About: The protonation/deprotonation equilibrium of azido-analogues of thymidine and uridine studied by UV spectroscopy and chemometrics

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About: The protonation/deprotonation equilibrium of azido-analogues of thymidine and uridine studied by UV spectroscopy and chemometrics Goto Sponge NotDistinct Permalink

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Description	In the present work we studied protonation/deprotonation equilibrium of azido-derivatives in aqueous solutions at various ionic strength by using UV spectra and chemometrics. The absorption spectra were measured from 240 to 320 nm at 25C.The absoption maxima of nucleic bases and their derivatives are very close and identical.From non-smoothed spectra the matrices were obtained that were used as input data for Multivariate Curve Resolution including the Alternation Least Squates (MCR-ALS, Matlab). In the present work we studied protonation/deprotonation equilibrium of azido-derivatives in aqueous solutions at various ionic strength by using UV spectra and chemometrics. The absorption spectra were measured from 240 to 320 nm at 25C.The absoption maxima of nucleic bases and their derivatives are very close and identical.From non-smoothed spectra the matrices were obtained that were used as input data for Multivariate Curve Resolution including the Alternation Least Squates (MCR-ALS, Matlab). (en)
Title	The protonation/deprotonation equilibrium of azido-analogues of thymidine and uridine studied by UV spectroscopy and chemometrics The protonation/deprotonation equilibrium of azido-analogues of thymidine and uridine studied by UV spectroscopy and chemometrics (en)
skos:prefLabel	The protonation/deprotonation equilibrium of azido-analogues of thymidine and uridine studied by UV spectroscopy and chemometrics The protonation/deprotonation equilibrium of azido-analogues of thymidine and uridine studied by UV spectroscopy and chemometrics (en)
skos:notation	RIV/00216224:14310/05:00012387!RIV10-MSM-14310___
http://linked.open...avai/riv/aktivita	P Z
http://linked.open...avai/riv/aktivity	P(GA203/02/0422), P(IAA1163201), Z(MSM 143100011)
http://linked.open...vai/riv/dodaniDat	2010
http://linked.open...aciTvurceVysledku	Topinková, Jana Trnková, Libuše
http://linked.open.../riv/druhVysledku	D - Článek ve sborníku
http://linked.open...iv/duvernostUdaju	S - Úplné a pravdivé údaje nepodléhající ochraně podle zvláštních právních předpisů
http://linked.open...titaPredkladatele	Masarykova univerzita / Přírodovědecká fakulta
http://linked.open...dnocenehoVysledku	539420
http://linked.open...ai/riv/idVysledku	RIV/00216224:14310/05:00012387
http://linked.open...riv/jazykVysledku	eng - angličtina
http://linked.open.../riv/klicovaSlova	Azido-analogues of thymidine and uridine; UV spektra; chemometrics (en)
http://linked.open.../riv/klicoveSlovo	chemometrics Azido-analogues of thymidine and uridine UV spektra
http://linked.open...ontrolniKodProRIV	[1B84ADE08361]
http://linked.open...v/mistoKonaniAkce	Brno, Česká Republika
http://linked.open...i/riv/mistoVydani	Brno,Česká Republika
http://linked.open...i/riv/nazevZdroje	sborník přispěvků- V. Pracovní setkání fyzikálních chemiků a elektrochemiků
http://linked.open...in/vavai/riv/obor	CF
http://linked.open...ichTvurcuVysledku	2 (xsd:int)
http://linked.open...cetTvurcuVysledku	2 (xsd:int)
http://linked.open...vavai/riv/projekt	New trends in electrochemistry of nucleic acids and their applications in enviromental chemistry Application of adsorptive transfer and elemination techniques in oligonucleotides and nucleic acids analysis.
http://linked.open...UplatneniVysledku	2005
http://linked.open...iv/tvurceVysledku	Trnková, Libuše Topinková, Jana
http://linked.open...vavai/riv/typAkce	CST - Celostátní
http://linked.open.../riv/zahajeniAkce	2005-02-08 (xsd:date)
http://linked.open...n/vavai/riv/zamer	http://linked.opendata.cz/resource/domain/vavai/zamer/MSM%20143100011
number of pages	2 (xsd:int)
http://purl.org/ne...btex#hasPublisher	Masarykova univerzita
https://schema.org/isbn	80-210-3637-0
http://localhost/t...ganizacniJednotka	14310

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