About: A new route to the syntheses of N-(fluorosulfuryl)sulfonamide salts: Crystal structure of Ph4P+ [CF3SO2NSO2F]-     Goto   Sponge   NotDistinct   Permalink

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Description
  • A new route for the preparation of potassium and tetraphenylphosphonium salts of N-(fluorosulfuryl)trifluoromethane sulfonamide is described. N-(chlorosulfuryl)-trifluoromethane sulfonamide CF3SO2NH SO2Cl, that was used for preparations of both salts, was prepared by the reaction of trifluoromethane sulfonamide CF3SO2NH2 and chlorosulfonic acid in the presence of SOCl2. The obtained N-(chlorosulfuryl)trifluoromethane sulfonamide was converted to potassium N-(fluorosulfuryl)trifluoromethane sulfonamide by using anhydrous KF. Potassium N-(fluorosulfuryl)trifluoromethane sulfonamide served as a starting material for the preparation of the corresponding tetraphenylphosphonium N-(fluorosulfuryl)trifluoromethane sulfonamide that crystallizes from the aqueous solution of potassium N-(fluorosulfuryl)trifluoromethane sulfonamide and tetraphenylphosphonium chloride. N-(fluorosulfuryl)trifluoromethane sulfonamide tetraphenylphosphonium salt is tetragonal, space group P-4.
  • A new route for the preparation of potassium and tetraphenylphosphonium salts of N-(fluorosulfuryl)trifluoromethane sulfonamide is described. N-(chlorosulfuryl)-trifluoromethane sulfonamide CF3SO2NH SO2Cl, that was used for preparations of both salts, was prepared by the reaction of trifluoromethane sulfonamide CF3SO2NH2 and chlorosulfonic acid in the presence of SOCl2. The obtained N-(chlorosulfuryl)trifluoromethane sulfonamide was converted to potassium N-(fluorosulfuryl)trifluoromethane sulfonamide by using anhydrous KF. Potassium N-(fluorosulfuryl)trifluoromethane sulfonamide served as a starting material for the preparation of the corresponding tetraphenylphosphonium N-(fluorosulfuryl)trifluoromethane sulfonamide that crystallizes from the aqueous solution of potassium N-(fluorosulfuryl)trifluoromethane sulfonamide and tetraphenylphosphonium chloride. N-(fluorosulfuryl)trifluoromethane sulfonamide tetraphenylphosphonium salt is tetragonal, space group P-4. (en)
Title
  • A new route to the syntheses of N-(fluorosulfuryl)sulfonamide salts: Crystal structure of Ph4P+ [CF3SO2NSO2F]-
  • A new route to the syntheses of N-(fluorosulfuryl)sulfonamide salts: Crystal structure of Ph4P+ [CF3SO2NSO2F]- (en)
skos:prefLabel
  • A new route to the syntheses of N-(fluorosulfuryl)sulfonamide salts: Crystal structure of Ph4P+ [CF3SO2NSO2F]-
  • A new route to the syntheses of N-(fluorosulfuryl)sulfonamide salts: Crystal structure of Ph4P+ [CF3SO2NSO2F]- (en)
skos:notation
  • RIV/00216224:14310/10:00043279!RIV13-MSM-14310___
http://linked.open...avai/riv/aktivita
http://linked.open...avai/riv/aktivity
  • Z(AV0Z40310501), Z(MSM 143100011)
http://linked.open...iv/cisloPeriodika
  • 29
http://linked.open...vai/riv/dodaniDat
http://linked.open...aciTvurceVysledku
http://linked.open.../riv/druhVysledku
http://linked.open...iv/duvernostUdaju
http://linked.open...titaPredkladatele
http://linked.open...dnocenehoVysledku
  • 244764
http://linked.open...ai/riv/idVysledku
  • RIV/00216224:14310/10:00043279
http://linked.open...riv/jazykVysledku
http://linked.open.../riv/klicovaSlova
  • N-(fluorosulfuryl) sulfonamides N-(fluorosulfuryl)trifluoromethane sulfonamide N-(chlorosulfuryl)trifluoromethane sulfonamide (en)
http://linked.open.../riv/klicoveSlovo
http://linked.open...odStatuVydavatele
  • CZ - Česká republika
http://linked.open...ontrolniKodProRIV
  • [A1277C35973E]
http://linked.open...i/riv/nazevZdroje
  • Polyhedron
http://linked.open...in/vavai/riv/obor
http://linked.open...ichTvurcuVysledku
http://linked.open...cetTvurcuVysledku
http://linked.open...UplatneniVysledku
http://linked.open...v/svazekPeriodika
  • 2010
http://linked.open...iv/tvurceVysledku
  • Beran, Martin
  • Příhoda, Jiří
  • Taraba, Jan
http://linked.open...ain/vavai/riv/wos
  • 000275640700006
http://linked.open...n/vavai/riv/zamer
issn
  • 0277-5387
number of pages
http://bibframe.org/vocab/doi
  • 10.1016/j.poly.2009.11.024
http://localhost/t...ganizacniJednotka
  • 14310
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