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  • Enantiomeric fractions (EF) of PCB 95, 132, 149, and 174, alpha-HCH, o,p'-DDD, and o,p'-DDT were analyzed in 112 soil samples using two-dimensional gas chromatography and triple-quadrupole mass spectrometry. To assess the soil conditions that facilitate enantioselective fractionation of chiral compounds, EF values of selected PCBs were further correlated with a wide range of physicochemical and microbial soil parameters in an attempt to identify the influential factors and their mutual relations. It was evident that soils where nonracemic ratios of investigated compounds were found were more carbon rich but they also contained significantly more humic and fulvic acids and total nitrogen. These specific physicochemical properties were accompanied by significantly increased values of all key biotic variables, the amount of microbial biomass, and its respiration activity (both basal and substrate-induced).
  • Enantiomeric fractions (EF) of PCB 95, 132, 149, and 174, alpha-HCH, o,p'-DDD, and o,p'-DDT were analyzed in 112 soil samples using two-dimensional gas chromatography and triple-quadrupole mass spectrometry. To assess the soil conditions that facilitate enantioselective fractionation of chiral compounds, EF values of selected PCBs were further correlated with a wide range of physicochemical and microbial soil parameters in an attempt to identify the influential factors and their mutual relations. It was evident that soils where nonracemic ratios of investigated compounds were found were more carbon rich but they also contained significantly more humic and fulvic acids and total nitrogen. These specific physicochemical properties were accompanied by significantly increased values of all key biotic variables, the amount of microbial biomass, and its respiration activity (both basal and substrate-induced). (en)
Title
  • WHICH FACTORS AFFECT THE FATE OF CHIRAL PERSISTENT ORGANIC POLLUTANTS IN THE TERRESTRIAL ECOSYSTEM?
  • WHICH FACTORS AFFECT THE FATE OF CHIRAL PERSISTENT ORGANIC POLLUTANTS IN THE TERRESTRIAL ECOSYSTEM? (en)
skos:prefLabel
  • WHICH FACTORS AFFECT THE FATE OF CHIRAL PERSISTENT ORGANIC POLLUTANTS IN THE TERRESTRIAL ECOSYSTEM?
  • WHICH FACTORS AFFECT THE FATE OF CHIRAL PERSISTENT ORGANIC POLLUTANTS IN THE TERRESTRIAL ECOSYSTEM? (en)
skos:notation
  • RIV/00216224:14310/08:00027896!RIV10-MSM-14310___
http://linked.open...avai/riv/aktivita
http://linked.open...avai/riv/aktivity
  • Z(MSM0021622412)
http://linked.open...iv/cisloPeriodika
  • 1
http://linked.open...vai/riv/dodaniDat
http://linked.open...aciTvurceVysledku
http://linked.open.../riv/druhVysledku
http://linked.open...iv/duvernostUdaju
http://linked.open...titaPredkladatele
http://linked.open...dnocenehoVysledku
  • 405725
http://linked.open...ai/riv/idVysledku
  • RIV/00216224:14310/08:00027896
http://linked.open...riv/jazykVysledku
http://linked.open.../riv/klicovaSlova
  • Chiral analysis; degradation; enentiomer; GC MS (en)
http://linked.open.../riv/klicoveSlovo
http://linked.open...odStatuVydavatele
  • GB - Spojené království Velké Británie a Severního Irska
http://linked.open...ontrolniKodProRIV
  • [849F34750200]
http://linked.open...i/riv/nazevZdroje
  • Organohalogen Compounds
http://linked.open...in/vavai/riv/obor
http://linked.open...ichTvurcuVysledku
http://linked.open...cetTvurcuVysledku
http://linked.open...UplatneniVysledku
http://linked.open...v/svazekPeriodika
  • 2008
http://linked.open...iv/tvurceVysledku
  • Dušek, Ladislav
  • Hofman, Jakub
  • Klánová, Jana
  • Kobližková, Martina
  • Bucheli, Thomas
http://linked.open...n/vavai/riv/zamer
issn
  • 1026-4892
number of pages
http://localhost/t...ganizacniJednotka
  • 14310
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