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  • In this work we apply nuclear magnetic resonance (NMR) spectroscopy of Fe-57 nuclei for investigation of submicron and nanocrystalline iron oxide systems. The studied iron oxide particles are obtained from ferrous hydroxide gels (prepared from FeCl2 and KOH) by aging at elevated temperatures (90 degrees C) with KNO3 as oxidant. The Fe-57 NAIR spectra of the samples are measured in temperature range 4.2-370 K in a zero external magnetic field. Signals of Fe-57 nuclei assigned to tetrahedral and octahedral iron sites are well resolved. The NMR spectra and their temperature dependences are compared with those of stoichiometric and nonstoichiometric magnetite single crystals, as well as with samples of maghemite.
  • In this work we apply nuclear magnetic resonance (NMR) spectroscopy of Fe-57 nuclei for investigation of submicron and nanocrystalline iron oxide systems. The studied iron oxide particles are obtained from ferrous hydroxide gels (prepared from FeCl2 and KOH) by aging at elevated temperatures (90 degrees C) with KNO3 as oxidant. The Fe-57 NAIR spectra of the samples are measured in temperature range 4.2-370 K in a zero external magnetic field. Signals of Fe-57 nuclei assigned to tetrahedral and octahedral iron sites are well resolved. The NMR spectra and their temperature dependences are compared with those of stoichiometric and nonstoichiometric magnetite single crystals, as well as with samples of maghemite. (en)
Title
  • Structure of Iron Oxide Nanoparticles Studied by Fe-57 NMR
  • Structure of Iron Oxide Nanoparticles Studied by Fe-57 NMR (en)
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  • Structure of Iron Oxide Nanoparticles Studied by Fe-57 NMR
  • Structure of Iron Oxide Nanoparticles Studied by Fe-57 NMR (en)
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  • RIV/00216208:11320/14:10290739!RIV15-MSM-11320___
http://linked.open...avai/riv/aktivita
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  • S
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  • 1
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  • 47934
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  • RIV/00216208:11320/14:10290739
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  • NMR; magnetite; Verwey transition (en)
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  • PL - Polská republika
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  • [7612A9097BC1]
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  • Acta Physica Polonica A
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  • 126
http://linked.open...iv/tvurceVysledku
  • Štěpánková, Helena
  • Chlan, Vojtěch
  • Křišťan, Petr
  • Řezníček, Richard
  • Goernert, P.
  • Payer, P.
http://linked.open...ain/vavai/riv/wos
  • 000339833100066
issn
  • 0587-4246
number of pages
http://bibframe.org/vocab/doi
  • 10.12693/APhysPolA.126.138
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  • 11320
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