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Description
  • A water-soluble methylene-bridged glycoluril dimer 2S was isolated. It was shown that 2S is the only kinetic product of the reaction between glycoluril derivative 1 and paraformaldehyde. Compound 2S is subsequently intermolecularly transformed into its diastereomer 2C. The kinetics and thermodynamics of the S- to C-shaped dimer isomerization were investigated under reaction conditions similar to those for cucurbituril synthesis.
  • A water-soluble methylene-bridged glycoluril dimer 2S was isolated. It was shown that 2S is the only kinetic product of the reaction between glycoluril derivative 1 and paraformaldehyde. Compound 2S is subsequently intermolecularly transformed into its diastereomer 2C. The kinetics and thermodynamics of the S- to C-shaped dimer isomerization were investigated under reaction conditions similar to those for cucurbituril synthesis. (en)
Title
  • Glycoluril Dimer Isomerization under Aqueous Acidic Conditions
  • Glycoluril Dimer Isomerization under Aqueous Acidic Conditions (en)
skos:prefLabel
  • Glycoluril Dimer Isomerization under Aqueous Acidic Conditions
  • Glycoluril Dimer Isomerization under Aqueous Acidic Conditions (en)
skos:notation
  • RIV/00216224:14310/12:00062306!RIV13-MSM-14310___
http://linked.open...avai/riv/aktivita
http://linked.open...avai/riv/aktivity
  • P(ED0001/01/01)
http://linked.open...iv/cisloPeriodika
  • 23
http://linked.open...vai/riv/dodaniDat
http://linked.open...aciTvurceVysledku
http://linked.open.../riv/druhVysledku
http://linked.open...iv/duvernostUdaju
http://linked.open...titaPredkladatele
http://linked.open...dnocenehoVysledku
  • 138245
http://linked.open...ai/riv/idVysledku
  • RIV/00216224:14310/12:00062306
http://linked.open...riv/jazykVysledku
http://linked.open.../riv/klicovaSlova
  • cucurbiturils; glycolurils; isomerization; dimers (en)
http://linked.open.../riv/klicoveSlovo
http://linked.open...odStatuVydavatele
  • US - Spojené státy americké
http://linked.open...ontrolniKodProRIV
  • [B3CB424A77A6]
http://linked.open...i/riv/nazevZdroje
  • The Journal of Organic Chemistry
http://linked.open...in/vavai/riv/obor
http://linked.open...ichTvurcuVysledku
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http://linked.open...vavai/riv/projekt
http://linked.open...UplatneniVysledku
http://linked.open...v/svazekPeriodika
  • 77
http://linked.open...iv/tvurceVysledku
  • Šindelář, Vladimír
  • Štancl, Marek
  • Garguláková, Zuzana
http://linked.open...ain/vavai/riv/wos
  • 000311926100051
issn
  • 0022-3263
number of pages
http://bibframe.org/vocab/doi
  • 10.1021/jo302063j
http://localhost/t...ganizacniJednotka
  • 14310
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