About: Island size evolution and molecular diffusion during growth of organic thin films followed by time-resolved specular and off-specular scattering     Goto   Sponge   NotDistinct   Permalink

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Description
  • We report on a combined off-specular and specular x-ray scattering growth study of ultrathin films of the prototypical organic semiconductor diindenoperylene (DIP, C32H16). We investigate the evolution of the in-plane correlation length and the growth kinetics of the films including their dependence on the substrate temperature and the growth rate. We observe a temperature-dependent collective rearrangement of DIP molecules from a transient surface induced to the thin-film phase, which can be rationalized by incorporating a thickness-dependent out-of-plane lattice parameter. We further observe that the nucleation behavior of DIP changes from the first to the second monolayer, which we relate to a difference in the diffusion length of the molecules.
  • We report on a combined off-specular and specular x-ray scattering growth study of ultrathin films of the prototypical organic semiconductor diindenoperylene (DIP, C32H16). We investigate the evolution of the in-plane correlation length and the growth kinetics of the films including their dependence on the substrate temperature and the growth rate. We observe a temperature-dependent collective rearrangement of DIP molecules from a transient surface induced to the thin-film phase, which can be rationalized by incorporating a thickness-dependent out-of-plane lattice parameter. We further observe that the nucleation behavior of DIP changes from the first to the second monolayer, which we relate to a difference in the diffusion length of the molecules. (en)
Title
  • Island size evolution and molecular diffusion during growth of organic thin films followed by time-resolved specular and off-specular scattering
  • Island size evolution and molecular diffusion during growth of organic thin films followed by time-resolved specular and off-specular scattering (en)
skos:prefLabel
  • Island size evolution and molecular diffusion during growth of organic thin films followed by time-resolved specular and off-specular scattering
  • Island size evolution and molecular diffusion during growth of organic thin films followed by time-resolved specular and off-specular scattering (en)
skos:notation
  • RIV/00216224:14740/14:00076244!RIV15-MSM-14740___
http://linked.open...avai/riv/aktivita
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  • P(ED1.1.00/02.0068)
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  • 4
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  • RIV/00216224:14740/14:00076244
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  • Thin film growth; organic semiconductors; X-ray scattering; molecular beam deposition (en)
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  • US - Spojené státy americké
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  • [0C1CA1C0C88F]
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  • Physical Review B
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  • 90
http://linked.open...iv/tvurceVysledku
  • Novák, Jiří
  • Banerjee, Rupak
  • Schreiber, Frank
  • Frank, Christian
  • Gerlach, Alexander
  • Kowarik, Stefan
  • Vorobiev, Alexei
http://linked.open...ain/vavai/riv/wos
  • 000339094100006
issn
  • 1098-0121
number of pages
http://bibframe.org/vocab/doi
  • 10.1103/PhysRevB.90.045410
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  • 14740
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