About: Isoquinoline alkaloids: a 15N NMR and x-ray study. Part 2

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rdf:type	skos:Concept http://linked.opendata.cz/ontology/domain/vavai/Vysledek
Description	Continuing our systematic 15N NMR study of isoquinoline alkaloids, we report a contribution extending our previous paper. The 15N NMR chemical shifts and 15N,1H long-range coupling pathways of tertiary and quaternary isoquinoline alkaloids of several constitutional types are presented. The selected compounds belong to the protoberberine, proaporphine, pavinane, rhoeadine and phtalideisoquinoline classes of alkaloids and were investigated by gradient-selected inverse-detected multiple bond correlation experiments (GHMBC and GSQMBC). In addition, x-ray data and the principal geometric parameters of stylopine, mecambridine, norchelerythrine, isothebaine and mecambrine are reported and discussed. Continuing our systematic 15N NMR study of isoquinoline alkaloids, we report a contribution extending our previous paper. The 15N NMR chemical shifts and 15N,1H long-range coupling pathways of tertiary and quaternary isoquinoline alkaloids of several constitutional types are presented. The selected compounds belong to the protoberberine, proaporphine, pavinane, rhoeadine and phtalideisoquinoline classes of alkaloids and were investigated by gradient-selected inverse-detected multiple bond correlation experiments (GHMBC and GSQMBC). In addition, x-ray data and the principal geometric parameters of stylopine, mecambridine, norchelerythrine, isothebaine and mecambrine are reported and discussed. (en) Continuing our systematic 15N NMR study of isoquinoline alkaloids, we report a contribution extending our previous paper. The 15N NMR chemical shifts and 15N,1H long-range coupling pathways of tertiary and quaternary isoquinoline alkaloids of several constitutional types are presented. The selected compounds belong to the protoberberine, proaporphine, pavinane, rhoeadine and phtalideisoquinoline classes of alkaloids and were investigated by gradient-selected inverse-detected multiple bond correlation experiments (GHMBC and GSQMBC). In addition, x-ray data and the principal geometric parameters of stylopine, mecambridine, norchelerythrine, isothebaine and mecambrine are reported and discussed. (cs)
Title	Isoquinoline alkaloids: a 15N NMR and x-ray study. Part 2 Isoquinoline alkaloids: a 15N NMR and x-ray study. Part 2 (en) Isoquinoline alkaloids: a 15N NMR and x-ray study. Part 2 (cs)
skos:prefLabel	Isoquinoline alkaloids: a 15N NMR and x-ray study. Part 2 Isoquinoline alkaloids: a 15N NMR and x-ray study. Part 2 (en) Isoquinoline alkaloids: a 15N NMR and x-ray study. Part 2 (cs)
skos:notation	RIV/00216224:14310/02:00006431!RIV09-MSM-14310___
http://linked.open...avai/riv/aktivita	P
http://linked.open...avai/riv/aktivity	P(LN00A016)
http://linked.open...iv/cisloPeriodika	11
http://linked.open...vai/riv/dodaniDat	2009
http://linked.open...aciTvurceVysledku	Táborská, Eva Dostál, Jiří Marek, Radek Marek, Jaromír
http://linked.open.../riv/druhVysledku	J - Článek v odborném periodiku
http://linked.open...iv/duvernostUdaju	S - Úplné a pravdivé údaje nepodléhající ochraně podle zvláštních právních předpisů
http://linked.open...titaPredkladatele	Masarykova univerzita / Přírodovědecká fakulta
http://linked.open...dnocenehoVysledku	649805
http://linked.open...ai/riv/idVysledku	RIV/00216224:14310/02:00006431
http://linked.open...riv/jazykVysledku	eng - angličtina
http://linked.open.../riv/klicovaSlova	alkaloid; isoquinoline; 15N NMR; X-ray (en)
http://linked.open.../riv/klicoveSlovo	15N NMR X-ray alkaloid isoquinoline
http://linked.open...odStatuVydavatele	GB - Spojené království Velké Británie a Severního Irska
http://linked.open...ontrolniKodProRIV	[AE5079AA9815]
http://linked.open...i/riv/nazevZdroje	Magnetic Resonance in Chemistry
http://linked.open...in/vavai/riv/obor	CC
http://linked.open...ichTvurcuVysledku	4 (xsd:int)
http://linked.open...cetTvurcuVysledku	6 (xsd:int)
http://linked.open...vavai/riv/projekt	BIOMOLECULAR CENTER
http://linked.open...UplatneniVysledku	2002
http://linked.open...v/svazekPeriodika	40
http://linked.open...iv/tvurceVysledku	Dostál, Jiří Marek, Radek Marek, Jaromír Táborská, Eva Slavík, Jiří Dommisse, Roger
http://linked.open...ain/vavai/riv/wos	000178816300002
issn	0749-1581
number of pages	6 (xsd:int)
http://localhost/t...ganizacniJednotka	14310

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