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rdf:type
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Description
| - Kinetika heterogenní katalytické reduktivní aminace cyklopentanonu byla studována na poloprovozním aktoklávu PAAR. N-cyklopentyliminocykolopentanon byl detekován jako hlavní intermediate v reakční směsi. Bylo zjištěno, že za daných podmínek nevzniká z hlavního intermediátu nežádoucí N,N-dicykopentylamin ale tento podléhá pomalé hydrolýze a vzniká žádaný cyklopentylamin v dobrém výtěžku. Bala zíksána malá množství vedlejších látek jako cyklopentanol a N,N-dicyklopentylamin. Experimentální data byla konfrontována s navrženým kinetickým modelem. (cs)
- The kinetics of heterogeneous catalytic reductive amination of cyclopentanone has been studied on a pilot plant PARR autoclave. N-cyclopentyliminocyclopentane was detected as the main intermediate in a reaction mixture. It was found that, at the given conditions, the main intermediate does not form the undesirable N,N-dicyclopentylamine but undergoes slow hydrolysis, and the desired product, cyclopentylamine, results in a good yield. Slight amounts of by-products such as cyclopentanole and N,N-dicyclopentylamine were obtained. The experimental data were confronted with the suggested kinetic model.
- The kinetics of heterogeneous catalytic reductive amination of cyclopentanone has been studied on a pilot plant PARR autoclave. N-cyclopentyliminocyclopentane was detected as the main intermediate in a reaction mixture. It was found that, at the given conditions, the main intermediate does not form the undesirable N,N-dicyclopentylamine but undergoes slow hydrolysis, and the desired product, cyclopentylamine, results in a good yield. Slight amounts of by-products such as cyclopentanole and N,N-dicyclopentylamine were obtained. The experimental data were confronted with the suggested kinetic model. (en)
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Title
| - Reductive amination of Cyclopentanone
- Reductive amination of Cyclopentanone (en)
- Reduktivní aminace cyklopentanonu (cs)
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skos:prefLabel
| - Reductive amination of Cyclopentanone
- Reductive amination of Cyclopentanone (en)
- Reduktivní aminace cyklopentanonu (cs)
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skos:notation
| - RIV/00216275:25310/05:00002684!RIV08-MSM-25310___
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http://linked.open.../vavai/riv/strany
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http://linked.open...avai/riv/aktivita
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http://linked.open...avai/riv/aktivity
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http://linked.open...iv/cisloPeriodika
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http://linked.open...vai/riv/dodaniDat
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http://linked.open...aciTvurceVysledku
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http://linked.open.../riv/druhVysledku
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http://linked.open...iv/duvernostUdaju
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http://linked.open...titaPredkladatele
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http://linked.open...dnocenehoVysledku
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http://linked.open...ai/riv/idVysledku
| - RIV/00216275:25310/05:00002684
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http://linked.open...riv/jazykVysledku
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http://linked.open.../riv/klicovaSlova
| - Cyclopentanone; Cyclopentylamine; N-cyclopentyliminocyclopentane; Heterogeneous catalytic reductive amination; Kinetics (en)
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http://linked.open.../riv/klicoveSlovo
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http://linked.open...odStatuVydavatele
| - GB - Spojené království Velké Británie a Severního Irska
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http://linked.open...ontrolniKodProRIV
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http://linked.open...i/riv/nazevZdroje
| - Applied catalysis A-General
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http://linked.open...in/vavai/riv/obor
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http://linked.open...ichTvurcuVysledku
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http://linked.open...cetTvurcuVysledku
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http://linked.open...UplatneniVysledku
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http://linked.open...v/svazekPeriodika
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http://linked.open...iv/tvurceVysledku
| - Doležal, Petr
- Hrdina, Radim
- Pavelek, Martin
- Machalický, Oldřich
- Šuláková, Romana
- Hrádková, Květoslava
- Kubec, Petr
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http://linked.open...n/vavai/riv/zamer
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issn
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number of pages
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http://localhost/t...ganizacniJednotka
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