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Description
  • The kinetics of structural changes in cytidine and deoxycytidine adlayers on the mercury film electrodes were investigated by means of current and capacitance transients using the potential step technique. By means of j-t transients we studied the processes taking place at the beginning of the growth or dissolution of physical condensed and highly ordered adlayers. On the other site the C-t transients revealed changes taking place within physical condensed cytidine adlayers at longer times. The kinetics of the interfacial rearrangements were better observed with the pyrolytic carbon than with glassy carbon electrodes. The experimental j-t and C-t curves were analysed by comparison with several models based on the nucleation and growth in combination with a parallel Lanqmuir-type adsorption/desorption process. Adsorption of cytidine on Au(111) from 0.1 M KClO4 electrolyte solution is characterized by formation of various films delimited by 2-D phase transitions.
  • The kinetics of structural changes in cytidine and deoxycytidine adlayers on the mercury film electrodes were investigated by means of current and capacitance transients using the potential step technique. By means of j-t transients we studied the processes taking place at the beginning of the growth or dissolution of physical condensed and highly ordered adlayers. On the other site the C-t transients revealed changes taking place within physical condensed cytidine adlayers at longer times. The kinetics of the interfacial rearrangements were better observed with the pyrolytic carbon than with glassy carbon electrodes. The experimental j-t and C-t curves were analysed by comparison with several models based on the nucleation and growth in combination with a parallel Lanqmuir-type adsorption/desorption process. Adsorption of cytidine on Au(111) from 0.1 M KClO4 electrolyte solution is characterized by formation of various films delimited by 2-D phase transitions. (en)
  • The kinetics of structural changes in cytidine and deoxycytidine adlayers on the mercury film electrodes were investigated by means of current and capacitance transients using the potential step technique. By means of j-t transients we studied the processes taking place at the beginning of the growth or dissolution of physical condensed and highly ordered adlayers. On the other site the C-t transients revealed changes taking place within physical condensed cytidine adlayers at longer times. The kinetics of the interfacial rearrangements were better observed with the pyrolytic carbon than with glassy carbon electrodes. The experimental j-t and C-t curves were analysed by comparison with several models based on the nucleation and growth in combination with a parallel Lanqmuir-type adsorption/desorption process. Adsorption of cytidine on Au(111) from 0.1 M KClO4 electrolyte solution is characterized by formation of various films delimited by 2-D phase transitions. (cs)
Title
  • Two-dimensional condensation of nucleic acid components at mercury film and gold electrodes
  • Two-dimensional condensation of nucleic acid components at mercury film and gold electrodes (en)
  • Two-dimensional condensation of nucleic acid components at mercury film and gold electrodes (cs)
skos:prefLabel
  • Two-dimensional condensation of nucleic acid components at mercury film and gold electrodes
  • Two-dimensional condensation of nucleic acid components at mercury film and gold electrodes (en)
  • Two-dimensional condensation of nucleic acid components at mercury film and gold electrodes (cs)
skos:notation
  • RIV/00216224:14310/01:00007532!RIV08-AV0-14310___
http://linked.open.../vavai/riv/strany
  • 110
http://linked.open...avai/riv/aktivita
http://linked.open...avai/riv/aktivity
  • P(GV204/97/K084), P(IAA4004002), P(IBS5004107)
http://linked.open...vai/riv/dodaniDat
http://linked.open...aciTvurceVysledku
http://linked.open.../riv/druhVysledku
http://linked.open...iv/duvernostUdaju
http://linked.open...titaPredkladatele
http://linked.open...dnocenehoVysledku
  • 699363
http://linked.open...ai/riv/idVysledku
  • RIV/00216224:14310/01:00007532
http://linked.open...riv/jazykVysledku
http://linked.open.../riv/klicovaSlova
  • cytidine adsorption; deoxycytidine adsorption; two-dimensional condensation; Au(111) (en)
http://linked.open.../riv/klicoveSlovo
http://linked.open...ontrolniKodProRIV
  • [03767F2BDC86]
http://linked.open...v/mistoKonaniAkce
  • 1.-6.6.2001
http://linked.open...i/riv/mistoVydani
  • Bratislava
http://linked.open...i/riv/nazevZdroje
  • Book of Abstracts, XVI th International Symposium on Bioelectrochemistry and Bioenergetics
http://linked.open...in/vavai/riv/obor
http://linked.open...ichTvurcuVysledku
http://linked.open...cetTvurcuVysledku
http://linked.open...vavai/riv/projekt
http://linked.open...UplatneniVysledku
http://linked.open...iv/tvurceVysledku
  • Hasoň, Stanislav
  • Vetterl, Vladimír
http://linked.open...vavai/riv/typAkce
http://linked.open.../riv/zahajeniAkce
number of pages
http://purl.org/ne...btex#hasPublisher
  • XVI th International Symposium on Bioelectrochemistry and Bioenergetics
http://localhost/t...ganizacniJednotka
  • 14310
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