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  • Tento příspěvek shrnuje aplikace NMR spektroskopie při studiu struktury, intramolekulárních a intermolekulárních interakcí derivátů purinu. (cs)
  • This contribution reviews applications of NMR spectroscopy in the investigation of the structure and the intra- and intermolecular interactions of purine derivatives. Purines represent a highly important class of heterocyclic compounds that are widely distributed in all living organisms, not only as constituents of nucleic acids, but also as signal molecules. Their structure, electron distribution, and proton-transfer processes determine their chemical reactivity, interactions with solvents, and, subsequently, also their biological activity and function. Along with X-ray diffraction, NMR spectroscopy represents one of the most important experimental tools for investigating molecular topology at the atomic level. In the following text, NMR methods suitable for studying the purine structure and their application to exploring samples at natural levels of the 13C and 15N isotopes are briefly reviewed. As will be shown, isotropic 13C and 15N chemical shifts, 1H-13C one- and three-bond J-coupling constants
  • This contribution reviews applications of NMR spectroscopy in the investigation of the structure and the intra- and intermolecular interactions of purine derivatives. Purines represent a highly important class of heterocyclic compounds that are widely distributed in all living organisms, not only as constituents of nucleic acids, but also as signal molecules. Their structure, electron distribution, and proton-transfer processes determine their chemical reactivity, interactions with solvents, and, subsequently, also their biological activity and function. Along with X-ray diffraction, NMR spectroscopy represents one of the most important experimental tools for investigating molecular topology at the atomic level. In the following text, NMR methods suitable for studying the purine structure and their application to exploring samples at natural levels of the 13C and 15N isotopes are briefly reviewed. As will be shown, isotropic 13C and 15N chemical shifts, 1H-13C one- and three-bond J-coupling constants (en)
Title
  • NMR Studies of Purines
  • NMR Studies of Purines (en)
  • NMR studium purinů (cs)
skos:prefLabel
  • NMR Studies of Purines
  • NMR Studies of Purines (en)
  • NMR studium purinů (cs)
skos:notation
  • RIV/00216224:14310/05:00013569!RIV08-MSM-14310___
http://linked.open.../vavai/riv/strany
  • 201-242
http://linked.open...avai/riv/aktivita
http://linked.open...avai/riv/aktivity
  • P(LN00A016)
http://linked.open...vai/riv/dodaniDat
http://linked.open...aciTvurceVysledku
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http://linked.open...iv/duvernostUdaju
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  • 532922
http://linked.open...ai/riv/idVysledku
  • RIV/00216224:14310/05:00013569
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  • NMR; purines; chemical shifts; coupling constants; tautomerism; protonation; complexation (en)
http://linked.open.../riv/klicoveSlovo
http://linked.open...ontrolniKodProRIV
  • [739FC7E79D89]
http://linked.open...i/riv/mistoVydani
  • London
http://linked.open...vEdiceCisloSvazku
  • 54
http://linked.open...i/riv/nazevZdroje
  • Annual Reports on NMR Spectroscopy
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http://linked.open...vavai/riv/projekt
http://linked.open...UplatneniVysledku
http://linked.open...iv/tvurceVysledku
  • Marek, Radek
  • Sklenář, Vladimír
number of pages
http://purl.org/ne...btex#hasPublisher
  • Elsevier
https://schema.org/isbn
  • 0-12-505454-8
http://localhost/t...ganizacniJednotka
  • 14310
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