About: Gadolinium(III)-Hydroxy Ladders Trapped in Succinate Frameworks with Optimized Magnetocaloric Effect

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Attributes	Values
rdf:type	skos:Concept http://linked.opendata.cz/ontology/domain/vavai/Vysledek
rdfs:seeAlso	http://dx.doi.org/10.1002/chem.201301221
Description	Two kinds of inorganic gadolinium(III)-hydroxy ladders, [2xn] and [3xn], were successfully trapped in succinate (suc) coordination polymers, [Gd-2(OH)(2)(suc)(2)(H2O)](n) 2nH(2)O (1) and [Gd-6(OH)(8)(suc)(5)(H2O)(2)](n)4nH(2)O (2), respectively. Such coordination polymers could be regarded as alternating inorganic-organic hybrid materials with relatively high density. Magnetic and heat capacity studies reveal a large cryogenic magnetocaloric effect (MCE) in both compounds, namely (H=70kG) 42.8Jkg(-1)K(-1) for complex 1 and 48.0Jkg(-1)K(-1) for complex 2. The effect of the high density is evident, which gives very large volumetric MCEs up to 120 and 144mJcm(-3)K(-1) for complexes 1 and 2, respectively. Two kinds of inorganic gadolinium(III)-hydroxy ladders, [2xn] and [3xn], were successfully trapped in succinate (suc) coordination polymers, [Gd-2(OH)(2)(suc)(2)(H2O)](n) 2nH(2)O (1) and [Gd-6(OH)(8)(suc)(5)(H2O)(2)](n)4nH(2)O (2), respectively. Such coordination polymers could be regarded as alternating inorganic-organic hybrid materials with relatively high density. Magnetic and heat capacity studies reveal a large cryogenic magnetocaloric effect (MCE) in both compounds, namely (H=70kG) 42.8Jkg(-1)K(-1) for complex 1 and 48.0Jkg(-1)K(-1) for complex 2. The effect of the high density is evident, which gives very large volumetric MCEs up to 120 and 144mJcm(-3)K(-1) for complexes 1 and 2, respectively. (en)
Title	Gadolinium(III)-Hydroxy Ladders Trapped in Succinate Frameworks with Optimized Magnetocaloric Effect Gadolinium(III)-Hydroxy Ladders Trapped in Succinate Frameworks with Optimized Magnetocaloric Effect (en)
skos:prefLabel	Gadolinium(III)-Hydroxy Ladders Trapped in Succinate Frameworks with Optimized Magnetocaloric Effect Gadolinium(III)-Hydroxy Ladders Trapped in Succinate Frameworks with Optimized Magnetocaloric Effect (en)
skos:notation	RIV/00216208:11320/13:10145604!RIV14-MSM-11320___
http://linked.open...avai/riv/aktivita	I P
http://linked.open...avai/riv/aktivity	I, P(LM2011025)
http://linked.open...iv/cisloPeriodika	40
http://linked.open...vai/riv/dodaniDat	2014
http://linked.open...aciTvurceVysledku	Sechovský, Vladimír Prokleška, Jan
http://linked.open.../riv/druhVysledku	J - Článek v odborném periodiku
http://linked.open...iv/duvernostUdaju	S - Úplné a pravdivé údaje nepodléhající ochraně podle zvláštních právních předpisů
http://linked.open...titaPredkladatele	Univerzita Karlova v Praze / Matematicko-fyzikální fakulta
http://linked.open...dnocenehoVysledku	76143
http://linked.open...ai/riv/idVysledku	RIV/00216208:11320/13:10145604
http://linked.open...riv/jazykVysledku	eng - angličtina
http://linked.open.../riv/klicovaSlova	succinate; magnetocaloric effect; magnetic properties; gadolinium; coordination polymers (en)
http://linked.open.../riv/klicoveSlovo	coordination polymers magnetocaloric effect gadolinium magnetic properties succinate
http://linked.open...odStatuVydavatele	DE - Spolková republika Německo
http://linked.open...ontrolniKodProRIV	[597A840FB12D]
http://linked.open...i/riv/nazevZdroje	Chemistry - A European Journal
http://linked.open...in/vavai/riv/obor	BM
http://linked.open...ichTvurcuVysledku	2 (xsd:int)
http://linked.open...cetTvurcuVysledku	10 (xsd:int)
http://linked.open...vavai/riv/projekt	MLTL - Magnetism and Low Temperature Laboratories - operation and development of national research infrastructure
http://linked.open...UplatneniVysledku	2013
http://linked.open...v/svazekPeriodika	19
http://linked.open...iv/tvurceVysledku	Prokleška, Jan Sechovský, Vladimír Leng, Ji-Dong Tong, Ming-Liang Orendac, Martin Tarasenko, Robert Chen, Yan-Cong Guo, Fu-Sheng Liu, Jun-Liang Zheng, Yan-Zhen
http://linked.open...ain/vavai/riv/wos	000325091300033
issn	0947-6539
number of pages	7 (xsd:int)
http://bibframe.org/vocab/doi	10.1002/chem.201301221
http://localhost/t...ganizacniJednotka	11320

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