About: Time-resolved luminescence spectroscopy as a tool for study of reaction mechanisms

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rdf:type	skos:Concept http://linked.opendata.cz/ontology/domain/vavai/Vysledek
Description	Ln(III) complexes of macrocyclic ligand H4dota and its derivatives are utilized in many areas of medicinal chemistry. Crucial factor for MRI and luminescence probes is determination of the number of the water molecules coordinated to Ln(III) complex, then its thermodynamic stability and kinetic inertness of the complexes. Time-resolved luminescence spectroscopy of Eu(III) ion and its complexes with macrocyclic DOTA-like ligands as model Ln(III) complexes in solutions for measurement of luminescence decay is used for the determination of the number of water molecules in the first coordination sphere. This measurement can be used for estimation of the number of coordinated water molecules in the course of Eu(III) complexation by ligands or Eu(III) complex dissociation in order to propose its reaction mechanism. The achieved results can be utilized for optimization of ligand structure for Ln(III) fast complexation/slow decomplexation. Ln(III) complexes of macrocyclic ligand H4dota and its derivatives are utilized in many areas of medicinal chemistry. Crucial factor for MRI and luminescence probes is determination of the number of the water molecules coordinated to Ln(III) complex, then its thermodynamic stability and kinetic inertness of the complexes. Time-resolved luminescence spectroscopy of Eu(III) ion and its complexes with macrocyclic DOTA-like ligands as model Ln(III) complexes in solutions for measurement of luminescence decay is used for the determination of the number of water molecules in the first coordination sphere. This measurement can be used for estimation of the number of coordinated water molecules in the course of Eu(III) complexation by ligands or Eu(III) complex dissociation in order to propose its reaction mechanism. The achieved results can be utilized for optimization of ligand structure for Ln(III) fast complexation/slow decomplexation. (en)
Title	Time-resolved luminescence spectroscopy as a tool for study of reaction mechanisms Time-resolved luminescence spectroscopy as a tool for study of reaction mechanisms (en)
skos:prefLabel	Time-resolved luminescence spectroscopy as a tool for study of reaction mechanisms Time-resolved luminescence spectroscopy as a tool for study of reaction mechanisms (en)
skos:notation	RIV/00216224:14310/10:00046189!RIV11-MSM-14310___
http://linked.open...avai/riv/aktivita	P
http://linked.open...avai/riv/aktivity	P(LC06035), P(ME09065), P(OC 179)
http://linked.open...vai/riv/dodaniDat	2011
http://linked.open...aciTvurceVysledku	Vaněk, Jakub Hermann, Petr Lubal, Přemysl Táborský, Petr
http://linked.open.../riv/druhVysledku	D - Článek ve sborníku
http://linked.open...iv/duvernostUdaju	S - Úplné a pravdivé údaje nepodléhající ochraně podle zvláštních právních předpisů
http://linked.open...titaPredkladatele	Masarykova univerzita / Přírodovědecká fakulta
http://linked.open...dnocenehoVysledku	292937
http://linked.open...ai/riv/idVysledku	RIV/00216224:14310/10:00046189
http://linked.open...riv/jazykVysledku	eng - angličtina
http://linked.open.../riv/klicovaSlova	time-resolved luminescence spectroscopy; lanthanide(III) complexes; macrocyclic ligands; kinetics; reaction mechanism (en)
http://linked.open.../riv/klicoveSlovo	time-resolved luminescence spectroscopy kinetics lanthanide(III) complexes macrocyclic ligands reaction mechanism
http://linked.open...ontrolniKodProRIV	[7EC3119B231A]
http://linked.open...v/mistoKonaniAkce	Praha
http://linked.open...i/riv/mistoVydani	Praha
http://linked.open...i/riv/nazevZdroje	Abstract Book of XIV. International Symposium on Luminescence Spectrometry
http://linked.open...in/vavai/riv/obor	CB
http://linked.open...ichTvurcuVysledku	4 (xsd:int)
http://linked.open...cetTvurcuVysledku	4 (xsd:int)
http://linked.open...vavai/riv/projekt	Centre of Biophysical Chemistry, Bioelectrochemistry and Bioanalysis. New Tools for Genomics, Proteomics and Biomedicine. Research of new detection systems based on sensor arrays for application in speciation analysis http://linked.opendata.cz/resource/domain/vavai/projekt/OC%20179
http://linked.open...UplatneniVysledku	2010
http://linked.open...iv/tvurceVysledku	Hermann, Petr Lubal, Přemysl Vaněk, Jakub Táborský, Petr
http://linked.open...vavai/riv/typAkce	WRD - Světová
http://linked.open.../riv/zahajeniAkce	2010-07-13 (xsd:date)
number of pages	216 (xsd:int)
http://purl.org/ne...btex#hasPublisher	Faculty of Pharmacy, Charles University, Prague
https://schema.org/isbn	978-80-254-6830-2
http://localhost/t...ganizacniJednotka	14310

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