About: Structure and properties of double-C,N-chelated tri-and diorganotin(IV) halides     Goto   Sponge   NotDistinct   Permalink

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  • Tri- and di-organotin(IV) compounds containing one or two 2-(dimethylaminomethyl)phenyl-(L-CN) groups as chelating ligands were prepared by reactions of lithium compound (LLi)-Li-CN with an appropriate amount of (organo)tin halide. The geometry of tin in 1 ((L-CN)(2)SnPhCl) is on the boundary between octahedral and trigonal bipyramidal. The diorganotin compounds 2-4 ((L-CN)(2)SnX2, where X = Cl, Br, I) have a distorted octahedral geometry in the solid state and show dynamic processes in solution with a lowering of activation energy of the dynamic process going from diiodide to dichloride derivative. Compound 5 ((LSnPhCl2)-Sn-CN) has a trigonal bipyramidal structure with non-equivalent chlorine atoms. Copyright (c) 2005 John Wiley & Sons, Ltd. (cs)
  • Tri- and di-organotin(IV) compounds containing one or two 2-(dimethylaminomethyl)phenyl-(L-CN) groups as chelating ligands were prepared by reactions of lithium compound (LLi)-Li-CN with an appropriate amount of (organo)tin halide. The geometry of tin in 1 ((L-CN)(2)SnPhCl) is on the boundary between octahedral and trigonal bipyramidal. The diorganotin compounds 2-4 ((L-CN)(2)SnX2, where X = Cl, Br, I) have a distorted octahedral geometry in the solid state and show dynamic processes in solution with a lowering of activation energy of the dynamic process going from diiodide to dichloride derivative. Compound 5 ((LSnPhCl2)-Sn-CN) has a trigonal bipyramidal structure with non-equivalent chlorine atoms. Copyright (c) 2005 John Wiley & Sons, Ltd.
  • Tri- and di-organotin(IV) compounds containing one or two 2-(dimethylaminomethyl)phenyl-(L-CN) groups as chelating ligands were prepared by reactions of lithium compound (LLi)-Li-CN with an appropriate amount of (organo)tin halide. The geometry of tin in 1 ((L-CN)(2)SnPhCl) is on the boundary between octahedral and trigonal bipyramidal. The diorganotin compounds 2-4 ((L-CN)(2)SnX2, where X = Cl, Br, I) have a distorted octahedral geometry in the solid state and show dynamic processes in solution with a lowering of activation energy of the dynamic process going from diiodide to dichloride derivative. Compound 5 ((LSnPhCl2)-Sn-CN) has a trigonal bipyramidal structure with non-equivalent chlorine atoms. Copyright (c) 2005 John Wiley & Sons, Ltd. (en)
Title
  • Structure and properties of double-C,N-chelated tri-and diorganotin(IV) halides
  • Structure and properties of double-C,N-chelated tri-and diorganotin(IV) halides (cs)
  • Structure and properties of double-C,N-chelated tri-and diorganotin(IV) halides (en)
skos:prefLabel
  • Structure and properties of double-C,N-chelated tri-and diorganotin(IV) halides
  • Structure and properties of double-C,N-chelated tri-and diorganotin(IV) halides (cs)
  • Structure and properties of double-C,N-chelated tri-and diorganotin(IV) halides (en)
skos:notation
  • RIV/00216275:25310/05:00002971!RIV08-MSM-25310___
http://linked.open.../vavai/riv/strany
  • 1101-1108
http://linked.open...avai/riv/aktivita
http://linked.open...avai/riv/aktivity
  • P(GA203/04/0223), P(GP203/02/D169), P(LC523), Z(MSM0021627501)
http://linked.open...iv/cisloPeriodika
  • 19
http://linked.open...vai/riv/dodaniDat
http://linked.open...aciTvurceVysledku
http://linked.open.../riv/druhVysledku
http://linked.open...iv/duvernostUdaju
http://linked.open...titaPredkladatele
http://linked.open...dnocenehoVysledku
  • 544959
http://linked.open...ai/riv/idVysledku
  • RIV/00216275:25310/05:00002971
http://linked.open...riv/jazykVysledku
http://linked.open.../riv/klicovaSlova
  • ORGANOMETALLIC CHEMISTRY; ARYLCOPPER COMPOUNDS ARNCUN; INTRAMOLECULAR COORDINATION; TRIORGANOTIN HALIDES; CRYSTAL-STRUCTURE; SN-N; REACTION PATHS; STEP SYNTHESIS; TIN CENTERS; SPECTROSCOPY (en)
http://linked.open.../riv/klicoveSlovo
http://linked.open...odStatuVydavatele
  • GB - Spojené království Velké Británie a Severního Irska
http://linked.open...ontrolniKodProRIV
  • [FEDC2A59A52C]
http://linked.open...i/riv/nazevZdroje
  • Applied Organometallic Chemistry
http://linked.open...in/vavai/riv/obor
http://linked.open...ichTvurcuVysledku
http://linked.open...cetTvurcuVysledku
http://linked.open...vavai/riv/projekt
http://linked.open...UplatneniVysledku
http://linked.open...v/svazekPeriodika
  • 1
http://linked.open...iv/tvurceVysledku
  • Císařová, Ivana
  • Novák, Petr
  • Padělková, Zdeňka
  • Růžička, Aleš
  • Holeček, Jaroslav
  • Kolářová, Lenka
http://linked.open...n/vavai/riv/zamer
issn
  • 0268-2605
number of pages
http://localhost/t...ganizacniJednotka
  • 25310
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