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  • Oligonucleotides containing adenines (A) or cytosines (C) yield reduction voltammetric peaks on mercury electrodes. The peak potentials of both bases are located very close to each other on the potential scale, so that usually only one voltammetric peak is observed. One signal only can be observed even when adsorptive transfer stripping voltammetry (AdTSV) is used. In the present work we have used elimination voltammetry with linear scan (EVLS) in connection with hanging mercury electrode, and shown that this electrochemical method is able to distinguish the two signals. EVLS is based on elimination of one or two selected currents from total currents measured by linear scan voltammetry. The function eliminating kinetic and charging currents, and conserving the diffusion current was calculated for the case of adsorbed electroactive substance. The theoretical elimination curve has a peak-counterpeak form. This elimination function was applied to the analysis of short oligonucleotides containing A and C
  • Oligonucleotides containing adenines (A) or cytosines (C) yield reduction voltammetric peaks on mercury electrodes. The peak potentials of both bases are located very close to each other on the potential scale, so that usually only one voltammetric peak is observed. One signal only can be observed even when adsorptive transfer stripping voltammetry (AdTSV) is used. In the present work we have used elimination voltammetry with linear scan (EVLS) in connection with hanging mercury electrode, and shown that this electrochemical method is able to distinguish the two signals. EVLS is based on elimination of one or two selected currents from total currents measured by linear scan voltammetry. The function eliminating kinetic and charging currents, and conserving the diffusion current was calculated for the case of adsorbed electroactive substance. The theoretical elimination curve has a peak-counterpeak form. This elimination function was applied to the analysis of short oligonucleotides containing A and C (en)
  • Oligonucleotides containing adenines (A) or cytosines (C) yield reduction voltammetric peaks on mercury electrodes. The peak potentials of both bases are located very close to each other on the potential scale, so that usually only one voltammetric peak is observed. One signal only can be observed even when adsorptive transfer stripping voltammetry (AdTSV) is used. In the present work we have used elimination voltammetry with linear scan (EVLS) in connection with hanging mercury electrode, and shown that this electrochemical method is able to distinguish the two signals. EVLS is based on elimination of one or two selected currents from total currents measured by linear scan voltammetry. The function eliminating kinetic and charging currents, and conserving the diffusion current was calculated for the case of adsorbed electroactive substance. The theoretical elimination curve has a peak-counterpeak form. This elimination function was applied to the analysis of short oligonucleotides containing A and C (cs)
Title
  • Elimination voltammetry of short oligonucleotides
  • Elimination voltammetry of short oligonucleotides (en)
  • Elimination voltammetry of short oligonucleotides (cs)
skos:prefLabel
  • Elimination voltammetry of short oligonucleotides
  • Elimination voltammetry of short oligonucleotides (en)
  • Elimination voltammetry of short oligonucleotides (cs)
skos:notation
  • RIV/00216224:14330/02:00006480!RIV08-AV0-14330___
http://linked.open.../vavai/riv/strany
  • 105
http://linked.open...avai/riv/aktivita
http://linked.open...avai/riv/aktivity
  • P(GA203/02/0422), P(GV204/97/K084), P(IAA1163201), Z(MSM 143100011)
http://linked.open...vai/riv/dodaniDat
http://linked.open...aciTvurceVysledku
http://linked.open.../riv/druhVysledku
http://linked.open...iv/duvernostUdaju
http://linked.open...titaPredkladatele
http://linked.open...dnocenehoVysledku
  • 644909
http://linked.open...ai/riv/idVysledku
  • RIV/00216224:14330/02:00006480
http://linked.open...riv/jazykVysledku
http://linked.open.../riv/klicovaSlova
  • Oligonucleotides; Reduction of adenine and cytosine; Elimination voltammetry with linear scan; adsorption; interaction (en)
http://linked.open.../riv/klicoveSlovo
http://linked.open...ontrolniKodProRIV
  • [0A1CC6FE6D35]
http://linked.open...v/mistoKonaniAkce
  • September 15-20, 2002, Düsseldorf, Germany
http://linked.open...i/riv/mistoVydani
  • Frankfurt am Mai, Germany
http://linked.open...i/riv/nazevZdroje
  • Electrochemistry in Molecular and Microscopic Dimensions, 53rd Annual Meeting of the International Society of Electrochemistry, Book of Abstracts
http://linked.open...in/vavai/riv/obor
http://linked.open...ichTvurcuVysledku
http://linked.open...cetTvurcuVysledku
http://linked.open...vavai/riv/projekt
http://linked.open...UplatneniVysledku
http://linked.open...iv/tvurceVysledku
  • Trnková, Libuše
  • Jelen, František
  • Postbieglová, Irena
http://linked.open...vavai/riv/typAkce
http://linked.open.../riv/zahajeniAkce
http://linked.open...n/vavai/riv/zamer
number of pages
http://purl.org/ne...btex#hasPublisher
  • Dechema e.V., Society for Chemical Engineering and Biotechnology,Frankfurt am Mai,Germany
http://localhost/t...ganizacniJednotka
  • 14330
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