About: DISSOCIATION KINETICS STUDY OF Ce(III) COMPLEXES WITH H8dotp (H8dotp = 1,4,7,10-TETRAAZACYCLODODECANE-1,4,7,10-TETRAKIS(METHYLPHOSPHONIC ACID))

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About: DISSOCIATION KINETICS STUDY OF Ce(III) COMPLEXES WITH H8dotp (H8dotp = 1,4,7,10-TETRAAZACYCLODODECANE-1,4,7,10-TETRAKIS(METHYLPHOSPHONIC ACID)) Goto Sponge NotDistinct Permalink

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rdf:type	skos:Concept http://linked.opendata.cz/ontology/domain/vavai/Vysledek
Description	The dissociation kinetics of cerium(III) complexes with H8dotp (I = 3.0 mol dm-3 (Na,H)ClO4, t = 25 - 60 degrees C) was studied by means of molecular absorption spectroscopy in the UV region. The mechanism of the proton-assisted reaction was proposed, and the activation parameters (Ea = 111 +/- 20 kJ mol-1, delta_H_act = 108 +/- 20 kJ mol-1, delta_S_act = 32 +/- 62 J K-1 mol-1) for the rate-determining step were calculated. The dissociation kinetics of cerium(III) complexes with H8dotp (I = 3.0 mol dm-3 (Na,H)ClO4, t = 25 - 60 degrees C) was studied by means of molecular absorption spectroscopy in the UV region. The mechanism of the proton-assisted reaction was proposed, and the activation parameters (Ea = 111 +/- 20 kJ mol-1, delta_H_act = 108 +/- 20 kJ mol-1, delta_S_act = 32 +/- 62 J K-1 mol-1) for the rate-determining step were calculated. (en)
Title	DISSOCIATION KINETICS STUDY OF Ce(III) COMPLEXES WITH H8dotp (H8dotp = 1,4,7,10-TETRAAZACYCLODODECANE-1,4,7,10-TETRAKIS(METHYLPHOSPHONIC ACID)) DISSOCIATION KINETICS STUDY OF Ce(III) COMPLEXES WITH H8dotp (H8dotp = 1,4,7,10-TETRAAZACYCLODODECANE-1,4,7,10-TETRAKIS(METHYLPHOSPHONIC ACID)) (en)
skos:prefLabel	DISSOCIATION KINETICS STUDY OF Ce(III) COMPLEXES WITH H8dotp (H8dotp = 1,4,7,10-TETRAAZACYCLODODECANE-1,4,7,10-TETRAKIS(METHYLPHOSPHONIC ACID)) DISSOCIATION KINETICS STUDY OF Ce(III) COMPLEXES WITH H8dotp (H8dotp = 1,4,7,10-TETRAAZACYCLODODECANE-1,4,7,10-TETRAKIS(METHYLPHOSPHONIC ACID)) (en)
skos:notation	RIV/00216224:14310/08:00025763!RIV10-MSM-14310___
http://linked.open...avai/riv/aktivita	P Z
http://linked.open...avai/riv/aktivity	P(LC06035), P(OC 179), Z(MSM0021620857)
http://linked.open...iv/cisloPeriodika	1-2
http://linked.open...vai/riv/dodaniDat	2010
http://linked.open...aciTvurceVysledku	Voráčová, Ivona Hermann, Petr Lubal, Přemysl Piskula, Zbigniew
http://linked.open.../riv/druhVysledku	J - Článek v odborném periodiku
http://linked.open...iv/duvernostUdaju	S - Úplné a pravdivé údaje nepodléhající ochraně podle zvláštních právních předpisů
http://linked.open...titaPredkladatele	Masarykova univerzita / Přírodovědecká fakulta
http://linked.open...dnocenehoVysledku	363849
http://linked.open...ai/riv/idVysledku	RIV/00216224:14310/08:00025763
http://linked.open...riv/jazykVysledku	eng - angličtina
http://linked.open.../riv/klicovaSlova	macrocyclic complexes; cyclen derivatives; phosphonate complexes; lanthanide(III) complexes; cerium(III); dissociation kinetics (en)
http://linked.open.../riv/klicoveSlovo	lanthanide(III) complexes phosphonate complexes cerium(III) cyclen derivatives dissociation kinetics macrocyclic complexes
http://linked.open...odStatuVydavatele	NL - Nizozemsko
http://linked.open...ontrolniKodProRIV	[8BE307D16B3D]
http://linked.open...i/riv/nazevZdroje	Journal of Alloys and Compounds
http://linked.open...in/vavai/riv/obor	CA
http://linked.open...ichTvurcuVysledku	4 (xsd:int)
http://linked.open...cetTvurcuVysledku	5 (xsd:int)
http://linked.open...vavai/riv/projekt	Centre of Biophysical Chemistry, Bioelectrochemistry and Bioanalysis. New Tools for Genomics, Proteomics and Biomedicine. http://linked.opendata.cz/resource/domain/vavai/projekt/OC%20179
http://linked.open...UplatneniVysledku	2008
http://linked.open...v/svazekPeriodika	451
http://linked.open...iv/tvurceVysledku	Hermann, Petr Lubal, Přemysl Svobodová, Ivona Piskula, Zbigniew Lis, Stefan
http://linked.open...ain/vavai/riv/wos	000253600400007
http://linked.open...n/vavai/riv/zamer	Nové molekulární systémy pro pokročilé aplikace prospěšné pro zdraví a šetrné k životnímu prostředí
issn	0925-8388
number of pages	4 (xsd:int)
http://localhost/t...ganizacniJednotka	14310

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