About: Adsorption of vapours of some organic compounds on surface of iron-substituted layered vanadyl phosphate

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rdf:type	skos:Concept http://linked.opendata.cz/ontology/domain/vavai/Vysledek
Description	Adsorption of vapours of some organic compounds on surface of iron-substituted layered vanadyl phosphate (cs) Gas chromatographic measurement of specific retention volumes of vapours of selected groups of organic compounds has been used to determine differential molar enthalpy of adsorption of their molecules on the surface of layered vanadyl phosphate substituted with ferric ions having the composition of [Fe(H2O)(0.20)(VO)(0.80)PO4. Various types of bonds of the molecules to the surface of the layered adsorbent including their probable orientation with respect to the layers have been discussed. It was observed a dependence of the specific peak elution volume and shape of chromatographic peak on the sample size in the cases of those compounds whose molecules are chemically bound to the adsorbent surface. A connection is pointed out between the adsorption strength of the organic molecules on the layered adsorbent and the tendency of the system to undergo intercalation reaction. Gas chromatographic measurement of specific retention volumes of vapours of selected groups of organic compounds has been used to determine differential molar enthalpy of adsorption of their molecules on the surface of layered vanadyl phosphate substituted with ferric ions having the composition of [Fe(H2O)(0.20)(VO)(0.80)PO4. Various types of bonds of the molecules to the surface of the layered adsorbent including their probable orientation with respect to the layers have been discussed. It was observed a dependence of the specific peak elution volume and shape of chromatographic peak on the sample size in the cases of those compounds whose molecules are chemically bound to the adsorbent surface. A connection is pointed out between the adsorption strength of the organic molecules on the layered adsorbent and the tendency of the system to undergo intercalation reaction. (en)
Title	Adsorption of vapours of some organic compounds on surface of iron-substituted layered vanadyl phosphate Adsorption of vapours of some organic compounds on surface of iron-substituted layered vanadyl phosphate (en) Adsorption of vapours of some organic compounds on surface of iron-substituted layered vanadyl phosphate (cs)
skos:prefLabel	Adsorption of vapours of some organic compounds on surface of iron-substituted layered vanadyl phosphate Adsorption of vapours of some organic compounds on surface of iron-substituted layered vanadyl phosphate (en) Adsorption of vapours of some organic compounds on surface of iron-substituted layered vanadyl phosphate (cs)
skos:notation	RIV/00216275:25310/00:00008268!RIV09-MSM-25310___
http://linked.open...avai/riv/aktivita	P Z
http://linked.open...avai/riv/aktivity	P(GA203/97/1010), Z(MSM 253100002)
http://linked.open...iv/cisloPeriodika	1
http://linked.open...vai/riv/dodaniDat	2009
http://linked.open...aciTvurceVysledku	Komárek, Karel Beneš, Ludvík
http://linked.open.../riv/druhVysledku	J - Článek v odborném periodiku
http://linked.open...iv/duvernostUdaju	S - Úplné a pravdivé údaje nepodléhající ochraně podle zvláštních právních předpisů
http://linked.open...titaPredkladatele	Univerzita Pardubice / Fakulta chemicko-technologická
http://linked.open...dnocenehoVysledku	703986
http://linked.open...ai/riv/idVysledku	RIV/00216275:25310/00:00008268
http://linked.open...riv/jazykVysledku	eng - angličtina
http://linked.open.../riv/klicovaSlova	adsorption; organic compounds; iron-substituted layered vanadyl phosphate (en)
http://linked.open.../riv/klicoveSlovo	adsorption organic compounds iron-substituted layered vanadyl phosphate
http://linked.open...odStatuVydavatele	CZ - Česká republika
http://linked.open...ontrolniKodProRIV	[901A51D0D446]
http://linked.open...i/riv/nazevZdroje	Collection of Czechoslovak Chemical Communications
http://linked.open...in/vavai/riv/obor	CB
http://linked.open...ichTvurcuVysledku	2 (xsd:int)
http://linked.open...cetTvurcuVysledku	7 (xsd:int)
http://linked.open...vavai/riv/projekt	Intercalates based on layered phosphates
http://linked.open...UplatneniVysledku	2000
http://linked.open...v/svazekPeriodika	65
http://linked.open...iv/tvurceVysledku	Komárek, Karel Zima, Vítězslav Beneš, Ludvík Melánová, Klára Hradil, P. Kalousová, J. Votinský, J.
http://linked.open...n/vavai/riv/zamer	http://linked.opendata.cz/resource/domain/vavai/zamer/MSM%20253100002
issn	0010-0765
number of pages	11 (xsd:int)
http://localhost/t...ganizacniJednotka	25310

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