of modified Evans-Polanyi-Semenov equation. Taking this fact it is stated that initiation of detonation of the mixtures with TMTA content proceeds through primarily fission of the TMTA molecule. If an ionic mechanism dominantly participates on thermal decomposition of some studied mixtures then resulting Ea R-1values do not correlate in the sense of the equation. This is the case of the TNT/TMTA mixtures where TNT has acidic character toward TMTA. Also in TNB/TMTA/RDX mixture might react amine interme
- Thermal reactivities of 1,3,5-trinitroso-1,3,5-triazinane (TMTA), 1,3,5-trinitro-1,3,5-triazinane (RDX), 2,4,6-trinitrotoluene (TNT), TNT/TMTA and RDX/TMTA mixtures and mixtures of 1,3,5-trinitrobenzene (TNB) with TMTA and TMTA/RDX were specified by means of differential thermal analysis with outputs evaluation by the Kissinger method. The reactivities, expressed as Ea R-1 slopes of Kissinger relationship, correlate with squares of detonation velocities of the corresponding explosive samples in the sense of modified Evans-Polanyi-Semenov equation. Taking this fact it is stated that initiation of detonation of the mixtures with TMTA content proceeds through primarily fission of the TMTA molecule. If an ionic mechanism dominantly participates on thermal decomposition of some studied mixtures then resulting Ea R-1values do not correlate in the sense of the equation. This is the case of the TNT/TMTA mixtures where TNT has acidic character toward TMTA. Also in TNB/TMTA/RDX mixture might react amine interme (en)
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| Title
| - Study of Thermal and Detonation Reactivities of the Mixtures Containing 1,3,5-Trinitroso-1,3,5-triazinane (TMTA)
- Studium tepelné a detonační reaktivity směsí, obsahujících 1,3,5-trinitroso-1,3,5-triazinan (cs)
- Study of Thermal and Detonation Reactivities of the Mixtures Containing 1,3,5-Trinitroso-1,3,5-triazinane (TMTA) (en)
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| skos:prefLabel
| - Study of Thermal and Detonation Reactivities of the Mixtures Containing 1,3,5-Trinitroso-1,3,5-triazinane (TMTA)
- Studium tepelné a detonační reaktivity směsí, obsahujících 1,3,5-trinitroso-1,3,5-triazinan (cs)
- Study of Thermal and Detonation Reactivities of the Mixtures Containing 1,3,5-Trinitroso-1,3,5-triazinane (TMTA) (en)
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| skos:notation
| - RIV/00216275:25310/05:00003169!RIV06-MSM-25310___
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| http://linked.open.../vavai/riv/strany
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| http://linked.open...avai/riv/aktivita
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| http://linked.open...avai/riv/aktivity
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| http://linked.open...iv/cisloPeriodika
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| http://linked.open...vai/riv/dodaniDat
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| http://linked.open...aciTvurceVysledku
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| http://linked.open.../riv/druhVysledku
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| http://linked.open...iv/duvernostUdaju
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| http://linked.open...titaPredkladatele
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| http://linked.open...dnocenehoVysledku
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| http://linked.open...ai/riv/idVysledku
| - RIV/00216275:25310/05:00003169
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| http://linked.open...riv/jazykVysledku
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| http://linked.open.../riv/klicovaSlova
| - 1; 3; 5-trinitrobenzene; 1; 3; 5-trinitroso-1; 3; 5-triazinane; 1; 3; 5-trinitro-1; 3; 5-triazinane; 2; 4; 6-trinitrotoluene; Detonation; DTA; Explosives; Initiation; Thermal reactivity; TMTA (en)
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| http://linked.open.../riv/klicoveSlovo
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| http://linked.open...odStatuVydavatele
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| http://linked.open...ontrolniKodProRIV
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| http://linked.open...i/riv/nazevZdroje
| - Central European Journal of Energetic Materials
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| http://linked.open...in/vavai/riv/obor
| |
| http://linked.open...ichTvurcuVysledku
| |
| http://linked.open...cetTvurcuVysledku
| |
| http://linked.open...UplatneniVysledku
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| http://linked.open...v/svazekPeriodika
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| http://linked.open...iv/tvurceVysledku
| - Zeman, Svatopluk
- Varga, Robert
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| http://linked.open...n/vavai/riv/zamer
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| issn
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| number of pages
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| http://localhost/t...ganizacniJednotka
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