About: Combined Contactless Conductometric, Photometric and Fluorimetric Single Point Detector for Capillary Separation Methods     Goto   Sponge   NotDistinct   Permalink

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Description
  • This work for the first time combines three on-capillary detection methods, namely capacitively coupled contactless conductometric (C4D), photometric (PD) and fluorimetric (FD), in a single (identical) point of detection cell, allowing concurrent measurements at a single point of detection for use in capillary electrophoresis, capillary electrochromatography and capillary/nano-liquid chromatography. The novel design is based on a standard 6.3 mm i.d. fiber-optic SMA adapter with a drilled opening for the separation capillary to go through, to which two concentrically positioned C4D detection electrodes with a detection gap of 7 mm were added on its each side acting simultaneously as capillary guides. The optical fibers in the SMA adapter were used for the photometric signal (absorbance) and another optical fiber at a 45 degree angle to the capillary was applied to collect the emitted light for FD. Light emitting diodes (255 nm and 470 nm) were used as light sources for the PD and FD detection modes.
  • This work for the first time combines three on-capillary detection methods, namely capacitively coupled contactless conductometric (C4D), photometric (PD) and fluorimetric (FD), in a single (identical) point of detection cell, allowing concurrent measurements at a single point of detection for use in capillary electrophoresis, capillary electrochromatography and capillary/nano-liquid chromatography. The novel design is based on a standard 6.3 mm i.d. fiber-optic SMA adapter with a drilled opening for the separation capillary to go through, to which two concentrically positioned C4D detection electrodes with a detection gap of 7 mm were added on its each side acting simultaneously as capillary guides. The optical fibers in the SMA adapter were used for the photometric signal (absorbance) and another optical fiber at a 45 degree angle to the capillary was applied to collect the emitted light for FD. Light emitting diodes (255 nm and 470 nm) were used as light sources for the PD and FD detection modes. (en)
Title
  • Combined Contactless Conductometric, Photometric and Fluorimetric Single Point Detector for Capillary Separation Methods
  • Combined Contactless Conductometric, Photometric and Fluorimetric Single Point Detector for Capillary Separation Methods (en)
skos:prefLabel
  • Combined Contactless Conductometric, Photometric and Fluorimetric Single Point Detector for Capillary Separation Methods
  • Combined Contactless Conductometric, Photometric and Fluorimetric Single Point Detector for Capillary Separation Methods (en)
skos:notation
  • RIV/00216224:14310/10:00042881!RIV13-GA0-14310___
http://linked.open...avai/riv/aktivita
http://linked.open...avai/riv/aktivity
  • P(GA203/09/1025), P(LC06023), S, Z(AV0Z40310501), Z(MSM0021622415)
http://linked.open...iv/cisloPeriodika
  • 1
http://linked.open...vai/riv/dodaniDat
http://linked.open...aciTvurceVysledku
http://linked.open.../riv/druhVysledku
http://linked.open...iv/duvernostUdaju
http://linked.open...titaPredkladatele
http://linked.open...dnocenehoVysledku
  • 251208
http://linked.open...ai/riv/idVysledku
  • RIV/00216224:14310/10:00042881
http://linked.open...riv/jazykVysledku
http://linked.open.../riv/klicovaSlova
  • detection; capillary separation methods; combined detector; photometric detection; fluorimetric detection; C4D (en)
http://linked.open.../riv/klicoveSlovo
http://linked.open...odStatuVydavatele
  • US - Spojené státy americké
http://linked.open...ontrolniKodProRIV
  • [82F69C29BA79]
http://linked.open...i/riv/nazevZdroje
  • Analytical Chemistry
http://linked.open...in/vavai/riv/obor
http://linked.open...ichTvurcuVysledku
http://linked.open...cetTvurcuVysledku
http://linked.open...vavai/riv/projekt
http://linked.open...UplatneniVysledku
http://linked.open...v/svazekPeriodika
  • 82
http://linked.open...iv/tvurceVysledku
  • Foret, František
  • Preisler, Jan
  • Ryvolová, Markéta
  • Paull, Brett
  • Krásenský, Pavel
  • Macka, Mirek
  • Hauser, Peter
http://linked.open...ain/vavai/riv/wos
  • 000273265700027
http://linked.open...n/vavai/riv/zamer
issn
  • 0003-2700
number of pages
http://localhost/t...ganizacniJednotka
  • 14310
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