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  • If the NMR spectrum does not contain any signal suitable for integration, a quantivative determination can be made from the whole spectrum which was properly broadened by an exponential multiplication of the FID. Then the mathematical procedure comprises either a multivariate calibration or a nonparametric estimation. For both methods an accuracy of the results is not easy to find out. However, it can be estimated from a confidence ellipse. For this graphical presentation a calibration set of, e.g., seven NMR spectra from repeated measurement of the same sample with the concentration of analyte corresponding to that which will be determined is obtained and each spectral curve is transformed into two coefficients x and y. These are in fact real and imaginary parts of the first complex number after the Fourier transform of the NMR spectrum.Around these points the confidence ellipses are drawn and then the point from sample with different concentration is added. If the point is pretty out of the ellipses
  • If the NMR spectrum does not contain any signal suitable for integration, a quantivative determination can be made from the whole spectrum which was properly broadened by an exponential multiplication of the FID. Then the mathematical procedure comprises either a multivariate calibration or a nonparametric estimation. For both methods an accuracy of the results is not easy to find out. However, it can be estimated from a confidence ellipse. For this graphical presentation a calibration set of, e.g., seven NMR spectra from repeated measurement of the same sample with the concentration of analyte corresponding to that which will be determined is obtained and each spectral curve is transformed into two coefficients x and y. These are in fact real and imaginary parts of the first complex number after the Fourier transform of the NMR spectrum.Around these points the confidence ellipses are drawn and then the point from sample with different concentration is added. If the point is pretty out of the ellipses (en)
  • If the NMR spectrum does not contain any signal suitable for integration, a quantivative determination can be made from the whole spectrum which was properly broadened by an exponential multiplication of the FID. Then the mathematical procedure comprises either a multivariate calibration or a nonparametric estimation. For both methods an accuracy of the results is not easy to find out. However, it can be estimated from a confidence ellipse. For this graphical presentation a calibration set of, e.g., seven NMR spectra from repeated measurement of the same sample with the concentration of analyte corresponding to that which will be determined is obtained and each spectral curve is transformed into two coefficients x and y. These are in fact real and imaginary parts of the first complex number after the Fourier transform of the NMR spectrum.Around these points the confidence ellipses are drawn and then the point from sample with different concentration is added. If the point is pretty out of the ellipses (cs)
Title
  • CONFIDENCE ELLIPSES FOR THE QUANTITATIVE ANALYSIS FROM THE WHOLE NMR SPECTRUM.
  • CONFIDENCE ELLIPSES FOR THE QUANTITATIVE ANALYSIS FROM THE WHOLE NMR SPECTRUM. (en)
  • CONFIDENCE ELLIPSES FOR THE QUANTITATIVE ANALYSIS FROM THE WHOLE NMR SPECTRUM. (cs)
skos:prefLabel
  • CONFIDENCE ELLIPSES FOR THE QUANTITATIVE ANALYSIS FROM THE WHOLE NMR SPECTRUM.
  • CONFIDENCE ELLIPSES FOR THE QUANTITATIVE ANALYSIS FROM THE WHOLE NMR SPECTRUM. (en)
  • CONFIDENCE ELLIPSES FOR THE QUANTITATIVE ANALYSIS FROM THE WHOLE NMR SPECTRUM. (cs)
skos:notation
  • RIV/00216224:14310/01:00005339!RIV08-MSM-14310___
http://linked.open.../vavai/riv/strany
  • 44
http://linked.open...avai/riv/aktivita
http://linked.open...avai/riv/aktivity
  • Z(MSM 143100011)
http://linked.open...vai/riv/dodaniDat
http://linked.open...aciTvurceVysledku
http://linked.open.../riv/druhVysledku
http://linked.open...iv/duvernostUdaju
http://linked.open...titaPredkladatele
http://linked.open...dnocenehoVysledku
  • 676247
http://linked.open...ai/riv/idVysledku
  • RIV/00216224:14310/01:00005339
http://linked.open...riv/jazykVysledku
http://linked.open.../riv/klicovaSlova
  • low resolution; quantitative analysis; confidence ellipse (en)
http://linked.open.../riv/klicoveSlovo
http://linked.open...ontrolniKodProRIV
  • [902E0381E43E]
http://linked.open...v/mistoKonaniAkce
  • Valtice
http://linked.open...i/riv/mistoVydani
  • Brno
http://linked.open...i/riv/nazevZdroje
  • 16th NMR Valtice, 23.-25.4.2001
http://linked.open...in/vavai/riv/obor
http://linked.open...ichTvurcuVysledku
http://linked.open...cetTvurcuVysledku
http://linked.open...UplatneniVysledku
http://linked.open...iv/tvurceVysledku
  • Halámek, Josef
  • Holík, Miroslav
http://linked.open...vavai/riv/typAkce
http://linked.open.../riv/zahajeniAkce
http://linked.open...n/vavai/riv/zamer
number of pages
http://purl.org/ne...btex#hasPublisher
  • Masarykova univerzita v Brně
https://schema.org/isbn
  • 80-210-2566-2
http://localhost/t...ganizacniJednotka
  • 14310
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