About: Ternary Recombination of H-3(+) and D-3(+) with Electrons in He-H-2 (D-2) Plasmas at Temperatures from 50 to 300 K

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About: Ternary Recombination of H-3(+) and D-3(+) with Electrons in He-H-2 (D-2) Plasmas at Temperatures from 50 to 300 K Goto Sponge NotDistinct Permalink

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rdf:type	skos:Concept http://linked.opendata.cz/ontology/domain/vavai/Vysledek
rdfs:seeAlso	http://dx.doi.org/10.1021/jp311978n
Description	We present results of plasma afterglow experiments on ternary electron ion recombination rate coefficients of H-3(+) and D-3(+) ions at temperatures from 50 to 300 K and compare them to possible three body reaction mechanisms Resonant electron capture into H-3* Rydberg states is likely to be the first step in the ternary recombination, rather than third-body-assisted capture. Subsequent interactions of the Rydberg molecules with ambient neutral and charged particles provide the rate-limiting step that completes the recombination. A semiquantitative model is proposed that reconciles several previously discrepant experimental observations. A rigorous treatment of the problem will require additional theoretical work and experimental investigations. We present results of plasma afterglow experiments on ternary electron ion recombination rate coefficients of H-3(+) and D-3(+) ions at temperatures from 50 to 300 K and compare them to possible three body reaction mechanisms Resonant electron capture into H-3* Rydberg states is likely to be the first step in the ternary recombination, rather than third-body-assisted capture. Subsequent interactions of the Rydberg molecules with ambient neutral and charged particles provide the rate-limiting step that completes the recombination. A semiquantitative model is proposed that reconciles several previously discrepant experimental observations. A rigorous treatment of the problem will require additional theoretical work and experimental investigations. (en)
Title	Ternary Recombination of H-3(+) and D-3(+) with Electrons in He-H-2 (D-2) Plasmas at Temperatures from 50 to 300 K Ternary Recombination of H-3(+) and D-3(+) with Electrons in He-H-2 (D-2) Plasmas at Temperatures from 50 to 300 K (en)
skos:prefLabel	Ternary Recombination of H-3(+) and D-3(+) with Electrons in He-H-2 (D-2) Plasmas at Temperatures from 50 to 300 K Ternary Recombination of H-3(+) and D-3(+) with Electrons in He-H-2 (D-2) Plasmas at Temperatures from 50 to 300 K (en)
skos:notation	RIV/00216208:11320/13:10191396!RIV14-GA0-11320___
http://linked.open...avai/riv/aktivita	I P S
http://linked.open...avai/riv/aktivity	I, P(GA205/09/1183), P(GAP209/12/0233), P(OC10046), S
http://linked.open...iv/cisloPeriodika	39
http://linked.open...vai/riv/dodaniDat	2014
http://linked.open...aciTvurceVysledku	Rubovič, Peter Plašil, Radek Dohnal, Petr Glosík, Juraj Hejduk, Michal
http://linked.open.../riv/druhVysledku	J - Článek v odborném periodiku
http://linked.open...iv/duvernostUdaju	S - Úplné a pravdivé údaje nepodléhající ochraně podle zvláštních právních předpisů
http://linked.open...titaPredkladatele	Univerzita Karlova v Praze / Matematicko-fyzikální fakulta
http://linked.open...dnocenehoVysledku	110542
http://linked.open...ai/riv/idVysledku	RIV/00216208:11320/13:10191396
http://linked.open...riv/jazykVysledku	eng - angličtina
http://linked.open.../riv/klicovaSlova	atoms; states; binary; ionization; spectroscopy; afterglow; gas; ions; dissociative recombination; collisional-radiative recombination (en)
http://linked.open.../riv/klicoveSlovo	ionization ions afterglow collisional-radiative recombination dissociative recombination atoms spectroscopy states binary gas
http://linked.open...odStatuVydavatele	US - Spojené státy americké
http://linked.open...ontrolniKodProRIV	[3C11AD288004]
http://linked.open...i/riv/nazevZdroje	Journal of Physical Chemistry A
http://linked.open...in/vavai/riv/obor	BL
http://linked.open...ichTvurcuVysledku	5 (xsd:int)
http://linked.open...cetTvurcuVysledku	6 (xsd:int)
http://linked.open...vavai/riv/projekt	Experimental astrochemistry - reactions of anions Laboratory astrophysics: Formation and recombination of astrophysically relevant ions. Astrochemistry
http://linked.open...UplatneniVysledku	2013
http://linked.open...v/svazekPeriodika	117
http://linked.open...iv/tvurceVysledku	Dohnal, Petr Glosík, Juraj Johnsen, R. Plašil, Radek Rubovič, Peter Hejduk, Michal
http://linked.open...ain/vavai/riv/wos	000326300600019
issn	1089-5639
number of pages	9 (xsd:int)
http://bibframe.org/vocab/doi	10.1021/jp311978n
http://localhost/t...ganizacniJednotka	11320

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