About: Voltammetric Study of Adenine Complex with Copper on Mercury Electrode

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An Entity of Type : http://linked.opendata.cz/ontology/domain/vavai/Vysledek, within Data Space : linked.opendata.cz associated with source document(s)

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rdf:type	skos:Concept http://linked.opendata.cz/ontology/domain/vavai/Vysledek
Description	The determination of adenine (Ade), adenosine (Ado) and hydrolyzed adenosine (h-Ado) in the presence of copper(II) ions is described by cyclic (CV) and elimination voltammetry with linear scan (EVLS) in connection with adsorptive stripping technique. Signals of adenine and copper-adenine complex were measured on a hanging mercury drop electrode (HMDE) in buffered solutions with different pH. The differences in electrochemical behavior of Ad,and Ado were found not only in dependence on the presence of copper ions, scan rate, Ade concentration and pH, but also on the accumulation time and potential where a copper-Ade complex is formed. A deeper evaluation of voltammetric responses was carried out by EVLS. The EVLS function E4 eliminating charging and kinetic current components and conserving the diffusion current component was capable of enhancing the current sensitivity of CV peaks and of detecting electron transfer in adsorbed state. The determination of adenine (Ade), adenosine (Ado) and hydrolyzed adenosine (h-Ado) in the presence of copper(II) ions is described by cyclic (CV) and elimination voltammetry with linear scan (EVLS) in connection with adsorptive stripping technique. Signals of adenine and copper-adenine complex were measured on a hanging mercury drop electrode (HMDE) in buffered solutions with different pH. The differences in electrochemical behavior of Ad,and Ado were found not only in dependence on the presence of copper ions, scan rate, Ade concentration and pH, but also on the accumulation time and potential where a copper-Ade complex is formed. A deeper evaluation of voltammetric responses was carried out by EVLS. The EVLS function E4 eliminating charging and kinetic current components and conserving the diffusion current component was capable of enhancing the current sensitivity of CV peaks and of detecting electron transfer in adsorbed state. (en)
Title	Voltammetric Study of Adenine Complex with Copper on Mercury Electrode Voltammetric Study of Adenine Complex with Copper on Mercury Electrode (en)
skos:prefLabel	Voltammetric Study of Adenine Complex with Copper on Mercury Electrode Voltammetric Study of Adenine Complex with Copper on Mercury Electrode (en)
skos:notation	RIV/00216224:14310/09:00043265!RIV11-MSM-14310___
http://linked.open...avai/riv/aktivita	P Z
http://linked.open...avai/riv/aktivity	P(IAA100040602), P(IAA400040804), P(KAN200040651), P(LC06035), Z(AV0Z50040507), Z(AV0Z50040702), Z(MSM0021622412)
http://linked.open...iv/cisloPeriodika	3-5
http://linked.open...vai/riv/dodaniDat	2011
http://linked.open...aciTvurceVysledku	Hasoň, Stanislav Jelen, František Trnková, Libuše Kizek, René Kouřilová, Alena
http://linked.open.../riv/druhVysledku	J - Článek v odborném periodiku
http://linked.open...iv/duvernostUdaju	S - Úplné a pravdivé údaje nepodléhající ochraně podle zvláštních právních předpisů
http://linked.open...titaPredkladatele	Masarykova univerzita / Přírodovědecká fakulta
http://linked.open...dnocenehoVysledku	349869
http://linked.open...ai/riv/idVysledku	RIV/00216224:14310/09:00043265
http://linked.open...riv/jazykVysledku	eng - angličtina
http://linked.open.../riv/klicovaSlova	Copper; Copper-adenine complex; Hanging mercury drop electrode; Cyclic voltammetry (en)
http://linked.open.../riv/klicoveSlovo	Copper Hanging mercury drop electrode Cyclic voltammetry Copper-adenine complex
http://linked.open...odStatuVydavatele	DE - Spolková republika Německo
http://linked.open...ontrolniKodProRIV	[341494A878C0]
http://linked.open...i/riv/nazevZdroje	Electroanalysis
http://linked.open...in/vavai/riv/obor	CG
http://linked.open...ichTvurcuVysledku	5 (xsd:int)
http://linked.open...cetTvurcuVysledku	5 (xsd:int)
http://linked.open...vavai/riv/projekt	Centre of Biophysical Chemistry, Bioelectrochemistry and Bioanalysis. New Tools for Genomics, Proteomics and Biomedicine. Electrochemical and optical analysis of biomacromolecules at the microelectrodes modified by a electroactive material nanolayer New approaches in electrochemical analysis of nucleic acids and oligonucleotides aimed at a ultrasensitive microdetection of DNA and DNA hybridization. Application of electrochemical methods focused on the microanalysis of nucleic acids bases and oligonucleotides
http://linked.open...UplatneniVysledku	2009
http://linked.open...v/svazekPeriodika	21
http://linked.open...iv/tvurceVysledku	Hasoň, Stanislav Kizek, René Trnková, Libuše Jelen, František Kouřilová, Alena
http://linked.open...n/vavai/riv/zamer	Biophysics of dynamic structures and functions of biological systems Genome and epigenome: 1D and 3D Structure, Dynamics, Interactions with Proteins and Functions Interactions among the chemicals, environment and biological systems and their consequences on the global, regional and local scales (INCHEMBIOL)
issn	1040-0397
number of pages	6 (xsd:int)
http://localhost/t...ganizacniJednotka	14310

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