About: Synthesis, Characterization and Structure of the Bis(methyl-cyclopentadienyl)vanadium(IV) Carboxylates

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rdf:type	skos:Concept http://linked.opendata.cz/ontology/domain/vavai/Vysledek
Description	The 1,1'-dimethylvanadocene dichloride ((C5H4CH3)2VCl2) reacts in aqueous solution with various carboxylic acids giving two different types of complexes. The 1,1'dimethylvanadocene complexes of monocarboxylic acids (C5H4CH3)2V(OOCR)2 (R = H, CCl3, CF3, C6H5) contain two monodentate carboxylic ligands, whereas oxalic and malonic acids act as chelate compounds of the formula (C5H4CH3)2 V(OOC-A-COO) (A= -, CH2). The structure of the (C5H4CH3)2V(OOCCF3)2 complex was determined by single crystal X-ray diffraction analysis. The isotropic and anisotropic EPR spectra of all the complexes prepared were recorded. The obtained EPR parameter values were found to be in agreement with proposed structures. The 1,1'-dimethylvanadocene dichloride ((C5H4CH3)2VCl2) reacts in aqueous solution with various carboxylic acids giving two different types of complexes. The 1,1'dimethylvanadocene complexes of monocarboxylic acids (C5H4CH3)2V(OOCR)2 (R = H, CCl3, CF3, C6H5) contain two monodentate carboxylic ligands, whereas oxalic and malonic acids act as chelate compounds of the formula (C5H4CH3)2 V(OOC-A-COO) (A= -, CH2). The structure of the (C5H4CH3)2V(OOCCF3)2 complex was determined by single crystal X-ray diffraction analysis. The isotropic and anisotropic EPR spectra of all the complexes prepared were recorded. The obtained EPR parameter values were found to be in agreement with proposed structures. (en) The 1,1'-dimethylvanadocene dichloride ((C5H4CH3)2VCl2) reacts in aqueous solution with various carboxylic acids giving two different types of complexes. The 1,1'dimethylvanadocene complexes of monocarboxylic acids (C5H4CH3)2V(OOCR)2 (R = H, CCl3, CF3, C6H5) contain two monodentate carboxylic ligands, whereas oxalic and malonic acids act as chelate compounds of the formula (C5H4CH3)2 V(OOC-A-COO) (A= -, CH2). The structure of the (C5H4CH3)2V(OOCCF3)2 complex was determined by single crystal X-ray diffraction analysis. The isotropic and anisotropic EPR spectra of all the complexes prepared were recorded. The obtained EPR parameter values were found to be in agreement with proposed structures. (cs)
Title	Synthesis, Characterization and Structure of the Bis(methyl-cyclopentadienyl)vanadium(IV) Carboxylates Synthesis, Characterization and Structure of the Bis(methyl-cyclopentadienyl)vanadium(IV) Carboxylates (en) Synthesis, Characterization and Structure of the Bis(methyl-cyclopentadienyl)vanadium(IV) Carboxylates (cs)
skos:prefLabel	Synthesis, Characterization and Structure of the Bis(methyl-cyclopentadienyl)vanadium(IV) Carboxylates Synthesis, Characterization and Structure of the Bis(methyl-cyclopentadienyl)vanadium(IV) Carboxylates (en) Synthesis, Characterization and Structure of the Bis(methyl-cyclopentadienyl)vanadium(IV) Carboxylates (cs)
skos:notation	RIV/00216275:25310/05:00001634!RIV08-MSM-25310___
http://linked.open.../vavai/riv/strany	157-168
http://linked.open...avai/riv/aktivita	P Z
http://linked.open...avai/riv/aktivity	P(GA203/99/M037), Z(MSM0021627501)
http://linked.open...iv/cisloPeriodika	1
http://linked.open...vai/riv/dodaniDat	2008
http://linked.open...aciTvurceVysledku	Pavlišta, Martin Vinklárek, Jaromír Holubová, Jana
http://linked.open.../riv/druhVysledku	J - Článek v odborném periodiku
http://linked.open...iv/duvernostUdaju	S - Úplné a pravdivé údaje nepodléhající ochraně podle zvláštních právních předpisů
http://linked.open...titaPredkladatele	Univerzita Pardubice / Fakulta chemicko-technologická
http://linked.open...dnocenehoVysledku	545733
http://linked.open...ai/riv/idVysledku	RIV/00216275:25310/05:00001634
http://linked.open...riv/jazykVysledku	eng - angličtina
http://linked.open.../riv/klicovaSlova	vanadocene (en)
http://linked.open.../riv/klicoveSlovo	vanadocene
http://linked.open...odStatuVydavatele	PL - Polská republika
http://linked.open...ontrolniKodProRIV	[B0146F9C18F3]
http://linked.open...i/riv/nazevZdroje	Central European Journal of Chemistry
http://linked.open...in/vavai/riv/obor	CA
http://linked.open...ichTvurcuVysledku	3 (xsd:int)
http://linked.open...cetTvurcuVysledku	5 (xsd:int)
http://linked.open...vavai/riv/projekt	Centre of molecular and crystal structures
http://linked.open...UplatneniVysledku	2005
http://linked.open...v/svazekPeriodika	3
http://linked.open...iv/tvurceVysledku	Císařová, Ivana Holubová, Jana Vinklárek, Jaromír Pavlišta, Martin Honzíček, Jan
http://linked.open...n/vavai/riv/zamer	Aimed preparation of special compounds and materials and investigation of their physical and chemical properties and supramolecular structures
issn	1644-3624
number of pages	10 (xsd:int)
http://localhost/t...ganizacniJednotka	25310

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