About: Fluorescein Analogues as Photoremovable Protecting Groups Absorbing at 520 nm     Goto   Sponge   NotDistinct   Permalink

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Description
  • A new photoremovable protecting group, (6-hydroxy-3-oxo-3H-xanthen-9-yl)methyl (1), with a molar absorption coefficient epsilon of 4 x 104 m–1 cm–1 at 520 nm for the release of carboxylates or phosphates is reported. Three derivatives of 1 (diethyl phosphate, acetate, and bromide) were isolated as complexes with DDQ and shown to release the ligands with quantum yields 2.4% in aqueous solution.
  • A new photoremovable protecting group, (6-hydroxy-3-oxo-3H-xanthen-9-yl)methyl (1), with a molar absorption coefficient epsilon of 4 x 104 m–1 cm–1 at 520 nm for the release of carboxylates or phosphates is reported. Three derivatives of 1 (diethyl phosphate, acetate, and bromide) were isolated as complexes with DDQ and shown to release the ligands with quantum yields 2.4% in aqueous solution. (en)
Title
  • Fluorescein Analogues as Photoremovable Protecting Groups Absorbing at 520 nm
  • Fluorescein Analogues as Photoremovable Protecting Groups Absorbing at 520 nm (en)
skos:prefLabel
  • Fluorescein Analogues as Photoremovable Protecting Groups Absorbing at 520 nm
  • Fluorescein Analogues as Photoremovable Protecting Groups Absorbing at 520 nm (en)
skos:notation
  • RIV/00216224:14310/13:00066105!RIV14-MSM-14310___
http://linked.open...avai/riv/aktivita
http://linked.open...avai/riv/aktivity
  • P(ED0001/01/01), P(GA203/09/0748), P(LM2011028), S
http://linked.open...iv/cisloPeriodika
  • 5
http://linked.open...vai/riv/dodaniDat
http://linked.open...aciTvurceVysledku
http://linked.open.../riv/druhVysledku
http://linked.open...iv/duvernostUdaju
http://linked.open...titaPredkladatele
http://linked.open...dnocenehoVysledku
  • 75355
http://linked.open...ai/riv/idVysledku
  • RIV/00216224:14310/13:00066105
http://linked.open...riv/jazykVysledku
http://linked.open.../riv/klicovaSlova
  • Photochemistry; protecting groups (en)
http://linked.open.../riv/klicoveSlovo
http://linked.open...odStatuVydavatele
  • US - Spojené státy americké
http://linked.open...ontrolniKodProRIV
  • [C52151D04905]
http://linked.open...i/riv/nazevZdroje
  • Journal of Organic Chemistry
http://linked.open...in/vavai/riv/obor
http://linked.open...ichTvurcuVysledku
http://linked.open...cetTvurcuVysledku
http://linked.open...vavai/riv/projekt
http://linked.open...UplatneniVysledku
http://linked.open...v/svazekPeriodika
  • 78
http://linked.open...iv/tvurceVysledku
  • Klán, Petr
  • Müller, Pavel
  • Wirz, Jakob
  • Šebej, Peter
  • Slanina, Tomáš
  • Al Anshori, Jamaludin
  • Angel P. A., Lovely
  • Wintner, Jürgen
http://linked.open...ain/vavai/riv/wos
  • 000315707500017
issn
  • 0022-3263
number of pages
http://bibframe.org/vocab/doi
  • 10.1021/jo301455n
http://localhost/t...ganizacniJednotka
  • 14310
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