About: Off-line coupling of capillary electrophoresis to inductively coupled plasma mass spectrometry for elemental speciation

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About: Off-line coupling of capillary electrophoresis to inductively coupled plasma mass spectrometry for elemental speciation Goto Sponge NotDistinct Permalink

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rdf:type	skos:Concept http://linked.opendata.cz/ontology/domain/vavai/Vysledek
Description	Forms of metals differentiated by oxidation state or bound ligands differ remarkably in the impact on their physiological function. On-line combination of column separation techniques, such as capillary electrophoresis (CE) or high performance liquid chromatography (HPLC), to inductively coupled plasma mass spectrometry ICP MS belongs to the most powerful tools for elemental speciation. It is usually achieved using nebulizers or direct injection interfaces. When combined with CE, these techniques can reduce separation resolution due to induced liquid flow in the separation column. Here we report the first off-line coupling of capillary electrophoresis with ICP MS, which is based on effluent deposition on a suitable target followed by laser ablation (LA) and transfer into ICP. The technique is compatible with microcolumn separations in terms of preservation both separation resolution and sensitivity. Forms of metals differentiated by oxidation state or bound ligands differ remarkably in the impact on their physiological function. On-line combination of column separation techniques, such as capillary electrophoresis (CE) or high performance liquid chromatography (HPLC), to inductively coupled plasma mass spectrometry ICP MS belongs to the most powerful tools for elemental speciation. It is usually achieved using nebulizers or direct injection interfaces. When combined with CE, these techniques can reduce separation resolution due to induced liquid flow in the separation column. Here we report the first off-line coupling of capillary electrophoresis with ICP MS, which is based on effluent deposition on a suitable target followed by laser ablation (LA) and transfer into ICP. The technique is compatible with microcolumn separations in terms of preservation both separation resolution and sensitivity. (en)
Title	Off-line coupling of capillary electrophoresis to inductively coupled plasma mass spectrometry for elemental speciation Off-line coupling of capillary electrophoresis to inductively coupled plasma mass spectrometry for elemental speciation (en)
skos:prefLabel	Off-line coupling of capillary electrophoresis to inductively coupled plasma mass spectrometry for elemental speciation Off-line coupling of capillary electrophoresis to inductively coupled plasma mass spectrometry for elemental speciation (en)
skos:notation	RIV/00216224:14310/08:00058802!RIV13-MSM-14310___
http://linked.open...avai/riv/aktivita	P Z
http://linked.open...avai/riv/aktivity	P(LC06035), Z(MSM0021622411), Z(MSM0021622412), Z(MSM0021622415)
http://linked.open...vai/riv/dodaniDat	2013
http://linked.open...aciTvurceVysledku	Vaculovič, Tomáš Preisler, Jan Vyhnánek, Radek Kanický, Viktor Foltynová, Pavla Peš, Ondřej Krásenský, Pavel
http://linked.open.../riv/druhVysledku	O - Ostatní výsledky nezařaditelné do žádného z výše uvedených druhů výsledku
http://linked.open...iv/duvernostUdaju	S - Úplné a pravdivé údaje nepodléhající ochraně podle zvláštních právních předpisů
http://linked.open...titaPredkladatele	Masarykova univerzita / Přírodovědecká fakulta
http://linked.open...dnocenehoVysledku	384424
http://linked.open...ai/riv/idVysledku	RIV/00216224:14310/08:00058802
http://linked.open...riv/jazykVysledku	eng - angličtina
http://linked.open.../riv/klicovaSlova	off-line coupling; capillary electrophoresis; inductively coupled plasma mass spectrometry; elemental speciation (en)
http://linked.open.../riv/klicoveSlovo	capillary electrophoresis inductively coupled plasma mass spectrometry off-line coupling elemental speciation
http://linked.open...ontrolniKodProRIV	[33C0D8004632]
http://linked.open...in/vavai/riv/obor	CB
http://linked.open...ichTvurcuVysledku	7 (xsd:int)
http://linked.open...cetTvurcuVysledku	7 (xsd:int)
http://linked.open...vavai/riv/projekt	Centre of Biophysical Chemistry, Bioelectrochemistry and Bioanalysis. New Tools for Genomics, Proteomics and Biomedicine.
http://linked.open...UplatneniVysledku	2008
http://linked.open...iv/tvurceVysledku	Kanický, Viktor Preisler, Jan Vaculovič, Tomáš Foltynová, Pavla Peš, Ondřej Krásenský, Pavel Vyhnánek, Radek
http://linked.open...n/vavai/riv/zamer	Study and application of plasma chemical reactions in non-isothermic low temperature plasma and its interaction with solid surface Interactions among the chemicals, environment and biological systems and their consequences on the global, regional and local scales (INCHEMBIOL) Molecular basis of cell and tissue regulations
http://localhost/t...ganizacniJednotka	14310

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