About: Synthesis and structure of lanthanide complexes with large-bite diphosphine dioxide ligands

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About: Synthesis and structure of lanthanide complexes with large-bite diphosphine dioxide ligands Goto Sponge NotDistinct Permalink

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Attributes	Values
rdf:type	skos:Concept http://linked.opendata.cz/ontology/domain/vavai/Vysledek
rdfs:seeAlso	http://dx.doi.org/10.1016/j.poly.2011.03.027
Description	Three large-bite diphosphine dioxide ligands were reacted with lanthanide salts to yield either molecular or polymeric complexes. The two flexible ligands gave bischelate complexes of general formulae [Ln(dppfO2)2Clx(NO3)2-x][FeCl4] and [Ln(dppdO2)2(NO3)2]NO3, where dppfO2 and dppdO2 are bis(diphenylphosphoryl) ferrocene and bis(diphenylphosphoryl)diphenyl ether, respectively. Reactions of the rigid bis(diphenylphosphoryl)benzene (dppbO2) with lanthanide salts yielded linear coordination polymers of a 1:1.5 metal-to-ligand stoichiometry. The compounds were studied by single crystal X-ray diffraction, IR spectroscopy, mass spectrometry, and TG/DSC techniques. Three large-bite diphosphine dioxide ligands were reacted with lanthanide salts to yield either molecular or polymeric complexes. The two flexible ligands gave bischelate complexes of general formulae [Ln(dppfO2)2Clx(NO3)2-x][FeCl4] and [Ln(dppdO2)2(NO3)2]NO3, where dppfO2 and dppdO2 are bis(diphenylphosphoryl) ferrocene and bis(diphenylphosphoryl)diphenyl ether, respectively. Reactions of the rigid bis(diphenylphosphoryl)benzene (dppbO2) with lanthanide salts yielded linear coordination polymers of a 1:1.5 metal-to-ligand stoichiometry. The compounds were studied by single crystal X-ray diffraction, IR spectroscopy, mass spectrometry, and TG/DSC techniques. (en)
Title	Synthesis and structure of lanthanide complexes with large-bite diphosphine dioxide ligands Synthesis and structure of lanthanide complexes with large-bite diphosphine dioxide ligands (en)
skos:prefLabel	Synthesis and structure of lanthanide complexes with large-bite diphosphine dioxide ligands Synthesis and structure of lanthanide complexes with large-bite diphosphine dioxide ligands (en)
skos:notation	RIV/00216224:14310/11:00049772!RIV12-GA0-14310___
http://linked.open...avai/riv/aktivita	P Z
http://linked.open...avai/riv/aktivity	P(GA203/08/1111), Z(MSM0021622410)
http://linked.open...iv/cisloPeriodika	9
http://linked.open...vai/riv/dodaniDat	2012
http://linked.open...aciTvurceVysledku	Nečas, Marek Pinkas, Jiří Moravec, Zdeněk Spíchal, Zdeněk Vrbková, Blanka
http://linked.open.../riv/druhVysledku	J - Článek v odborném periodiku
http://linked.open...iv/duvernostUdaju	S - Úplné a pravdivé údaje nepodléhající ochraně podle zvláštních právních předpisů
http://linked.open...titaPredkladatele	Masarykova univerzita / Přírodovědecká fakulta
http://linked.open...dnocenehoVysledku	233888
http://linked.open...ai/riv/idVysledku	RIV/00216224:14310/11:00049772
http://linked.open...riv/jazykVysledku	eng - angličtina
http://linked.open.../riv/klicovaSlova	Diphosphine dioxide; Lanthanides; Coordination polymers; Chelates; X-ray crystallography (en)
http://linked.open.../riv/klicoveSlovo	X-ray crystallography Chelates Coordination polymers Diphosphine dioxide Lanthanides
http://linked.open...odStatuVydavatele	GB - Spojené království Velké Británie a Severního Irska
http://linked.open...ontrolniKodProRIV	[803A90075079]
http://linked.open...i/riv/nazevZdroje	Polyhedron
http://linked.open...in/vavai/riv/obor	CA
http://linked.open...ichTvurcuVysledku	5 (xsd:int)
http://linked.open...cetTvurcuVysledku	5 (xsd:int)
http://linked.open...vavai/riv/projekt	Synthesis and properties of inorganic-organic polymeric materials
http://linked.open...UplatneniVysledku	2011
http://linked.open...v/svazekPeriodika	30
http://linked.open...iv/tvurceVysledku	Moravec, Zdeněk Nečas, Marek Pinkas, Jiří Spíchal, Zdeněk Vrbková, Blanka
http://linked.open...n/vavai/riv/zamer	Physical and chemical properties of advanced materials and structures
issn	0277-5387
number of pages	8 (xsd:int)
http://localhost/t...ganizacniJednotka	14310

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