About: Study of copper and purine-copper complexes on modified carbon electrodes by cyclic and elimination voltammetry     Goto   Sponge   NotDistinct   Permalink

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  • Using a paraffin impregnated graphite electrode (PIGE) and mercury-modified pyrolytic graphite electrode with basal orientation (Hg-PGEb) copper(II) and Cu(II)-DNA purine base solutions have been studied by cyclic (CV) and linear sweep voltammetry (LSV) in connection with elimination voltammetry with linear scan (EVLS). In chloride and bromide solutions (pH 6), the redox process of Cu(II) proceeded on PIGE with two cathodic and two anodic potentially separated signals. According to the elimination function E4, the first cathodic peak corresponds to the reduction Cu(II) + e(-) -> Cu(I) with the possibility of fast disproportionation 2Cu(I) -> Cu(II)+ Cu(0). The E4 of the second cathodic peak signalized an electrode process controlled by a surface reaction. The electrode system of Cu(II) on Hg-PGEb in borate buffer (pH 9.2) was characterized by one cathodic and one anodic peak.
  • Using a paraffin impregnated graphite electrode (PIGE) and mercury-modified pyrolytic graphite electrode with basal orientation (Hg-PGEb) copper(II) and Cu(II)-DNA purine base solutions have been studied by cyclic (CV) and linear sweep voltammetry (LSV) in connection with elimination voltammetry with linear scan (EVLS). In chloride and bromide solutions (pH 6), the redox process of Cu(II) proceeded on PIGE with two cathodic and two anodic potentially separated signals. According to the elimination function E4, the first cathodic peak corresponds to the reduction Cu(II) + e(-) -> Cu(I) with the possibility of fast disproportionation 2Cu(I) -> Cu(II)+ Cu(0). The E4 of the second cathodic peak signalized an electrode process controlled by a surface reaction. The electrode system of Cu(II) on Hg-PGEb in borate buffer (pH 9.2) was characterized by one cathodic and one anodic peak. (en)
Title
  • Study of copper and purine-copper complexes on modified carbon electrodes by cyclic and elimination voltammetry
  • Study of copper and purine-copper complexes on modified carbon electrodes by cyclic and elimination voltammetry (en)
skos:prefLabel
  • Study of copper and purine-copper complexes on modified carbon electrodes by cyclic and elimination voltammetry
  • Study of copper and purine-copper complexes on modified carbon electrodes by cyclic and elimination voltammetry (en)
skos:notation
  • RIV/00216224:14310/08:00024270!RIV10-MSM-14310___
http://linked.open...avai/riv/aktivita
http://linked.open...avai/riv/aktivity
  • P(IAA100040602), P(IAA400040804), P(LC06035), P(OC 174), Z(AV0Z50040507), Z(AV0Z50040702)
http://linked.open...iv/cisloPeriodika
  • JAN 2008
http://linked.open...vai/riv/dodaniDat
http://linked.open...aciTvurceVysledku
http://linked.open.../riv/druhVysledku
http://linked.open...iv/duvernostUdaju
http://linked.open...titaPredkladatele
http://linked.open...dnocenehoVysledku
  • 398098
http://linked.open...ai/riv/idVysledku
  • RIV/00216224:14310/08:00024270
http://linked.open...riv/jazykVysledku
http://linked.open.../riv/klicovaSlova
  • copper-purine complexes; paraffin-impregnated graphite electrode; mercury-film electrode; anodic and cathodic stripping techniques; elimination voltammetry; confidence ellipse (en)
http://linked.open.../riv/klicoveSlovo
http://linked.open...odStatuVydavatele
  • CH - Švýcarská konfederace
http://linked.open...ontrolniKodProRIV
  • [D03766C3E281]
http://linked.open...i/riv/nazevZdroje
  • Sensors
http://linked.open...in/vavai/riv/obor
http://linked.open...ichTvurcuVysledku
http://linked.open...cetTvurcuVysledku
http://linked.open...vavai/riv/projekt
http://linked.open...UplatneniVysledku
http://linked.open...v/svazekPeriodika
  • 8
http://linked.open...iv/tvurceVysledku
  • Trnková, Libuše
  • Zerzánková, Lenka
  • Dyčka, Filip
  • Jelen, František
  • Mikelová, Radka
http://linked.open...n/vavai/riv/zamer
issn
  • 1424-8220
number of pages
http://localhost/t...ganizacniJednotka
  • 14310
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