About: Determination of chiral organic compounds in environmental matrices with two-dimensional gas chromatography coupled to triple quadrupole mass spectrometry     Goto   Sponge   NotDistinct   Permalink

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Description
  • Two-dimensional gas chromatography (GC-GC) combined with triple quadrupole mass spectrometers (MS-MS) was used for analysis of chiral compounds, which were extracted from soil and air samples of Czech Republic and former Yugoslavia. Air samples were collected using polyurethane foam based passive air samplers. Soil samples were collected at the same sites. Enantiomeric fraction (EF) values were used to describe enantiomeric signatures. EF values in soil ranged from 0.408 to 0.524 for PCB 95, from 0.458 to 0.597 for PCB 132, from 0.494 to 0.547 for PCB 149 and from 0.478 to 0.535 for PCB 174. In some soil samples were also measured EF values of selected OCPs. EF values for alpha-HCH ranged from 0.475 to 0.517, for o,p-DDD from 0.368 to 0.570 and for o,p-DDT from 0.365 to 0.513. EFs were correlated with the set of physico-chemical and microbiological parameters of the soils in order to better assess the fate of the compounds in the environment.
  • Two-dimensional gas chromatography (GC-GC) combined with triple quadrupole mass spectrometers (MS-MS) was used for analysis of chiral compounds, which were extracted from soil and air samples of Czech Republic and former Yugoslavia. Air samples were collected using polyurethane foam based passive air samplers. Soil samples were collected at the same sites. Enantiomeric fraction (EF) values were used to describe enantiomeric signatures. EF values in soil ranged from 0.408 to 0.524 for PCB 95, from 0.458 to 0.597 for PCB 132, from 0.494 to 0.547 for PCB 149 and from 0.478 to 0.535 for PCB 174. In some soil samples were also measured EF values of selected OCPs. EF values for alpha-HCH ranged from 0.475 to 0.517, for o,p-DDD from 0.368 to 0.570 and for o,p-DDT from 0.365 to 0.513. EFs were correlated with the set of physico-chemical and microbiological parameters of the soils in order to better assess the fate of the compounds in the environment. (en)
Title
  • Determination of chiral organic compounds in environmental matrices with two-dimensional gas chromatography coupled to triple quadrupole mass spectrometry
  • Determination of chiral organic compounds in environmental matrices with two-dimensional gas chromatography coupled to triple quadrupole mass spectrometry (en)
skos:prefLabel
  • Determination of chiral organic compounds in environmental matrices with two-dimensional gas chromatography coupled to triple quadrupole mass spectrometry
  • Determination of chiral organic compounds in environmental matrices with two-dimensional gas chromatography coupled to triple quadrupole mass spectrometry (en)
skos:notation
  • RIV/00216224:14310/06:00023679!RIV10-MSM-14310___
http://linked.open...avai/riv/aktivita
http://linked.open...avai/riv/aktivity
  • Z(MSM0021622412)
http://linked.open...iv/cisloPeriodika
  • 1
http://linked.open...vai/riv/dodaniDat
http://linked.open...aciTvurceVysledku
http://linked.open.../riv/druhVysledku
http://linked.open...iv/duvernostUdaju
http://linked.open...titaPredkladatele
http://linked.open...dnocenehoVysledku
  • 471121
http://linked.open...ai/riv/idVysledku
  • RIV/00216224:14310/06:00023679
http://linked.open...riv/jazykVysledku
http://linked.open.../riv/klicovaSlova
  • Chiral; enantiomer; degradation; GC MS (en)
http://linked.open.../riv/klicoveSlovo
http://linked.open...odStatuVydavatele
  • NO - Norské království
http://linked.open...ontrolniKodProRIV
  • [816CEEEF84F9]
http://linked.open...i/riv/nazevZdroje
  • Organohalogen Compounds
http://linked.open...in/vavai/riv/obor
http://linked.open...ichTvurcuVysledku
http://linked.open...cetTvurcuVysledku
http://linked.open...UplatneniVysledku
http://linked.open...v/svazekPeriodika
  • 2006
http://linked.open...iv/tvurceVysledku
  • Klánová, Jana
  • Kobližková, Martina
  • Bucheli, Thomas
  • Brandli, Rahel
http://linked.open...n/vavai/riv/zamer
issn
  • 1026-4892
number of pages
http://localhost/t...ganizacniJednotka
  • 14310
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