About: Synthesis, X-ray crystal structure and thermal decomposition of two peroxovanadium complexes with coordinated ammonia molecules: [{VO(O-2)2(NH3)}(2){[mu-Cu(NH3)(4)}] and [Zn(NH3)(4)][VO(O-2)(2)(NH3)](2)

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About: Synthesis, X-ray crystal structure and thermal decomposition of two peroxovanadium complexes with coordinated ammonia molecules: [{VO(O-2)2(NH3)}(2){[mu-Cu(NH3)(4)}] and [Zn(NH3)(4)][VO(O-2)(2)(NH3)](2) Goto Sponge NotDistinct Permalink

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rdf:type	skos:Concept http://linked.opendata.cz/ontology/domain/vavai/Vysledek
Description	The compounds [{VO(O-2)(2)(NH3)}(2){mu-Cu(NH3)(4)}] (1) and [Zn(NH3)(4)][VO(O-2)(2)(NH3)](2) (2) were prepared and characterized by elemental analysis and infrared spectra. The single crystal X-ray study revealed that the structure of 1 consists of trinuclear complex molecules [(NH3)OV(O-2)(2){mu-Cu(NH3)(4)}(O-2)(2)VO(NH3)] with a rare heterobimetalic peroxo bridge: copper(II)-peroxo ligand-vanadium(V). The structure of 2 is composed of tetraamminezinc(II) cations and ammineoxodiperoxovanadate(V) anions. In course of thermal decomposition of 1 performed up to 620 degrees C, the following intermediate products: [Cu(NH3)(2)(VO3)(2)], and subsequently a mixture of V2O5 with monoclinic beta-Cu2V2O7, were gradually formed. The final product of decomposition is Cu(Vo(3))(2). The thermal decomposition of 2 is a two-step process. The compounds [{VO(O-2)(2)(NH3)}(2){mu-Cu(NH3)(4)}] (1) and [Zn(NH3)(4)][VO(O-2)(2)(NH3)](2) (2) were prepared and characterized by elemental analysis and infrared spectra. The single crystal X-ray study revealed that the structure of 1 consists of trinuclear complex molecules [(NH3)OV(O-2)(2){mu-Cu(NH3)(4)}(O-2)(2)VO(NH3)] with a rare heterobimetalic peroxo bridge: copper(II)-peroxo ligand-vanadium(V). The structure of 2 is composed of tetraamminezinc(II) cations and ammineoxodiperoxovanadate(V) anions. In course of thermal decomposition of 1 performed up to 620 degrees C, the following intermediate products: [Cu(NH3)(2)(VO3)(2)], and subsequently a mixture of V2O5 with monoclinic beta-Cu2V2O7, were gradually formed. The final product of decomposition is Cu(Vo(3))(2). The thermal decomposition of 2 is a two-step process. (en)
Title	Synthesis, X-ray crystal structure and thermal decomposition of two peroxovanadium complexes with coordinated ammonia molecules: [{VO(O-2)2(NH3)}(2){[mu-Cu(NH3)(4)}] and [Zn(NH3)(4)][VO(O-2)(2)(NH3)](2) Synthesis, X-ray crystal structure and thermal decomposition of two peroxovanadium complexes with coordinated ammonia molecules: [{VO(O-2)2(NH3)}(2){[mu-Cu(NH3)(4)}] and [Zn(NH3)(4)][VO(O-2)(2)(NH3)](2) (en)
skos:prefLabel	Synthesis, X-ray crystal structure and thermal decomposition of two peroxovanadium complexes with coordinated ammonia molecules: [{VO(O-2)2(NH3)}(2){[mu-Cu(NH3)(4)}] and [Zn(NH3)(4)][VO(O-2)(2)(NH3)](2) Synthesis, X-ray crystal structure and thermal decomposition of two peroxovanadium complexes with coordinated ammonia molecules: [{VO(O-2)2(NH3)}(2){[mu-Cu(NH3)(4)}] and [Zn(NH3)(4)][VO(O-2)(2)(NH3)](2) (en)
skos:notation	RIV/00216224:14310/08:00026161!RIV10-MSM-14310___
http://linked.open...avai/riv/aktivita	Z
http://linked.open...avai/riv/aktivity	Z(MSM0021622415)
http://linked.open...iv/cisloPeriodika	2
http://linked.open...vai/riv/dodaniDat	2010
http://linked.open...aciTvurceVysledku	Marek, Jaromír
http://linked.open.../riv/druhVysledku	J - Článek v odborném periodiku
http://linked.open...iv/duvernostUdaju	S - Úplné a pravdivé údaje nepodléhající ochraně podle zvláštních právních předpisů
http://linked.open...titaPredkladatele	Masarykova univerzita / Přírodovědecká fakulta
http://linked.open...dnocenehoVysledku	398818
http://linked.open...ai/riv/idVysledku	RIV/00216224:14310/08:00026161
http://linked.open...riv/jazykVysledku	eng - angličtina
http://linked.open.../riv/klicovaSlova	peroxovanadium complexes; ammine complexes; X-ray structure; IR spectra; thermal decomposition (en)
http://linked.open.../riv/klicoveSlovo	ammine complexes thermal decomposition X-ray structure IR spectra peroxovanadium complexes
http://linked.open...odStatuVydavatele	GB - Spojené království Velké Británie a Severního Irska
http://linked.open...ontrolniKodProRIV	[B9F90B420A86]
http://linked.open...i/riv/nazevZdroje	Polyhedron
http://linked.open...in/vavai/riv/obor	CA
http://linked.open...ichTvurcuVysledku	1 (xsd:int)
http://linked.open...cetTvurcuVysledku	5 (xsd:int)
http://linked.open...UplatneniVysledku	2008
http://linked.open...v/svazekPeriodika	27
http://linked.open...iv/tvurceVysledku	Marek, Jaromír Tatiersky, J. Schwendt, P. Chrappová, J. Dudášová, D.
http://linked.open...ain/vavai/riv/wos	000253518700021
http://linked.open...n/vavai/riv/zamer	Molecular basis of cell and tissue regulations
issn	0277-5387
number of pages	7 (xsd:int)
http://localhost/t...ganizacniJednotka	14310

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