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Description
  • Elimination Voltammetry with Linear Scan (EVLS) is able to eliminate one or two selected current components from a total linear sweep voltammetric current. This is achieved by using elimination function obtained by the linear combination of total currents measured at different scan rates. In comparison with cyclic voltammetry (CV) or linear sweep voltammetry (LSV), the EVLS provides specific advantages: (a) expanded the available electrode potential range, (b) increased current sensitivity, and (c) improved peak resolution. The last two benefits result from the fact that the elimination of kinetic and charging currents decreases the irreversible current width and increases the peak height. The effect is particularly pronounced in the case where adsorption is involved. For the electroactive substance adsorbed or interacting with the electrode surface, the elimination function gives a well detectable peak-counterpeak signal which can be successfully used to analyze overlapped reduction or oxidation sign
  • Elimination Voltammetry with Linear Scan (EVLS) is able to eliminate one or two selected current components from a total linear sweep voltammetric current. This is achieved by using elimination function obtained by the linear combination of total currents measured at different scan rates. In comparison with cyclic voltammetry (CV) or linear sweep voltammetry (LSV), the EVLS provides specific advantages: (a) expanded the available electrode potential range, (b) increased current sensitivity, and (c) improved peak resolution. The last two benefits result from the fact that the elimination of kinetic and charging currents decreases the irreversible current width and increases the peak height. The effect is particularly pronounced in the case where adsorption is involved. For the electroactive substance adsorbed or interacting with the electrode surface, the elimination function gives a well detectable peak-counterpeak signal which can be successfully used to analyze overlapped reduction or oxidation sign (en)
  • Elimination Voltammetry with Linear Scan (EVLS) is able to eliminate one or two selected current components from a total linear sweep voltammetric current. This is achieved by using elimination function obtained by the linear combination of total currents measured at different scan rates. In comparison with cyclic voltammetry (CV) or linear sweep voltammetry (LSV), the EVLS provides specific advantages: (a) expanded the available electrode potential range, (b) increased current sensitivity, and (c) improved peak resolution. The last two benefits result from the fact that the elimination of kinetic and charging currents decreases the irreversible current width and increases the peak height. The effect is particularly pronounced in the case where adsorption is involved. For the electroactive substance adsorbed or interacting with the electrode surface, the elimination function gives a well detectable peak-counterpeak signal which can be successfully used to analyze overlapped reduction or oxidation sign (cs)
Title
  • Application of elimination voltammetry with linear scan in bioelectrochemistry
  • Application of elimination voltammetry with linear scan in bioelectrochemistry (en)
  • Application of elimination voltammetry with linear scan in bioelectrochemistry (cs)
skos:prefLabel
  • Application of elimination voltammetry with linear scan in bioelectrochemistry
  • Application of elimination voltammetry with linear scan in bioelectrochemistry (en)
  • Application of elimination voltammetry with linear scan in bioelectrochemistry (cs)
skos:notation
  • RIV/00216224:14310/03:00008232!RIV08-AV0-14310___
http://linked.open.../vavai/riv/strany
  • 92-92
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  • P(GA203/02/0422), P(GV204/97/K084), P(IAA1163201)
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  • 598857
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  • RIV/00216224:14310/03:00008232
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  • Voltammetric methods; elimination voltammetry with linear scan (EVLS); elimination functions; adsorbed species; mercury and solid electrodes; resolution of reduction and oxidation signals in oligo- and poly-nucleotides (en)
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  • [692178DBB0CA]
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  • Sao Pedro, Brazil
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  • Sao Paulo, Brazil
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  • The role of electrochemistry in sustained development of modern societies, 54 th ISE Meeting
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  • Trnková, Libuše
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  • 14310
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