About: Solution Behavior of DOTP Analogs and Their Lanthanide(III) Complexes     Goto   Sponge   NotDistinct   Permalink

An Entity of Type : http://linked.opendata.cz/ontology/domain/vavai/Vysledek, within Data Space : linked.opendata.cz associated with source document(s)

AttributesValues
rdf:type
Description
  • Complexes of trivalent lanthanides are utilized in medicine and preclinical research as magnetic resonance, optical or nuclear probes. In this contribution, thermodynamic (ligand dissociation and complex stability constants) and kinetic (formation and dissociation) properties of selected lanthanide(III) complexes with phosphorus-containing macrocyclic ligand which are based on cyclen skeleton will be presented. The ligands are H8dotp analogs where substituents modified on all parent phosphonate groups are monoester (H4dotpOEt), phosphinate (H4dotpH) or phenylphosphinate (H4dotpPh). The H8dotp analogs are less basic then the mother ligand and, consequently, the thermodynamic stabilities of the lanthanide(III) complexes are much lower. Rates of the complex formation of studied ligands are of the same order of magnitude to that for H8dotp. Kinetic inertness of complexes of the anologs is mostly lower; however, the kinetic inerteness is still much higher than that of complexes of open-chain ligands.
  • Complexes of trivalent lanthanides are utilized in medicine and preclinical research as magnetic resonance, optical or nuclear probes. In this contribution, thermodynamic (ligand dissociation and complex stability constants) and kinetic (formation and dissociation) properties of selected lanthanide(III) complexes with phosphorus-containing macrocyclic ligand which are based on cyclen skeleton will be presented. The ligands are H8dotp analogs where substituents modified on all parent phosphonate groups are monoester (H4dotpOEt), phosphinate (H4dotpH) or phenylphosphinate (H4dotpPh). The H8dotp analogs are less basic then the mother ligand and, consequently, the thermodynamic stabilities of the lanthanide(III) complexes are much lower. Rates of the complex formation of studied ligands are of the same order of magnitude to that for H8dotp. Kinetic inertness of complexes of the anologs is mostly lower; however, the kinetic inerteness is still much higher than that of complexes of open-chain ligands. (en)
Title
  • Solution Behavior of DOTP Analogs and Their Lanthanide(III) Complexes
  • Solution Behavior of DOTP Analogs and Their Lanthanide(III) Complexes (en)
skos:prefLabel
  • Solution Behavior of DOTP Analogs and Their Lanthanide(III) Complexes
  • Solution Behavior of DOTP Analogs and Their Lanthanide(III) Complexes (en)
skos:notation
  • RIV/00216224:14310/11:00054681!RIV12-MSM-14310___
http://linked.open...avai/riv/aktivita
http://linked.open...avai/riv/aktivity
  • P(ME09065), S
http://linked.open...vai/riv/dodaniDat
http://linked.open...aciTvurceVysledku
http://linked.open.../riv/druhVysledku
http://linked.open...iv/duvernostUdaju
http://linked.open...titaPredkladatele
http://linked.open...dnocenehoVysledku
  • 230523
http://linked.open...ai/riv/idVysledku
  • RIV/00216224:14310/11:00054681
http://linked.open...riv/jazykVysledku
http://linked.open.../riv/klicovaSlova
  • Macrocyclic Ligandsů thermodynamics; kinetics; Ln(III) ions (en)
http://linked.open.../riv/klicoveSlovo
http://linked.open...ontrolniKodProRIV
  • [C8CF0C251D09]
http://linked.open...in/vavai/riv/obor
http://linked.open...ichTvurcuVysledku
http://linked.open...cetTvurcuVysledku
http://linked.open...vavai/riv/projekt
http://linked.open...UplatneniVysledku
http://linked.open...iv/tvurceVysledku
  • Kotek, Jan
  • Lubal, Přemysl
  • Vaněk, Jakub
  • Kotková, Zuzana
  • Ševčík, Radek
http://localhost/t...ganizacniJednotka
  • 14310
Faceted Search & Find service v1.16.118 as of Jun 21 2024


Alternative Linked Data Documents: ODE     Content Formats:   [cxml] [csv]     RDF   [text] [turtle] [ld+json] [rdf+json] [rdf+xml]     ODATA   [atom+xml] [odata+json]     Microdata   [microdata+json] [html]    About   
This material is Open Knowledge   W3C Semantic Web Technology [RDF Data] Valid XHTML + RDFa
OpenLink Virtuoso version 07.20.3240 as of Jun 21 2024, on Linux (x86_64-pc-linux-gnu), Single-Server Edition (126 GB total memory, 48 GB memory in use)
Data on this page belongs to its respective rights holders.
Virtuoso Faceted Browser Copyright © 2009-2024 OpenLink Software