About: Convenient Synthesis of Substituted Aryl Cyanides and 1,1-Dicyanobenzyl Benzoate     Goto   Sponge   NotDistinct   Permalink

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  • This paper demonstrates that a sophistic approach can be very effective and simple method for Green Chemistry. Sophistic approach is shown on examples of preparation of two different pure products from the very same kit of reagents, i. e. for reaction of cyanide anion with 2,4-dichlorobenzyl chloride and benzoyl chloride, respectively. An application of suitable reaction conditions provide for reactions of 2,4-dichlorobenzyl chloride both 2,4-dichlorobenzyl cyanide and 2,3-bis(2,4-dichlorophenyl)propanenitrile, for benzoyl chloride reaction produce benzoyl cyanide and benzoyloxy-phenylmalonodinitrile, respectively.
  • This paper demonstrates that a sophistic approach can be very effective and simple method for Green Chemistry. Sophistic approach is shown on examples of preparation of two different pure products from the very same kit of reagents, i. e. for reaction of cyanide anion with 2,4-dichlorobenzyl chloride and benzoyl chloride, respectively. An application of suitable reaction conditions provide for reactions of 2,4-dichlorobenzyl chloride both 2,4-dichlorobenzyl cyanide and 2,3-bis(2,4-dichlorophenyl)propanenitrile, for benzoyl chloride reaction produce benzoyl cyanide and benzoyloxy-phenylmalonodinitrile, respectively. (en)
Title
  • Convenient Synthesis of Substituted Aryl Cyanides and 1,1-Dicyanobenzyl Benzoate
  • Convenient Synthesis of Substituted Aryl Cyanides and 1,1-Dicyanobenzyl Benzoate (en)
skos:prefLabel
  • Convenient Synthesis of Substituted Aryl Cyanides and 1,1-Dicyanobenzyl Benzoate
  • Convenient Synthesis of Substituted Aryl Cyanides and 1,1-Dicyanobenzyl Benzoate (en)
skos:notation
  • RIV/00216224:14310/11:00050722!RIV12-MPO-14310___
http://linked.open...avai/riv/aktivita
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  • P(2A-1TP1/090)
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  • 3
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  • 191954
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  • RIV/00216224:14310/11:00050722
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  • NITRILES; CATALYST; PHASE (en)
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  • US - Spojené státy americké
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  • [35C805BD40E1]
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  • ORGANIC PREPARATIONS AND PROCEDURES INTERNATIONAL
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  • 43
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  • Dlouhý, Milan
  • Pazdera, Pavel
  • Šimbera, Jan
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  • 000291536300003
issn
  • 0030-4948
number of pages
http://bibframe.org/vocab/doi
  • 10.1080/00304948.2011.582000
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  • 14310
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