About: Cubic octanuclear aluminum fluoride phosphonate

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rdf:type	skos:Concept http://linked.opendata.cz/ontology/domain/vavai/Vysledek
Description	A crystalline complex [Al8F12{(CH3)2C(NH3)PO3}12] (1) was isolated from the supernatant of the hydrothermal reaction of gibbsite Al- (OH)3 with 1-amino-1-methyl-ethylphosphonic acid (AIPA) and the HF mineralizer. The single-crystal X-ray diffraction analysis revealed a highly symmetrical cubic Al8F12 core with aluminum atoms at the corners, bridging fluorides spanning all edges, and 12 bidentate bridging phosphonate ligands completing the octahedral coordination sphere of aluminum centers. The stability of the complex in solution was established by electrospray mass spectrometry and the high molecular symmetry ( Th) was reflected in the appearance of single resonances in the 1H, 19F, and 31P NMR spectra. A crystalline complex [Al8F12{(CH3)2C(NH3)PO3}12] (1) was isolated from the supernatant of the hydrothermal reaction of gibbsite Al- (OH)3 with 1-amino-1-methyl-ethylphosphonic acid (AIPA) and the HF mineralizer. The single-crystal X-ray diffraction analysis revealed a highly symmetrical cubic Al8F12 core with aluminum atoms at the corners, bridging fluorides spanning all edges, and 12 bidentate bridging phosphonate ligands completing the octahedral coordination sphere of aluminum centers. The stability of the complex in solution was established by electrospray mass spectrometry and the high molecular symmetry ( Th) was reflected in the appearance of single resonances in the 1H, 19F, and 31P NMR spectra. (en)
Title	Cubic octanuclear aluminum fluoride phosphonate Cubic octanuclear aluminum fluoride phosphonate (en)
skos:prefLabel	Cubic octanuclear aluminum fluoride phosphonate Cubic octanuclear aluminum fluoride phosphonate (en)
skos:notation	RIV/00216224:14310/06:00015818!RIV10-MSM-14310___
http://linked.open...avai/riv/aktivita	P Z
http://linked.open...avai/riv/aktivity	P(GA202/06/0757), P(GA203/04/0296), Z(AV0Z10100522), Z(MSM0021622410)
http://linked.open...iv/cisloPeriodika	17
http://linked.open...vai/riv/dodaniDat	2010
http://linked.open...aciTvurceVysledku	Kratochvíl, Jan Nečas, Marek Pinkas, Jiří
http://linked.open.../riv/druhVysledku	J - Článek v odborném periodiku
http://linked.open...iv/duvernostUdaju	S - Úplné a pravdivé údaje nepodléhající ochraně podle zvláštních právních předpisů
http://linked.open...titaPredkladatele	Masarykova univerzita / Přírodovědecká fakulta
http://linked.open...dnocenehoVysledku	470129
http://linked.open...ai/riv/idVysledku	RIV/00216224:14310/06:00015818
http://linked.open...riv/jazykVysledku	eng - angličtina
http://linked.open.../riv/klicovaSlova	aluminum; fluoride; phosphonate; D4R (en)
http://linked.open.../riv/klicoveSlovo	aluminum fluoride D4R phosphonate
http://linked.open...odStatuVydavatele	US - Spojené státy americké
http://linked.open...ontrolniKodProRIV	[AC27E38916EF]
http://linked.open...i/riv/nazevZdroje	INORGANIC CHEMISTRY
http://linked.open...in/vavai/riv/obor	CA
http://linked.open...ichTvurcuVysledku	3 (xsd:int)
http://linked.open...cetTvurcuVysledku	4 (xsd:int)
http://linked.open...vavai/riv/projekt	Universal methods for solution of periodic and aperiodic structures in the recioprocal and direct space Sonochemical synthesis of oxide and phosphate materials
http://linked.open...UplatneniVysledku	2006
http://linked.open...v/svazekPeriodika	45
http://linked.open...iv/tvurceVysledku	Kratochvíl, Jan Nečas, Marek Petříček, Václav Pinkas, Jiří
http://linked.open...ain/vavai/riv/wos	000239723300003
http://linked.open...n/vavai/riv/zamer	Wave and Corpuscular Light Propagation, Optical Materials and Technology Physical and chemical properties of advanced materials and structures
issn	0020-1669
number of pages	3 (xsd:int)
http://localhost/t...ganizacniJednotka	14310

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