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  • The magnetocaloric effect of a coordination. polymeric material with a repeating unit of Gd(OH)CO3 has been studied experimentally using isothermal magnetization and heat capacity measurements. The maximum entropy change, -Delta S-m, reaches 66.4 J kg(-1) K-1 or 355 mJ cm(-3) K-1 for Delta H = 7 T and T = 1.8 K. Density functional theory (DFT) calculations show weak and competing antiferromagnetic interactions between the metal centres.
  • The magnetocaloric effect of a coordination. polymeric material with a repeating unit of Gd(OH)CO3 has been studied experimentally using isothermal magnetization and heat capacity measurements. The maximum entropy change, -Delta S-m, reaches 66.4 J kg(-1) K-1 or 355 mJ cm(-3) K-1 for Delta H = 7 T and T = 1.8 K. Density functional theory (DFT) calculations show weak and competing antiferromagnetic interactions between the metal centres. (en)
Title
  • Study of a magnetic-cooling material Gd(OH)CO3
  • Study of a magnetic-cooling material Gd(OH)CO3 (en)
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  • Study of a magnetic-cooling material Gd(OH)CO3
  • Study of a magnetic-cooling material Gd(OH)CO3 (en)
skos:notation
  • RIV/00216208:11320/14:10271609!RIV15-MSM-11320___
http://linked.open...avai/riv/aktivita
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  • I, P(LM2011025)
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  • 25
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  • 48228
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  • RIV/00216208:11320/14:10271609
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  • relaxation; coolers; refrigeration; clusters; gd complexes; crystal-structure; molecular magnets; magnetocaloric materials; low-temperature; metal-organic framework (en)
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  • GB - Spojené království Velké Británie a Severního Irska
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  • [87419B70BCFE]
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  • Journal of Materials Chemistry A
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  • 2
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  • Prokleška, Jan
  • Sechovský, Vladimír
  • Tong, Ming-Liang
  • Orendac, Martin
  • Tarasenko, Robert
  • Chen, Yan-Cong
  • Liu, Jun-Liang
  • Zheng, Yan-Zhen
  • Meng, Zhao-Sha
  • Fu, Zhendong
  • Qin, Lei
  • Wu, Chao
  • Yang, Ding-Feng
http://linked.open...ain/vavai/riv/wos
  • 000337774100052
issn
  • 2050-7488
number of pages
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  • 10.1039/c4ta01646g
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  • 11320
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