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  • For the fast characteristics of mixtures of Aluminium, Gallium and Indium the fluorimetric evaluation in the form of complexes with 8-hydroxyquinoline-5-sulphonic acid is described at selected pH. The highly collinear correlated fluorescent spectra and their first derivation were evaluated under various experimental conditions with the Multiple Linear Regression (MLR), Partial Least Squares (PLS) methods and Kalman filtering. When comparing the results, the PLS gives the least relative prediction errors under optimal conditions, 5.6-15.9% for the concentration range of Al 0.025-0.2 mu g cm(-3), Ga 0.1-0.8 mu g cm(-3) and In 0.1-0.8 mu g cm(-3) in the mixture.
  • For the fast characteristics of mixtures of Aluminium, Gallium and Indium the fluorimetric evaluation in the form of complexes with 8-hydroxyquinoline-5-sulphonic acid is described at selected pH. The highly collinear correlated fluorescent spectra and their first derivation were evaluated under various experimental conditions with the Multiple Linear Regression (MLR), Partial Least Squares (PLS) methods and Kalman filtering. When comparing the results, the PLS gives the least relative prediction errors under optimal conditions, 5.6-15.9% for the concentration range of Al 0.025-0.2 mu g cm(-3), Ga 0.1-0.8 mu g cm(-3) and In 0.1-0.8 mu g cm(-3) in the mixture. (en)
Title
  • Multicomponental fluorimetric determination of aluminium, gallium and indium
  • Multicomponental fluorimetric determination of aluminium, gallium and indium (en)
skos:prefLabel
  • Multicomponental fluorimetric determination of aluminium, gallium and indium
  • Multicomponental fluorimetric determination of aluminium, gallium and indium (en)
skos:notation
  • RIV/00216224:14410/08:00063962!RIV13-MSM-14410___
http://linked.open...avai/riv/aktivita
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  • I, Z(MSM0021630501)
http://linked.open...iv/cisloPeriodika
  • 2
http://linked.open...vai/riv/dodaniDat
http://linked.open...aciTvurceVysledku
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  • 381074
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  • RIV/00216224:14410/08:00063962
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  • 8-hydroxyquinoline-5-sulphonic acid; multivariate evaluation; aluminium; gallium; indium complexes; fluorescence (en)
http://linked.open.../riv/klicoveSlovo
http://linked.open...odStatuVydavatele
  • US - Spojené státy americké
http://linked.open...ontrolniKodProRIV
  • [17EF57444D7B]
http://linked.open...i/riv/nazevZdroje
  • Journal of fluorescence
http://linked.open...in/vavai/riv/obor
http://linked.open...ichTvurcuVysledku
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http://linked.open...UplatneniVysledku
http://linked.open...v/svazekPeriodika
  • 18
http://linked.open...iv/tvurceVysledku
  • Jančář, Luděk
  • Vojta, Šimon
  • Sommer, Lumir
http://linked.open...ain/vavai/riv/wos
  • 000253896400012
http://linked.open...n/vavai/riv/zamer
issn
  • 1053-0509
number of pages
http://bibframe.org/vocab/doi
  • 10.1007/s10895-007-0273-2
http://localhost/t...ganizacniJednotka
  • 14410
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