About: Heat capacity, enthalpy and entropy of Sr14Co11O33 and Sr6Co5O15     Goto   Sponge   NotDistinct   Permalink

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  • Heat capacity and enthalpy increments of two ternary strontium cobalt mixed oxides Sr14Co11O33 and Sr6Co5O15 were measured by the relaxation time method (2-250 K ), DSC (258-355 K) and drop calorimetry (573-1173 K). Temperature dependencies of the molar heat capacity in the form C-pm=1359.46 + 0.355826.T-19.5816.10(6).T(-2)J K-1 mol(-1) for Sr14Co11O33 and C-pm=515.81+0.313326.T-5.07872.10(6)-T-2 J K-1 mol(-1) for Sr6Co5O15 respectively, were derived by the least-squares method from the experimental data. The heat capacity was analyzed in terms of a combined Debye-Einstein model. The molar entropies at 298.15 K, S-m(298.15 K) = 1339.76 J K-1 mol(-1) for Sr14Co11O33 and S-m(298.15 K) = 578.77 J K-1 mol(-1) for Sr6Co5O15 were evaluated from the low temperature heat capacity measurements. (C) 2013 Elsevier B.V. All rights reserved.
  • Heat capacity and enthalpy increments of two ternary strontium cobalt mixed oxides Sr14Co11O33 and Sr6Co5O15 were measured by the relaxation time method (2-250 K ), DSC (258-355 K) and drop calorimetry (573-1173 K). Temperature dependencies of the molar heat capacity in the form C-pm=1359.46 + 0.355826.T-19.5816.10(6).T(-2)J K-1 mol(-1) for Sr14Co11O33 and C-pm=515.81+0.313326.T-5.07872.10(6)-T-2 J K-1 mol(-1) for Sr6Co5O15 respectively, were derived by the least-squares method from the experimental data. The heat capacity was analyzed in terms of a combined Debye-Einstein model. The molar entropies at 298.15 K, S-m(298.15 K) = 1339.76 J K-1 mol(-1) for Sr14Co11O33 and S-m(298.15 K) = 578.77 J K-1 mol(-1) for Sr6Co5O15 were evaluated from the low temperature heat capacity measurements. (C) 2013 Elsevier B.V. All rights reserved. (en)
Title
  • Heat capacity, enthalpy and entropy of Sr14Co11O33 and Sr6Co5O15
  • Heat capacity, enthalpy and entropy of Sr14Co11O33 and Sr6Co5O15 (en)
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  • Heat capacity, enthalpy and entropy of Sr14Co11O33 and Sr6Co5O15
  • Heat capacity, enthalpy and entropy of Sr14Co11O33 and Sr6Co5O15 (en)
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  • RIV/00216208:11320/14:10210334!RIV15-MSM-11320___
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  • I, P(GA13-17538S), P(GAP108/10/1006), P(LM2011025), S
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  • 18865
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  • RIV/00216208:11320/14:10210334
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  • Calorimetry; Entropy; Enthalpy increments; Heat capacity; Strontium cobalt oxides (en)
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  • NL - Nizozemsko
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  • [1660B1BE794C]
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  • Thermochimica Acta
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  • 575
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  • Růžička, Květoslav
  • Sofer, Zdeněk
  • Svoboda, Pavel
  • Leitner, Jindřich
  • Sedmidubský, David
  • Jankovský, Ondrřej
http://linked.open...ain/vavai/riv/wos
  • 000329889500022
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  • 0040-6031
number of pages
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  • 10.1016/j.tca.2013.10.031
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  • 11320
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