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  • Polycyclic aromatic hydrocarbons (PAHs) are of considerable concern due to their well-recognised toxicity and especially due to the carcinogenic hazard which they present. PAHs are semi-volatile and therefore partition between vapour and condensed phases in the atmosphere and both the vapour and particulate forms undergo chemical reactions. This article briefly reviews the current understanding of vapour-particle partitioning of PAHs and the PAH deposition processes, and in greater detail, their chemical reactions. PAHs are reactive towards a number of atmospheric oxidants, most notably the hydroxyl radical, ozone, the nitrate radical (NO3) and nitrogen dioxide. Rate coefficient data are reviewed for reactions of lower molecular weight PAH vapour with these species as well as for heterogeneous reactions of higher molecular weight compounds.
  • Polycyclic aromatic hydrocarbons (PAHs) are of considerable concern due to their well-recognised toxicity and especially due to the carcinogenic hazard which they present. PAHs are semi-volatile and therefore partition between vapour and condensed phases in the atmosphere and both the vapour and particulate forms undergo chemical reactions. This article briefly reviews the current understanding of vapour-particle partitioning of PAHs and the PAH deposition processes, and in greater detail, their chemical reactions. PAHs are reactive towards a number of atmospheric oxidants, most notably the hydroxyl radical, ozone, the nitrate radical (NO3) and nitrogen dioxide. Rate coefficient data are reviewed for reactions of lower molecular weight PAH vapour with these species as well as for heterogeneous reactions of higher molecular weight compounds. (en)
Title
  • Chemical reactivity and long-range transport potential of polycyclic aromatic hydrocarbons - a review
  • Chemical reactivity and long-range transport potential of polycyclic aromatic hydrocarbons - a review (en)
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  • Chemical reactivity and long-range transport potential of polycyclic aromatic hydrocarbons - a review
  • Chemical reactivity and long-range transport potential of polycyclic aromatic hydrocarbons - a review (en)
skos:notation
  • RIV/00216224:14310/13:00071064!RIV14-MSM-14310___
http://linked.open...avai/riv/aktivita
http://linked.open...avai/riv/aktivity
  • P(ED0001/01/01), P(EE2.3.20.0053), P(LM2011028)
http://linked.open...iv/cisloPeriodika
  • 24
http://linked.open...vai/riv/dodaniDat
http://linked.open...aciTvurceVysledku
  • Lammel, Gerhard
http://linked.open.../riv/druhVysledku
http://linked.open...iv/duvernostUdaju
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http://linked.open...dnocenehoVysledku
  • 65222
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  • RIV/00216224:14310/13:00071064
http://linked.open...riv/jazykVysledku
http://linked.open.../riv/klicovaSlova
  • GAS-PHASE REACTIONS; LIQUID-CHROMATOGRAPHY; SEMIVOLATILE ORGANIC-COMPOUNDS; SIMULATED ATMOSPHERIC CONDITIONS; AIRBORNE PARTICULATE MATTER; RADICAL-INITIATED REACTIONS; MS; PCBS; CONTINENTAL BOUNDARY-LAYER (en)
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  • GB - Spojené království Velké Británie a Severního Irska
http://linked.open...ontrolniKodProRIV
  • [D765D092413D]
http://linked.open...i/riv/nazevZdroje
  • Chemical Society Reviews
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http://linked.open...v/svazekPeriodika
  • 42
http://linked.open...iv/tvurceVysledku
  • Lammel, Gerhard
  • Harrison, R. M.
  • Keyte, I. J.
http://linked.open...ain/vavai/riv/wos
  • 000327260500009
issn
  • 0306-0012
number of pages
http://bibframe.org/vocab/doi
  • 10.1039/c3cs60147a
http://localhost/t...ganizacniJednotka
  • 14310
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