About: A New Method of Apparent Protonation Constant Evaluation from Voltammetric Data     Goto   Sponge   NotDistinct   Permalink

An Entity of Type : http://linked.opendata.cz/ontology/domain/vavai/Vysledek, within Data Space : linked.opendata.cz associated with source document(s)

AttributesValues
rdf:type
Description
  • In general, the determination of apparent protonation constants of organic electroactive substances from polarographic and voltammetric data is based on the dependence of peak potential (Ep) on pH. Then the pKa value is given as an intersection of two lines characterizing a different shift Ep of protonated and unprotonated particles on pH. Due to the fact that both slopes of these lines usually are not very different, the exact assessment of the intersection is problematic. Our new proposed method, which is able to determine pKa values from the Rp (peak resistance) depending on pH, eliminates this drawback.
  • In general, the determination of apparent protonation constants of organic electroactive substances from polarographic and voltammetric data is based on the dependence of peak potential (Ep) on pH. Then the pKa value is given as an intersection of two lines characterizing a different shift Ep of protonated and unprotonated particles on pH. Due to the fact that both slopes of these lines usually are not very different, the exact assessment of the intersection is problematic. Our new proposed method, which is able to determine pKa values from the Rp (peak resistance) depending on pH, eliminates this drawback. (en)
Title
  • A New Method of Apparent Protonation Constant Evaluation from Voltammetric Data
  • A New Method of Apparent Protonation Constant Evaluation from Voltammetric Data (en)
skos:prefLabel
  • A New Method of Apparent Protonation Constant Evaluation from Voltammetric Data
  • A New Method of Apparent Protonation Constant Evaluation from Voltammetric Data (en)
skos:notation
  • RIV/00216224:14310/13:00068495!RIV14-MSM-14310___
http://linked.open...avai/riv/aktivita
http://linked.open...avai/riv/aktivity
  • S
http://linked.open...vai/riv/dodaniDat
http://linked.open...aciTvurceVysledku
http://linked.open.../riv/druhVysledku
http://linked.open...iv/duvernostUdaju
http://linked.open...titaPredkladatele
http://linked.open...dnocenehoVysledku
  • 58823
http://linked.open...ai/riv/idVysledku
  • RIV/00216224:14310/13:00068495
http://linked.open...riv/jazykVysledku
http://linked.open.../riv/klicovaSlova
  • Electrochemical determination of pKa; linear sweep voltammetry; elimination voltammetry; adenine (en)
http://linked.open.../riv/klicoveSlovo
http://linked.open...ontrolniKodProRIV
  • [18D6D017D229]
http://linked.open...v/mistoKonaniAkce
  • Jetřichovice
http://linked.open...i/riv/mistoVydani
  • Ústí nad Labem
http://linked.open...i/riv/nazevZdroje
  • XXXIII.Moderní elektrochemické metody, sborník přednášek
http://linked.open...in/vavai/riv/obor
http://linked.open...ichTvurcuVysledku
http://linked.open...cetTvurcuVysledku
http://linked.open...UplatneniVysledku
http://linked.open...iv/tvurceVysledku
  • Trnková, Libuše
  • Pilařová, Iveta
  • Serrano, Núria
http://linked.open...vavai/riv/typAkce
http://linked.open.../riv/zahajeniAkce
number of pages
http://purl.org/ne...btex#hasPublisher
  • Srsenová Lenka - Best servis Ústí nad Labem
https://schema.org/isbn
  • 9788090522114
http://localhost/t...ganizacniJednotka
  • 14310
Faceted Search & Find service v1.16.118 as of Jun 21 2024


Alternative Linked Data Documents: ODE     Content Formats:   [cxml] [csv]     RDF   [text] [turtle] [ld+json] [rdf+json] [rdf+xml]     ODATA   [atom+xml] [odata+json]     Microdata   [microdata+json] [html]    About   
This material is Open Knowledge   W3C Semantic Web Technology [RDF Data] Valid XHTML + RDFa
OpenLink Virtuoso version 07.20.3240 as of Jun 21 2024, on Linux (x86_64-pc-linux-gnu), Single-Server Edition (126 GB total memory, 58 GB memory in use)
Data on this page belongs to its respective rights holders.
Virtuoso Faceted Browser Copyright © 2009-2024 OpenLink Software