About: A new rearrangement of fused tetracyclic heterocycles in an acidic medium in the presence of NaBH3CN

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About: A new rearrangement of fused tetracyclic heterocycles in an acidic medium in the presence of NaBH3CN Goto Sponge NotDistinct Permalink

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rdf:type	skos:Concept http://linked.opendata.cz/ontology/domain/vavai/Vysledek
Description	In acidic medium the criss-cross cycloadduct with four fused five-membered rings rearranges to a heterocyclic compound with a completely different structure consisting of two six-membered and two five-membered rings. This newly discovered rearrangement was observed in the presence of a reducing agent (NaBH3CN). The rearrangement proceeds easily and with an extremely high yield. In acidic medium the criss-cross cycloadduct with four fused five-membered rings rearranges to a heterocyclic compound with a completely different structure consisting of two six-membered and two five-membered rings. This newly discovered rearrangement was observed in the presence of a reducing agent (NaBH3CN). The rearrangement proceeds easily and with an extremely high yield. (en)
Title	A new rearrangement of fused tetracyclic heterocycles in an acidic medium in the presence of NaBH3CN A new rearrangement of fused tetracyclic heterocycles in an acidic medium in the presence of NaBH3CN (en)
skos:prefLabel	A new rearrangement of fused tetracyclic heterocycles in an acidic medium in the presence of NaBH3CN A new rearrangement of fused tetracyclic heterocycles in an acidic medium in the presence of NaBH3CN (en)
skos:notation	RIV/00216224:14310/06:00017337!RIV10-MSM-14310___
http://linked.open...avai/riv/aktivita	Z
http://linked.open...avai/riv/aktivity	Z(MSM 143100011)
http://linked.open...iv/cisloPeriodika	2006
http://linked.open...vai/riv/dodaniDat	2010
http://linked.open...aciTvurceVysledku	Potáček, Milan Man, Stanislav Pížová, Hana Marek, Radek Taraba, Jan
http://linked.open.../riv/druhVysledku	J - Článek v odborném periodiku
http://linked.open...iv/duvernostUdaju	S - Úplné a pravdivé údaje nepodléhající ochraně podle zvláštních právních předpisů
http://linked.open...titaPredkladatele	Masarykova univerzita / Přírodovědecká fakulta
http://linked.open...dnocenehoVysledku	463664
http://linked.open...ai/riv/idVysledku	RIV/00216224:14310/06:00017337
http://linked.open...riv/jazykVysledku	eng - angličtina
http://linked.open.../riv/klicovaSlova	rearrangement; fused heterocycles; sodium cyanoborohydride; acidic medium (en)
http://linked.open.../riv/klicoveSlovo	rearrangement fused heterocycles acidic medium sodium cyanoborohydride
http://linked.open...odStatuVydavatele	GB - Spojené království Velké Británie a Severního Irska
http://linked.open...ontrolniKodProRIV	[A993B1A66706]
http://linked.open...i/riv/nazevZdroje	Tetrahedron Letters
http://linked.open...in/vavai/riv/obor	CC
http://linked.open...ichTvurcuVysledku	5 (xsd:int)
http://linked.open...cetTvurcuVysledku	5 (xsd:int)
http://linked.open...UplatneniVysledku	2006
http://linked.open...v/svazekPeriodika	47
http://linked.open...iv/tvurceVysledku	Man, Stanislav Marek, Radek Potáček, Milan Pížová, Hana Taraba, Jan
http://linked.open...ain/vavai/riv/wos	000241775000033
http://linked.open...n/vavai/riv/zamer	http://linked.opendata.cz/resource/domain/vavai/zamer/MSM%20143100011
issn	0040-4039
number of pages	3 (xsd:int)
http://localhost/t...ganizacniJednotka	14310

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