About: Laser desorption ionization of red phosphorus clusters and their use for mass calibration in time-of-flight mass

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About: Laser desorption ionization of red phosphorus clusters and their use for mass calibration in time-of-flight mass Goto Sponge NotDistinct Permalink

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rdf:type	skos:Concept http://linked.opendata.cz/ontology/domain/vavai/Vysledek
Description	Phosphorus clusters P-n (n = 1-89) are easily formed from red phosphorus by laser desorption ionization (LDI) and they cover a range of up to approx. m/z 3000 in both positive and negative ion mode. The clusters are singly charged and the spectra are simple because phosphorus is monoisotopic. The mass spectra can be measured with an acceptable resolution and intensity. The use of positively charged P-n clusters for calibration in mass spectrometry was examined and it was demonstrated that in external calibration a standard deviation of +/-0.04 m/z units can be achieved even when using a common commercial matrix-assisted laser desorption/ionization time-of-flight (MALDI-TOF) instrument. When used as internal standards the P-n clusters react with some analytes - C-60 and C-70 fullerenes and cucurbituril[8], for example. Phosphorus clusters P-n (n = 1-89) are easily formed from red phosphorus by laser desorption ionization (LDI) and they cover a range of up to approx. m/z 3000 in both positive and negative ion mode. The clusters are singly charged and the spectra are simple because phosphorus is monoisotopic. The mass spectra can be measured with an acceptable resolution and intensity. The use of positively charged P-n clusters for calibration in mass spectrometry was examined and it was demonstrated that in external calibration a standard deviation of +/-0.04 m/z units can be achieved even when using a common commercial matrix-assisted laser desorption/ionization time-of-flight (MALDI-TOF) instrument. When used as internal standards the P-n clusters react with some analytes - C-60 and C-70 fullerenes and cucurbituril[8], for example. (en)
Title	Laser desorption ionization of red phosphorus clusters and their use for mass calibration in time-of-flight mass Laser desorption ionization of red phosphorus clusters and their use for mass calibration in time-of-flight mass (en)
skos:prefLabel	Laser desorption ionization of red phosphorus clusters and their use for mass calibration in time-of-flight mass Laser desorption ionization of red phosphorus clusters and their use for mass calibration in time-of-flight mass (en)
skos:notation	RIV/00216224:14310/09:00039767!RIV10-MSM-14310___
http://linked.open...avai/riv/aktivita	S Z
http://linked.open...avai/riv/aktivity	S, Z(MSM0021622411)
http://linked.open...iv/cisloPeriodika	23
http://linked.open...vai/riv/dodaniDat	2010
http://linked.open...aciTvurceVysledku	Sládková, Kateřina Houška, Jan Havel, Josef
http://linked.open.../riv/druhVysledku	J - Článek v odborném periodiku
http://linked.open...iv/duvernostUdaju	S - Úplné a pravdivé údaje nepodléhající ochraně podle zvláštních právních předpisů
http://linked.open...titaPredkladatele	Masarykova univerzita / Přírodovědecká fakulta
http://linked.open...dnocenehoVysledku	323250
http://linked.open...ai/riv/idVysledku	RIV/00216224:14310/09:00039767
http://linked.open...riv/jazykVysledku	eng - angličtina
http://linked.open.../riv/klicovaSlova	ELECTROSPRAY-IONIZATION; ABLATION SYNTHESIS; MALDI-TOF; DESORPTION/IONIZATION; ISOMERS; SPECTRA (en)
http://linked.open.../riv/klicoveSlovo	ABLATION SYNTHESIS DESORPTION/IONIZATION ISOMERS MALDI-TOF ELECTROSPRAY-IONIZATION SPECTRA
http://linked.open...odStatuVydavatele	GB - Spojené království Velké Británie a Severního Irska
http://linked.open...ontrolniKodProRIV	[5F347EE59380]
http://linked.open...i/riv/nazevZdroje	Rapid Communications in Mass Spectrometry
http://linked.open...in/vavai/riv/obor	CB
http://linked.open...ichTvurcuVysledku	3 (xsd:int)
http://linked.open...cetTvurcuVysledku	3 (xsd:int)
http://linked.open...UplatneniVysledku	2009
http://linked.open...v/svazekPeriodika	2009
http://linked.open...iv/tvurceVysledku	Havel, Josef Sládková, Kateřina Houška, Jan
http://linked.open...n/vavai/riv/zamer	Study and application of plasma chemical reactions in non-isothermic low temperature plasma and its interaction with solid surface
issn	0951-4198
number of pages	5 (xsd:int)
http://localhost/t...ganizacniJednotka	14310

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