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  • Experimentální a teoretické studium Cp2VO2CO: použití (CO32-)-C-13 zkoumání struktury d(1)-metalocenových komplexů (cs)
  • EPR study has shown that the anticancer agent vanadocene dichloride (Cp2VCl2) interacts with carbonate contained in physiological solutions. Chelate complex Cp2VO2CO (\A(iso)(V-51)\ = 175.1 MHz, g(iso) = 1.9861) is the only paramagnetic species formed in the range about the physiological pH (5.5-11.0). The superhyperfine coupling (\a(iso)(C-13)\ = 24.1 MHz) was evidenced at measurements using C-13 labelled carbonate. The structure of carbonate complex was validated by comparison of observed and theoretical calculated HFC tensors (at the density functional level of theory).
  • EPR study has shown that the anticancer agent vanadocene dichloride (Cp2VCl2) interacts with carbonate contained in physiological solutions. Chelate complex Cp2VO2CO (\A(iso)(V-51)\ = 175.1 MHz, g(iso) = 1.9861) is the only paramagnetic species formed in the range about the physiological pH (5.5-11.0). The superhyperfine coupling (\a(iso)(C-13)\ = 24.1 MHz) was evidenced at measurements using C-13 labelled carbonate. The structure of carbonate complex was validated by comparison of observed and theoretical calculated HFC tensors (at the density functional level of theory). (en)
Title
  • Experimentální a teoretické studium Cp2VO2CO: použití (CO32-)-C-13 zkoumání struktury d(1)-metalocenových komplexů (cs)
  • An experiment and theoretical study of the Cp2VO2CO: use (CO32-)-C-13 for structure investigation of d(1)-metallocene complexes
  • An experiment and theoretical study of the Cp2VO2CO: use (CO32-)-C-13 for structure investigation of d(1)-metallocene complexes (en)
skos:prefLabel
  • Experimentální a teoretické studium Cp2VO2CO: použití (CO32-)-C-13 zkoumání struktury d(1)-metalocenových komplexů (cs)
  • An experiment and theoretical study of the Cp2VO2CO: use (CO32-)-C-13 for structure investigation of d(1)-metallocene complexes
  • An experiment and theoretical study of the Cp2VO2CO: use (CO32-)-C-13 for structure investigation of d(1)-metallocene complexes (en)
skos:notation
  • RIV/00216275:25310/04:00001635!RIV08-MSM-25310___
http://linked.open.../vavai/riv/strany
  • 870-874
http://linked.open...avai/riv/aktivita
http://linked.open...avai/riv/aktivity
  • Z(MSM 253100001)
http://linked.open...iv/cisloPeriodika
  • 10
http://linked.open...vai/riv/dodaniDat
http://linked.open...aciTvurceVysledku
http://linked.open.../riv/druhVysledku
http://linked.open...iv/duvernostUdaju
http://linked.open...titaPredkladatele
http://linked.open...dnocenehoVysledku
  • 554100
http://linked.open...ai/riv/idVysledku
  • RIV/00216275:25310/04:00001635
http://linked.open...riv/jazykVysledku
http://linked.open.../riv/klicovaSlova
  • EPR spectroscopy; super-hyperfine coupling; DFT calculations; vanadocene dichloride; antitumor agents (en)
http://linked.open.../riv/klicoveSlovo
http://linked.open...odStatuVydavatele
  • GB - Spojené království Velké Británie a Severního Irska
http://linked.open...ontrolniKodProRIV
  • [AF3BB3AAAAB0]
http://linked.open...i/riv/nazevZdroje
  • Magnetic Resonance in Chemistry
http://linked.open...in/vavai/riv/obor
http://linked.open...ichTvurcuVysledku
http://linked.open...cetTvurcuVysledku
http://linked.open...UplatneniVysledku
http://linked.open...v/svazekPeriodika
  • 42
http://linked.open...iv/tvurceVysledku
  • Holubová, Jana
  • Vinklárek, Jaromír
  • Honzíček, Jan
http://linked.open...n/vavai/riv/zamer
issn
  • 0749-1581
number of pages
http://localhost/t...ganizacniJednotka
  • 25310
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