About: Bis(bidentate) Complexes of Imidobis(diphenylphosphino chalcogenides) [M{N(XPPh2)2 - X, X'}2] (X = S or Se; M = Ni, Pd or Pt).

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About: Bis(bidentate) Complexes of Imidobis(diphenylphosphino chalcogenides) [M{N(XPPh2)2 - X, X'}2] (X = S or Se; M = Ni, Pd or Pt). Goto Sponge NotDistinct Permalink

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rdf:type	skos:Concept http://linked.opendata.cz/ontology/domain/vavai/Vysledek
Description	The compound NH(SePPh(2))(2) has been synthesised from NH(PPh(2))(2) and selenium in refluxing toluene. A range of complexes [M{N(XPPh(2))(2)-X, X'}(2)] (X = Se, M = Pt 1 or Pd 2; X = S, M = Pt 3, Pd 4 or Ni 5) of the monoanions derived from NH(SePPh(2))(2) and its sulfur analogue have been prepared. The new compounds have been characterised by microanalysis, NMR and IR spectroscopy. The crystal structures of NH(SePPh(2))(2), 1, 2 and 5 were determined. The neutral NH(SePPh(2))(2) crystallised as H-bonded dimer pairs with a noticeable difference in the hydrogen bonded End nonhydrogen bonded P=Se bond lengths. The P=Se groups are approximately anti. On complexation the anionic ligands are bidentate and in all cases the resulting MX(2)P(2)N rings are distinctly puckered. The compound NH(SePPh(2))(2) has been synthesised from NH(PPh(2))(2) and selenium in refluxing toluene. A range of complexes [M{N(XPPh(2))(2)-X, X'}(2)] (X = Se, M = Pt 1 or Pd 2; X = S, M = Pt 3, Pd 4 or Ni 5) of the monoanions derived from NH(SePPh(2))(2) and its sulfur analogue have been prepared. The new compounds have been characterised by microanalysis, NMR and IR spectroscopy. The crystal structures of NH(SePPh(2))(2), 1, 2 and 5 were determined. The neutral NH(SePPh(2))(2) crystallised as H-bonded dimer pairs with a noticeable difference in the hydrogen bonded End nonhydrogen bonded P=Se bond lengths. The P=Se groups are approximately anti. On complexation the anionic ligands are bidentate and in all cases the resulting MX(2)P(2)N rings are distinctly puckered. (en)
Title	Bis(bidentate) Complexes of Imidobis(diphenylphosphino chalcogenides) [M{N(XPPh2)2 - X, X'}2] (X = S or Se; M = Ni, Pd or Pt). Bis(bidentate) Complexes of Imidobis(diphenylphosphino chalcogenides) [M{N(XPPh2)2 - X, X'}2] (X = S or Se; M = Ni, Pd or Pt). (en)
skos:prefLabel	Bis(bidentate) Complexes of Imidobis(diphenylphosphino chalcogenides) [M{N(XPPh2)2 - X, X'}2] (X = S or Se; M = Ni, Pd or Pt). Bis(bidentate) Complexes of Imidobis(diphenylphosphino chalcogenides) [M{N(XPPh2)2 - X, X'}2] (X = S or Se; M = Ni, Pd or Pt). (en)
skos:notation	RIV/00216224:14310/95:00005900!RIV/2003/MSM/143103/N
http://linked.open.../vavai/riv/strany	1607-1613
http://linked.open...avai/riv/aktivita	Z
http://linked.open...avai/riv/aktivity	Z(MSM 143100011)
http://linked.open...iv/cisloPeriodika	10
http://linked.open...vai/riv/dodaniDat	2003
http://linked.open...aciTvurceVysledku	Novosad, Josef
http://linked.open.../riv/druhVysledku	J - Článek v odborném periodiku
http://linked.open...iv/duvernostUdaju	S - Úplné a pravdivé údaje nepodléhající ochraně podle zvláštních právních předpisů
http://linked.open...titaPredkladatele	Masarykova univerzita / Přírodovědecká fakulta
http://linked.open...dnocenehoVysledku	841742
http://linked.open...ai/riv/idVysledku	RIV/00216224:14310/95:00005900
http://linked.open...riv/jazykVysledku	eng - angličtina
http://linked.open.../riv/klicovaSlova	MOLECULAR-STRUCTURE, CRYSTAL-STRUCTURE, REACTIVITY, ACID (en)
http://linked.open.../riv/klicoveSlovo	ACID CRYSTAL-STRUCTURE MOLECULAR-STRUCTURE REACTIVITY
http://linked.open...odStatuVydavatele	GB - Spojené království Velké Británie a Severního Irska
http://linked.open...ontrolniKodProRIV	[EE4C5F11A139]
http://linked.open...i/riv/nazevZdroje	J. Chem. Soc.,Dalton Trans., 1607 (1995).
http://linked.open...in/vavai/riv/obor	CA
http://linked.open...ichTvurcuVysledku	1 (xsd:int)
http://linked.open...cetTvurcuVysledku	6 (xsd:int)
http://linked.open...ocetUcastnikuAkce	0 (xsd:int)
http://linked.open...nichUcastnikuAkce	0 (xsd:int)
http://linked.open...UplatneniVysledku	1995
http://linked.open...v/svazekPeriodika	1995
http://linked.open...iv/tvurceVysledku	Phillips, J. Novosad, Josef Bhattacharyya, P. Slawin, A. M. Z. Williams, D. J. Woollins, J. D.
http://linked.open...n/vavai/riv/zamer	http://linked.opendata.cz/resource/domain/vavai/zamer/MSM%20143100011
issn	0300-9246
number of pages	7 (xsd:int)
http://localhost/t...ganizacniJednotka	14310

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