About: Arsenic-Rich Acid Mine Water with Extreme Arsenic Concentration: Mineralogy, Geochemistry, Microbiology, and Environmental Implications     Goto   Sponge   NotDistinct   Permalink

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  • Extremely arsenic-rich acid mine waters have developed by weathering of native arsenic in a sulfide-poor environment on the 10th level of the Svornost mine in Jachymov (Czech Republic). Arsenic rapidly oxidizes to arsenolite (As2O3), and there are droplets of liquid on the arsenolite crust with high As concentration (80,000-130,000 mg.L-1), pH close to 0, and density of 1.65 g.cm(-1). According to the X-ray absorption spectroscopy on the frozen droplets, most of the arsenic is As(III) and iron is fully oxidized to Fe(III). The EXAFS spectra on the As K edge can be interpreted in terms of arsenic polymerization in the aqueous solution. The secondary mineral that precipitates in the droplets is kaatialaite [Fe3+(H2AsO4)(3).5H(2)O]. Other unusual minerals associated with the arsenic lens are behounekite [U4+(SO4)(2).4H(2)O], stepite [U4+(AsO3OH)(2).4H(2)O], vysokyite [U4+[AsO2(OH)(2)](4).4H(2)O], and an unnamed phase (H3O)(+)(2)(UO2)(2)(AsO4)(2).nH(2)O.
  • Extremely arsenic-rich acid mine waters have developed by weathering of native arsenic in a sulfide-poor environment on the 10th level of the Svornost mine in Jachymov (Czech Republic). Arsenic rapidly oxidizes to arsenolite (As2O3), and there are droplets of liquid on the arsenolite crust with high As concentration (80,000-130,000 mg.L-1), pH close to 0, and density of 1.65 g.cm(-1). According to the X-ray absorption spectroscopy on the frozen droplets, most of the arsenic is As(III) and iron is fully oxidized to Fe(III). The EXAFS spectra on the As K edge can be interpreted in terms of arsenic polymerization in the aqueous solution. The secondary mineral that precipitates in the droplets is kaatialaite [Fe3+(H2AsO4)(3).5H(2)O]. Other unusual minerals associated with the arsenic lens are behounekite [U4+(SO4)(2).4H(2)O], stepite [U4+(AsO3OH)(2).4H(2)O], vysokyite [U4+[AsO2(OH)(2)](4).4H(2)O], and an unnamed phase (H3O)(+)(2)(UO2)(2)(AsO4)(2).nH(2)O. (en)
Title
  • Arsenic-Rich Acid Mine Water with Extreme Arsenic Concentration: Mineralogy, Geochemistry, Microbiology, and Environmental Implications
  • Arsenic-Rich Acid Mine Water with Extreme Arsenic Concentration: Mineralogy, Geochemistry, Microbiology, and Environmental Implications (en)
skos:prefLabel
  • Arsenic-Rich Acid Mine Water with Extreme Arsenic Concentration: Mineralogy, Geochemistry, Microbiology, and Environmental Implications
  • Arsenic-Rich Acid Mine Water with Extreme Arsenic Concentration: Mineralogy, Geochemistry, Microbiology, and Environmental Implications (en)
skos:notation
  • RIV/00216224:14310/14:00079322!RIV15-MSM-14310___
http://linked.open...avai/riv/aktivita
http://linked.open...avai/riv/aktivity
  • I, P(GP13-31276P), S
http://linked.open...iv/cisloPeriodika
  • 23
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  • 4120
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  • RIV/00216224:14310/14:00079322
http://linked.open...riv/jazykVysledku
http://linked.open.../riv/klicovaSlova
  • IRON MOUNTAIN; NATIONAL-PARK; NEGATIVE PH; NEW-ZEALAND; WELL-WATER; DRAINAGE; COMMUNITIES; CONTAMINATION; CALIFORNIA; OXIDATION (en)
http://linked.open.../riv/klicoveSlovo
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  • US - Spojené státy americké
http://linked.open...ontrolniKodProRIV
  • [668DD5357BD2]
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  • ENVIRONMENTAL SCIENCE & TECHNOLOGY
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  • 48
http://linked.open...iv/tvurceVysledku
  • Plášil, Jakub
  • Škoda, Radek
  • Majzlan, Juraj
  • Gescher, Johannes
  • Kogler, Felix
  • Kusel, Kristen
  • Mangold, Stefan
  • Neu, Thomas R
  • Rothe, Joerg
  • Rusznyak, Anna
http://linked.open...ain/vavai/riv/wos
  • 000345803800016
issn
  • 0013-936X
number of pages
http://bibframe.org/vocab/doi
  • 10.1021/es5024916
http://localhost/t...ganizacniJednotka
  • 14310
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