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rdf:type
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Description
| - Trialkyl phosphates OP(OR)3 (R = Me, Et, Ph, SiMe3) react with AlMe3, AlEt3, and GaMe3 in hydrocarbon solvents to form the adducts Me3Al.OP(OR)3 (R = Me (1), Et (2), Ph (3), SiMe3 (4)), Et3Al.OP(OR)3 (R = SiMe3 (5)), and Me3Ga.OP(OR)3 (R = Me (6), SiMe3 (7)). These products were characterized by 1H, 13C, 29Si, and 31P NMR, infrared (IR), and mass (MS) spectroscopies, and elemental analysis. The trimethylsilyl ester adducts 4, 5, and 7 further undergo a thermally induced dealkylsilylation with the formation of cyclic alumino- and gallophosphate dimers, [R'2M(m2-O)2P(OSiMe3)2]2 (R'2M = Me2Al (8), Et2Al (9), and Me2Ga (10)). The molecular structures of 8 and 9 were confirmed by X-ray crystallography.
- Trialkyl phosphates OP(OR)3 (R = Me, Et, Ph, SiMe3) react with AlMe3, AlEt3, and GaMe3 in hydrocarbon solvents to form the adducts Me3Al.OP(OR)3 (R = Me (1), Et (2), Ph (3), SiMe3 (4)), Et3Al.OP(OR)3 (R = SiMe3 (5)), and Me3Ga.OP(OR)3 (R = Me (6), SiMe3 (7)). These products were characterized by 1H, 13C, 29Si, and 31P NMR, infrared (IR), and mass (MS) spectroscopies, and elemental analysis. The trimethylsilyl ester adducts 4, 5, and 7 further undergo a thermally induced dealkylsilylation with the formation of cyclic alumino- and gallophosphate dimers, [R'2M(m2-O)2P(OSiMe3)2]2 (R'2M = Me2Al (8), Et2Al (9), and Me2Ga (10)). The molecular structures of 8 and 9 were confirmed by X-ray crystallography. (en)
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Title
| - Reactions of Trialkyl Phosphates with Trialkyls of Aluminum and Gallium: New Route to Alumino- and Gallophosphate Compounds via Dealkylsilylation
- Reactions of Trialkyl Phosphates with Trialkyls of Aluminum and Gallium: New Route to Alumino- and Gallophosphate Compounds via Dealkylsilylation (en)
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skos:prefLabel
| - Reactions of Trialkyl Phosphates with Trialkyls of Aluminum and Gallium: New Route to Alumino- and Gallophosphate Compounds via Dealkylsilylation
- Reactions of Trialkyl Phosphates with Trialkyls of Aluminum and Gallium: New Route to Alumino- and Gallophosphate Compounds via Dealkylsilylation (en)
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skos:notation
| - RIV/00216224:14310/99:00000808!RIV/2002/MSM/143102/N
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http://linked.open.../vavai/riv/strany
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http://linked.open...avai/riv/aktivita
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http://linked.open...avai/riv/aktivity
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http://linked.open...iv/cisloPeriodika
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http://linked.open...vai/riv/dodaniDat
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http://linked.open...aciTvurceVysledku
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http://linked.open.../riv/druhVysledku
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http://linked.open...iv/duvernostUdaju
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http://linked.open...titaPredkladatele
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http://linked.open...dnocenehoVysledku
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http://linked.open...ai/riv/idVysledku
| - RIV/00216224:14310/99:00000808
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http://linked.open...riv/jazykVysledku
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http://linked.open.../riv/klicovaSlova
| - building blocks, phosphates, aluminum, gallium, dealkylsilylation (en)
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http://linked.open.../riv/klicoveSlovo
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http://linked.open...odStatuVydavatele
| - US - Spojené státy americké
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http://linked.open...ontrolniKodProRIV
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http://linked.open...i/riv/nazevZdroje
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http://linked.open...in/vavai/riv/obor
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http://linked.open...ichTvurcuVysledku
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http://linked.open...cetTvurcuVysledku
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http://linked.open...ocetUcastnikuAkce
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http://linked.open...nichUcastnikuAkce
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http://linked.open...UplatneniVysledku
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http://linked.open...v/svazekPeriodika
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http://linked.open...iv/tvurceVysledku
| - Pinkas, Jiří
- Yang, Y.
- Chakraborty, D.
- Murugavel, R.
- Noltemeyer, M.
- Roesky, Herbert W.
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http://linked.open...n/vavai/riv/zamer
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issn
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number of pages
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http://localhost/t...ganizacniJednotka
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