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Description
  • An approach of sample introduction for inductively coupled mass spectrometry (ICPMS), diode laser thermal vaporization (DLTV) is described. The method allows quantitative determination of metals in submicroliter volumes of liquid samples. Laser power is sufficient to induce pyrolysis of a suitable substrate with the deposited sample leading to aerosol generation. Unlike existing sample introduction systems based on laser ablation, it uses a NIR diode laser rather than an expensive high-energy pulsed laser. For certain elements, this sample introduction technique may serve as an alternative to solution analysis with conventional nebulizers. Using a prearranged calibration set, DLTV ICPMS provides rapid and reproducible sample analysis (RSD 10%). Sample preparation is fast and simple, and the prepared samples can easily be archived and transported. The limits of detection for Co, Ni, Zn, Mo, Cd, Sn, and Pb deposited on the preprinted paper were found to be in the range of 0.4–30 pg.
  • An approach of sample introduction for inductively coupled mass spectrometry (ICPMS), diode laser thermal vaporization (DLTV) is described. The method allows quantitative determination of metals in submicroliter volumes of liquid samples. Laser power is sufficient to induce pyrolysis of a suitable substrate with the deposited sample leading to aerosol generation. Unlike existing sample introduction systems based on laser ablation, it uses a NIR diode laser rather than an expensive high-energy pulsed laser. For certain elements, this sample introduction technique may serve as an alternative to solution analysis with conventional nebulizers. Using a prearranged calibration set, DLTV ICPMS provides rapid and reproducible sample analysis (RSD 10%). Sample preparation is fast and simple, and the prepared samples can easily be archived and transported. The limits of detection for Co, Ni, Zn, Mo, Cd, Sn, and Pb deposited on the preprinted paper were found to be in the range of 0.4–30 pg. (en)
Title
  • Diode laser thermal vaporization inductively coupled plasma mass spectrometry
  • Diode laser thermal vaporization inductively coupled plasma mass spectrometry (en)
skos:prefLabel
  • Diode laser thermal vaporization inductively coupled plasma mass spectrometry
  • Diode laser thermal vaporization inductively coupled plasma mass spectrometry (en)
skos:notation
  • RIV/00216224:14740/12:00057290!RIV13-GA0-14740___
http://linked.open...avai/riv/aktivita
http://linked.open...avai/riv/aktivity
  • P(ED1.1.00/02.0068), P(GA203/09/1025), P(GAP206/12/0538), S, Z(MSM0021622411), Z(MSM0021622412), Z(MSM0021622415)
http://linked.open...iv/cisloPeriodika
  • 5
http://linked.open...vai/riv/dodaniDat
http://linked.open...aciTvurceVysledku
http://linked.open.../riv/druhVysledku
http://linked.open...iv/duvernostUdaju
http://linked.open...titaPredkladatele
http://linked.open...dnocenehoVysledku
  • 131392
http://linked.open...ai/riv/idVysledku
  • RIV/00216224:14740/12:00057290
http://linked.open...riv/jazykVysledku
http://linked.open.../riv/klicovaSlova
  • Laser ablation; inductively coupled plasma; mass spectrometry; sample introduction; diode laser; pyrolysis; thermal vaporization (en)
http://linked.open.../riv/klicoveSlovo
http://linked.open...odStatuVydavatele
  • US - Spojené státy americké
http://linked.open...ontrolniKodProRIV
  • [AF50417FBE50]
http://linked.open...i/riv/nazevZdroje
  • Analytical Chemistry
http://linked.open...in/vavai/riv/obor
http://linked.open...ichTvurcuVysledku
http://linked.open...cetTvurcuVysledku
http://linked.open...vavai/riv/projekt
http://linked.open...UplatneniVysledku
http://linked.open...v/svazekPeriodika
  • 84
http://linked.open...iv/tvurceVysledku
  • Kanický, Viktor
  • Preisler, Jan
  • Foltynová, Pavla
http://linked.open...ain/vavai/riv/wos
  • 000301021400026
http://linked.open...n/vavai/riv/zamer
issn
  • 0003-2700
number of pages
http://bibframe.org/vocab/doi
  • 10.1021/ac202884m
http://localhost/t...ganizacniJednotka
  • 14740
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