About: Study of copper and purine-copper complexes on modified carbon electrodes by cyclic and elimination voltammetry

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About: Study of copper and purine-copper complexes on modified carbon electrodes by cyclic and elimination voltammetry Goto Sponge NotDistinct Permalink

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rdf:type	skos:Concept http://linked.opendata.cz/ontology/domain/vavai/Vysledek
Description	Using a paraffin impregnated graphite electrode (PIGE) and mercury-modified pyrolytic graphite electrode with basal orientation (Hg-PGEb) copper(II) and Cu(II)-DNA purine base solutions have been studied by cyclic (CV) and linear sweep voltammetry (LSV) in connection with elimination voltammetry with linear scan (EVLS). In chloride and bromide solutions (pH 6), the redox process of Cu(II) proceeded on PIGE with two cathodic and two anodic potentially separated signals. According to the elimination function E4, the first cathodic peak corresponds to the reduction Cu(II) + e(-) -> Cu(I) with the possibility of fast disproportionation 2Cu(I) -> Cu(II)+ Cu(0). The E4 of the second cathodic peak signalized an electrode process controlled by a surface reaction. The electrode system of Cu(II) on Hg-PGEb in borate buffer (pH 9.2) was characterized by one cathodic and one anodic peak. Using a paraffin impregnated graphite electrode (PIGE) and mercury-modified pyrolytic graphite electrode with basal orientation (Hg-PGEb) copper(II) and Cu(II)-DNA purine base solutions have been studied by cyclic (CV) and linear sweep voltammetry (LSV) in connection with elimination voltammetry with linear scan (EVLS). In chloride and bromide solutions (pH 6), the redox process of Cu(II) proceeded on PIGE with two cathodic and two anodic potentially separated signals. According to the elimination function E4, the first cathodic peak corresponds to the reduction Cu(II) + e(-) -> Cu(I) with the possibility of fast disproportionation 2Cu(I) -> Cu(II)+ Cu(0). The E4 of the second cathodic peak signalized an electrode process controlled by a surface reaction. The electrode system of Cu(II) on Hg-PGEb in borate buffer (pH 9.2) was characterized by one cathodic and one anodic peak. (en)
Title	Study of copper and purine-copper complexes on modified carbon electrodes by cyclic and elimination voltammetry Study of copper and purine-copper complexes on modified carbon electrodes by cyclic and elimination voltammetry (en)
skos:prefLabel	Study of copper and purine-copper complexes on modified carbon electrodes by cyclic and elimination voltammetry Study of copper and purine-copper complexes on modified carbon electrodes by cyclic and elimination voltammetry (en)
skos:notation	RIV/00216224:14310/08:00024270!RIV10-MSM-14310___
http://linked.open...avai/riv/aktivita	P Z
http://linked.open...avai/riv/aktivity	P(IAA100040602), P(IAA400040804), P(LC06035), P(OC 174), Z(AV0Z50040507), Z(AV0Z50040702)
http://linked.open...iv/cisloPeriodika	JAN 2008
http://linked.open...vai/riv/dodaniDat	2010
http://linked.open...aciTvurceVysledku	Dyčka, Filip Zerzánková, Lenka Jelen, František Trnková, Libuše Mikelová, Radka
http://linked.open.../riv/druhVysledku	J - Článek v odborném periodiku
http://linked.open...iv/duvernostUdaju	S - Úplné a pravdivé údaje nepodléhající ochraně podle zvláštních právních předpisů
http://linked.open...titaPredkladatele	Masarykova univerzita / Přírodovědecká fakulta
http://linked.open...dnocenehoVysledku	398098
http://linked.open...ai/riv/idVysledku	RIV/00216224:14310/08:00024270
http://linked.open...riv/jazykVysledku	eng - angličtina
http://linked.open.../riv/klicovaSlova	copper-purine complexes; paraffin-impregnated graphite electrode; mercury-film electrode; anodic and cathodic stripping techniques; elimination voltammetry; confidence ellipse (en)
http://linked.open.../riv/klicoveSlovo	anodic and cathodic stripping techniques confidence ellipse copper-purine complexes mercury-film electrode paraffin-impregnated graphite electrode elimination voltammetry
http://linked.open...odStatuVydavatele	CH - Švýcarská konfederace
http://linked.open...ontrolniKodProRIV	[D03766C3E281]
http://linked.open...i/riv/nazevZdroje	Sensors
http://linked.open...in/vavai/riv/obor	CG
http://linked.open...ichTvurcuVysledku	5 (xsd:int)
http://linked.open...cetTvurcuVysledku	5 (xsd:int)
http://linked.open...vavai/riv/projekt	Centre of Biophysical Chemistry, Bioelectrochemistry and Bioanalysis. New Tools for Genomics, Proteomics and Biomedicine. New approaches in electrochemical analysis of nucleic acids and oligonucleotides aimed at a ultrasensitive microdetection of DNA and DNA hybridization. Application of electrochemical methods focused on the microanalysis of nucleic acids bases and oligonucleotides http://linked.opendata.cz/resource/domain/vavai/projekt/OC%20174
http://linked.open...UplatneniVysledku	2008
http://linked.open...v/svazekPeriodika	8
http://linked.open...iv/tvurceVysledku	Trnková, Libuše Zerzánková, Lenka Dyčka, Filip Jelen, František Mikelová, Radka
http://linked.open...n/vavai/riv/zamer	Biophysics of dynamic structures and functions of biological systems Genome and epigenome: 1D and 3D Structure, Dynamics, Interactions with Proteins and Functions
issn	1424-8220
number of pages	16 (xsd:int)
http://localhost/t...ganizacniJednotka	14310

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